A ceramic product includes a printed self-supporting three-dimensional ceramic structure formed by additive manufacturing. The printed self-supporting three-dimensional ceramic structure includes a pre-defined geometric arrangement of features having an average diameter in a range of greater than 50 nanometers to less than 1000 nanometers.

The present disclosure relates to a protective coating composition for a hard surface, wherein the composition comprises an organic solvent and a polysiloxane having the general formula (I), wherein: R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are independently an alkyl group having from 1 to 8 carbon atoms; Y and Z are independently a divalent linking group selected from the group consisting of urea, urethane, oxygen atom, sulfur atom and alkylene having from 1 to 8 carbon atoms; A, B, L and M are independently a divalent slinking group selected from the group consisting of alkylene having from 1 to 8 carbon atoms, with the proviso that if the combined linking groups formed by -A-Y-L- and -M-ZB are independently an alkylene, then the alkylene is independently different from ethylene; n is an integer from 5 to 1500; and m and p are independently an integer from 1 to 3. In another aspect, the present disclosure is directed to a method of reducing contamination from a hard surface.

The present disclosure relates to a protective coating composition for a hard surface, wherein the composition comprises an organic solvent and a polysiloxane having the general formula (I), wherein: R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are independently an alkyl group having from 1 to 8 carbon atoms; Y and Z are independently a divalent linking group selected from the group consisting of urea, urethane, oxygen atom, sulfur atom and alkylene having from 1 to 8 carbon atoms; A, B, L and M are independently a divalent slinking group selected from the group consisting of alkylene having from 1 to 8 carbon atoms, with the proviso that if the combined linking groups formed by -A-Y-L- and -M-ZB are independently an alkylene, then the alkylene is independently different from ethylene; n is an integer from 5 to 1500; and m and p are independently an integer from 1 to 3. In another aspect, the present disclosure is directed to a method of reducing contamination from a hard surface.

The present invention pertains to a polymeric liquid polysiloxane material comprising non-organofunctional Q-type siloxane moieties and optionally mono-organofunctional T-type siloxane moieties, for efficient rearrangement and curing reactions. The present invention further pertains to associated uses of the material.

The invention provides a hydrophilized carbosiloxane vinylic monomer which comprises (1) a poly(carbosiloxane) segment, (2) one sole ethylenically unsaturated group, and (3) at least one terminal or pendant group which is a hydrophilic group or hydrophilic polymer chain. The present invention is also related to a polymer, an actinically-crosslinkable silicone-containing prepolymer, a silicone hydrogel polymeric material, or a silicone hydrogel contact lens, which comprises monomeric units derived from a hydrophilized carbosiloxane vinylic monomer of the invention.

The invention provides a hydrophilized carbosiloxane vinylic monomer which comprises (1) a poly(carbosiloxane) segment, (2) one sole ethylenically unsaturated group, and (3) at least one terminal or pendant group which is a hydrophilic group or hydrophilic polymer chain. The present invention is also related to a polymer, an actinically-crosslinkable silicone-containing prepolymer, a silicone hydrogel polymeric material, or a silicone hydrogel contact lens, which comprises monomeric units derived from a hydrophilized carbosiloxane vinylic monomer of the invention.

The invention provides a hydrophilized polydiorganosiloxane vinylic crosslinker which comprises (1) a polydiorganosiloxane polymer chain comprising dimethylsiloxane units and hydrophilized siloxane units each having one methyl substituent and one monovalent C.sub.4-C.sub.40 organic radical substituent having two to six hydroxyl groups, wherein the molar ratio of the hydrophilized siloxane units to the dimethylsiloxane units is from about 0.035 to about 0.15, and (2) two terminal (meth)acryloyl groups. The hydrophilized polydiorganosiloxane vinylic crosslinker has a number average molecular weight of from about 3000 Daltons to about 80,000 Daltons. The present invention is also related to a silicone hydrogel contact lens, which comprises repeating units derived from a hydrophilized polydiorganosiloxane vinylic crosslinker of the invention.

The invention provides a hydrophilized polydiorganosiloxane vinylic crosslinker which comprises (1) a polydiorganosiloxane polymer chain comprising dimethylsiloxane units and hydrophilized siloxane units each having one methyl substituent and one monovalent C.sub.4-C.sub.40 organic radical substituent having two to six hydroxyl groups, wherein the molar ratio of the hydrophilized siloxane units to the dimethylsiloxane units is from about 0.035 to about 0.15, and (2) two terminal (meth)acryloyl groups. The hydrophilized polydiorganosiloxane vinylic crosslinker has a number average molecular weight of from about 3000 Daltons to about 80,000 Daltons. The present invention is also related to a silicone hydrogel contact lens, which comprises repeating units derived from a hydrophilized polydiorganosiloxane vinylic crosslinker of the invention.

A high refractive index molecule and high refractive index polymers comprising such monomers. The high refractive index monomer comprises a carrier atom having a high refractive index group attached thereto, the high refractive index group comprising a heterocyclic compound comprising at least one sulfur atom.

A high refractive index molecule and high refractive index polymers comprising such monomers. The high refractive index monomer comprises a carrier atom having a high refractive index group attached thereto, the high refractive index group comprising a heterocyclic compound comprising at least one sulfur atom.