Patent classifications
C08G65/2606
METHOD FOR PRODUCING POLYETHER CARBONATE POLYOLS
The invention relates to a method for producing polyether carbonate polyols by adding alkylene oxides and carbon dioxide to an H-functional starter substance in the presence of a double metal cyanide (DMC) catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, wherein () alkylene oxide and carbon dioxide are added to an H-functional starter substance in a reactor with a total pressure (absolute) of 5 to 120 bar in the presence of a double metal cyanide catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, and a reaction mixture containing the polyether carbonate polyol is obtained, () the reaction mixture obtained in step () remains in the reactor or is optionally continuously transferred to a downstream reactor at a starting total pressure (absolute) of 5 to 120 bar, the content of free alkylene oxide in the reaction mixture being reduced in the course of a downstream reaction in each case, and the total pressure (absolute) can be reduced by up to 50% during the step (), and () the content of highly volatile components of the obtained reaction mixture is thermally reduced at a temperature of 80 C. to 200 C. The invention is characterized in that () the reaction mixture resulting from step () is brought to a total pressure (absolute) of 2.0 bar, preferably 0.5 bar to 2.0 bar, particularly preferably 0.9 bar to 1.1 bar, prior to step () and then left at a temperature of 80 to 180 C. for a dwell time of at least 0.5 h. After the dwell time has expired, 5 to 100 ppm of component K is added to the resulting mixture, component K being selected from at least one compound which contains a phosphorus-oxygen-hydrogen group.
PROCESS FOR MAKING POLYETHERS WITH REDUCED AMOUNTS OF UNSATURATED MONOLS
Unsaturated polyether monols are removed from polyether polyols by reaction with a functionalized thiol compound or a polythiol compound. This process replaces the terminal unsaturation with a functional group, or else couples two or more of the monols to form a polyol. The functionality of the polyether polyol product is increased by the removal of the monols.
MODIFIED CELLULOSE FIBER
Modified cellulose fibers having an average fiber size of 5 m or more, wherein one or more substituents selected from substituents represented by the following general formulas (1) and (2): CH.sub.2CH(OH)R.sub.1 (1); CH.sub.2CH(OH)CH.sub.2(OA).sub.n-OR.sub.1 (2); wherein each R.sub.1 in the general formulas (1) and (2) is independently a linear or branched alkyl group having 3 or more carbon atoms and 30 or less carbon atoms; n in the general formula (2) is a number of 0 or more and 50 or less; and A is a linear or branched, divalent saturated hydrocarbon group having 1 or more carbon atoms and 6 or less carbon atoms, are bonded to cellulose fibers via an ether bond, wherein the modified cellulose fibers have a cellulose I crystal structure. The modified cellulose fibers of the present invention have high dispersibility in the resin and can exhibit an effect of increasing strength, so that the modified cellulose fibers are suitable as various fillers, and the like, and the resin composition blended with the modified cellulose fibers can be suitably used in daily sundries, household electric appliance parts, wrapping materials for household electric appliance parts, automobile parts, resins for three-dimensional modeling, and the like.
Polyols suitable for hot molded foam production with high renewable resource content
Polyols are produced by an alkoxylation process in which a vegetable oil containing hydroxyl functional groups is combined with a DMC catalyst to form a mixture, the DMC catalyst is then activated by adding ethylene oxide and/or propylene oxide to the vegetable oil/catalyst mixture, and ethylene oxide and propylene oxide are added to the mixture containing activated DMC catalyst in amounts such that the total of percentage of ethylene oxide in the polyol plus percentage of primary hydroxyl groups in the polyol produced is from 50 to 77% and the percentage of primary hydroxyl groups is at least 30% but less than 50%. These polyols are useful for the production of molded polyurethane foams, particularly, hot-cure molded polyurethane foams.
PROCESSES AND PRODUCTION PLANTS FOR PRODUCING POLYMER POLYOLS
Processes for preparing a polymer polyol (PMPO) in which a base polyol is continuously produced in a continuous base polyol reactor, the base polyol is continuously discharged from the continuous base polyol reactor; the base polyol is continuously introduced to a continuous PMPO reactor, which is different from the continuous base polyol reactor, and PMPO is continuously removed from the PMPO reactor. Production plant configured to carry out such processes are also described.
Method for making propylene oxide/ethylene oxide copolymers using double metal cyanide catalysts, and copolymers so made
Random poly(propylene oxide-co-ethylene oxide) polymers are made by polymerizing a mixture of propylene oxide and a small amount of ethylene oxide in the presence of a starter and a double metal cyanide catalyst complex, and then feeding in a mixture of propylene oxide and ethylene oxide while increasing the ethylene oxide concentration in the mixture to at least 90%. This produces a polyol suitable for making high resiliency polyurethane foam without need for adding an ethylene oxide cap.
Additive to prevent phase separation of low profile additive in unsaturated thermoset polyester compositions
The present invention relates to an additive to prevent phase separation between a low profile additive and the other components of the molding composition, said other components comprising at least an unsaturated resin and an unsaturated monomer.
METHOD FOR PRODUCING POLYETHER CARBONATE POLYOLS
The present invention provides a process for preparing polyether carbonate polyols from H-functional starter substance, alkylene oxide and carbon dioxide in the presence of a DMC catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, wherein the carbon dioxide used has a purity of 99.5000% to 99.9449% by volume.
COATING FORMULATION WITH AN OPEN TIME ADDITIVE
The present invention relates to a coating composition which is a stable aqueous dispersion of polymer particles and a phenyl glycidyl ether adduct of maltodextrin. The composition of the present invention is useful for improving open time in coatings formulations.
Method for the production of polyether carbonate polyols and device therefor
The present invention relates to a method for producing polyether carbonate polyols by addition of one or more alkylene oxides and carbon dioxide to one or more H-functional starter substances in the presence of at least one DMC catalyst, in which the reaction is conducted in a main reactor (8) and a tubular reactor (11, 17) connected as a post reactor downstream thereof, wherein the method is characterized in that at the outlet (13) of the tubular reactor (11, 17) a temperature is set that is at least 10 C. above the temperature in the inside of the main reactor (8). The invention further relates to a device for carrying out said method.