A flexible substrate with a high optical transparency (>80% from 400 to 750 nm) that is retained after exposure to 300° C., near-zero birefringence (<±0.001), and a relatively low CTE (<60 ppm/° C.) is disclosed. The substrate may be manufactured as single layer, polyimide films and as a multi-layer laminate comprising a polyimide layer and a thin glass layer. The polyimides may include alicyclic dianhydrides and aromatic, cardo diamines. The films formed of the polyimides can serve as flexible substrates for optical displays and other applications that require their unique combination of properties.

The present invention relates to a pickering emulsion composition using polyimide particles and a method for preparing the same. The pickering emulsion stabilized by the polyimide particles according to the present invention has a very stable dispersed phase and does not cause flocculation, creaming, coalescence and phase separation even after a long time, and has an advantage of being capable of forming both an oil-in-water type emulsion and a water-in-oil type emulsion. Further, the polyimide particles used in the present invention can be synthesized in a simple manner and have partial wettability without the surface treatment and pH control so that they can be easily used for the emulsion stabilization.

The present disclosure provides a polyimide film having improved heat resistance and refractive index by using a polyimide precursor composition comprising a diamine of Chemical Formula 1 and an acid dianhydride of Chemical Formula 2 as polymerization components, thereby reducing the difference in refractive index from the upper layer to improve bottom emission efficiency.

The present disclosure relates to a polyimide-based resin film which is synthesized by the reaction of an acid anhydride compound having a specific structure and a diamine compound, thereby capable of ensuring excellent optical properties even under high temperature heat treatment conditions, and stably maintaining optical properties even during further heat treatment, a substrate for display device, and an optical device using the same.

A transparent and tint-free polyimide film, a preparation method thereof and an optical PI film are provided in the disclosure. The transparent and tint-free polyimide film not only has excellent light transmittance (≥85% @500 nm), but also has high modulus (tensile modulus≥3.8 GPa) and low coefficient of thermal expansion (≤30 ppm/Celsius, 50-200 Celsius) and other characteristics, so as to the transparent and tint-free polyimide film can meet the needs of flexible optoelectronic display devices.

In a first aspect, a single layer polymer film includes 60 to 99 wt % of a crosslinked polyimide, having a gel fraction in the range of from 20 to 100% and a refractive index of 1.74 or less, and 1 to 40 wt % of a colorant. A surface of the single layer polymer film has been textured and has a maximum roughness (S.sub.pv) of 6 μm or more, an L* color of 30 or less and a 60° gloss of 15 or less. In a second aspect, a coverlay for a printed circuit board includes the single layer polymer film of the first aspect. In third and fourth aspects, processes are disclosed for forming a single layer polymer film including a crosslinked polyimide film including a dianhydride and a diamine.

Provided is a liquid crystal alignment agent that makes it possible to obtain a liquid crystal alignment film having a superior balance among solvent resistance, liquid crystal alignment properties, and voltage holding ratio. The liquid crystal alignment agent contains a polymer [P] including: at least one ring structure of an oxetane ring and an oxirane ring; (B) a functional group that reacts with at least one of the oxetane ring and the oxirane ring by heating; and (C) an optically aligning group.

A polyimide of the present invention contains an alicyclic acid dianhydride, a fluorine-containing aromatic acid dianhydride and 3′,4,4′-biphenyl-tetracarboxylic acid dianhydride as acid dianhydrides, and contains 3,3′-diaminodiphenyl sulfone and a fluoroalkyl-substituted benzidine as diamines. A polyimide film of the present invention contains the polyimide resin. For example, the polyimide film is obtained by applying a polyimide solution, which is obtained by dissolving the polyimide resin in an organic solvent, onto a substrate, and removing the solvent.

A photoalignment agent is provided. The photoalignment agent includes a copolymer of ii) at least one of a cyclobutanedianhydride (CBDA) and a cyclobutanedianhydride (CBDA) derivative, and ii) a diamine, and the diamine includes an electron donor group.

According to one embodiment, a varnish for a photo alignment film includes an imidization promotor and a first polyamic acid-based compound in an organic solvent. The first polyamic acid-based compound is a polyamic acid or a polyamic acid ester. The imidization promotor has skeleton containing no primary amino group and no secondary amino group. The first polyamic acid-based compound has terminal skeletons containing no primary amino group.