A modified polysiloxane has formula (I) ##STR00001##
In formula (I) m is an integer between 0 and 10000; n is an integer between 0 and 10000; m and n cannot be equal to 0 simultaneously; R.sub.1-R.sub.7 are the same or different; and at least one of R.sub.1-R.sub.7 includes a group having a reversible chemical bond system based on a hydrogen bond, a coordinate bond, or a covalent bond. The polysioxane is used as a main chain to introduce a reversible chemical bond having temperature sensitivity by using a chemical method, so as to obtain a polymer material which is highly sensitive to temperature. The temperature-sensitive properties of materials provide functional materials for specific applications, such as medical external fixation materials, orthopedic materials, and packaging materials, can be obtained by using particular processing and preparation methods.

A modified polysiloxane has formula (I) ##STR00001##
In formula (I) m is an integer between 0 and 10000; n is an integer between 0 and 10000; m and n cannot be equal to 0 simultaneously; R.sub.1-R.sub.7 are the same or different; and at least one of R.sub.1-R.sub.7 includes a group having a reversible chemical bond system based on a hydrogen bond, a coordinate bond, or a covalent bond. The polysioxane is used as a main chain to introduce a reversible chemical bond having temperature sensitivity by using a chemical method, so as to obtain a polymer material which is highly sensitive to temperature. The temperature-sensitive properties of materials provide functional materials for specific applications, such as medical external fixation materials, orthopedic materials, and packaging materials, can be obtained by using particular processing and preparation methods.

A silirane-functionalized compound that consists of a substrate to which a least two silirane groups of the formula (1) are covalently bonded, a mixture containing the silirane-functionalized compounds, and a process for preparing siloxanes using the mixture are described herein.

Provided are fluorine-free, oleophobic layers including one more or polydimethylsiloxane resin layers. The layers can be disposed on a portion of or all of a surface of a substrate. Also provided are methods of making and using same.

Provided are fluorine-free, oleophobic layers including one more or polydimethylsiloxane resin layers. The layers can be disposed on a portion of or all of a surface of a substrate. Also provided are methods of making and using same.

Provided are fluorine-free, oleophobic layers including one more or polydimethylsiloxane resin layers. The layers can be disposed on a portion of or all of a surface of a substrate. Also provided are methods of making and using same.

The present invention pertains to a branched polymeric liquid poly siloxane material comprising non-organofunctional Q-type siloxane moieties and mono-organofunctional T-type siloxane moieties, as well as optionally tri-organofunctional M-type siloxane moieties and/or di-organofunctional D-type siloxane moieties characterized in that the polysiloxane material has a specified degree of polymerization, comprises a significant amount of four-membered Q2-type and/or Q3-type siloxane ring species relative to the total Q-type siloxane species, and is optionally functionalized at specific moieties. The present invention further pertains to methods for producing the polymeric liquid polysiloxane material as well as associated uses of the material.

A cosmetic ingredient for cosmetic products has a polymer structure which includes an emollient or film-forming cosmetic polymer which is transparent to light. An organic chromophore molecule is inserted and chemically linked into the polymer, which can be a fixed color molecule or a photochromic molecule capable of rapidly switching from one color to another. The colored or photochromic molecule is inserted and chemically linked by transesterification into a cosmetic oil provided with functionalities which are suitable for the chemical anchoring of the molecule and chemically linked to said oil. The cosmetic oil may be a silicone macrodiol functionalized with a photochromic derivative designed so as to ensure the transition between a colorless state and a colored state following irradiation with ultraviolet light.

A cosmetic ingredient for cosmetic products has a polymer structure which includes an emollient or film-forming cosmetic polymer which is transparent to light. An organic chromophore molecule is inserted and chemically linked into the polymer, which can be a fixed color molecule or a photochromic molecule capable of rapidly switching from one color to another. The colored or photochromic molecule is inserted and chemically linked by transesterification into a cosmetic oil provided with functionalities which are suitable for the chemical anchoring of the molecule and chemically linked to said oil. The cosmetic oil may be a silicone macrodiol functionalized with a photochromic derivative designed so as to ensure the transition between a colorless state and a colored state following irradiation with ultraviolet light.

A curable composition is disclosed. The curable composition comprises (I) an epoxide-functional silicone-acrylate polymer and (II) an aminosiloxane. The epoxide-functional silicone-acrylate polymer comprises acrylate-derived monomeric units comprising siloxane moieties, epoxide-functional moieties, and optionally, hydrocarbyl moieties, and the aminosiloxane comprises an average of at least two amine functional groups per molecule. A method of preparing the curable composition is also disclosed, and includes reacting (A) an acryloxy-functional organosilicon component, (B) an epoxy-functional acrylate component, and optionally (C) an acrylate component, to give the epoxide-functional silicone-acrylate polymer (I), and combining the epoxide-functional silicone-acrylate polymer (I) with the aminosiloxane (II). An aminosiloxane-silicone-acrylate copolymer prepared with the composition, a cured product comprising the same, and methods of preparing the same, are also disclosed.