Synthesis of organyloxyfunctional organosilicon compounds is facilitated by a two-step process using a basic lithium, guanidine or amidine catalyst in the first step, and a phosphorus compound having a PO linkage in a second step.

Synthesis of organyloxyfunctional organosilicon compounds is facilitated by a two-step process using a basic lithium, guanidine or amidine catalyst in the first step, and a phosphorus compound having a PO linkage in a second step.

A fluorinated compound having at least one (meth)acrylate functional group disclosed. A curable composition comprising the fluorinated compound and polyfunctional acrylate, a cured product formed from the curable composition, and method of forming the cured product are also disclosed.

A fluorinated compound having at least one (meth)acrylate functional group disclosed. A curable composition comprising the fluorinated compound and polyfunctional acrylate, a cured product formed from the curable composition, and method of forming the cured product are also disclosed.

An object is to provide a polydimethylsiloxane-containing monomer that exhibits satisfactory compatibility with a hydrophilic monomer and a hydrophilic polymer, in which a polymerization product obtained by polymerizing a composition including the polydimethylsiloxane-containing monomer, the hydrophilic monomer, and the hydrophilic polymer has an anti-lipid adhesion property. It has been recognized that a polydimethylsiloxane-containing monomer having a phosphorylcholine group and a hydroxy group can achieve the object, and thus the present disclosure has been completed.

Methods and formulations for modified silicone resins of Formula (I) are presented: ##STR00001##
The R.sup.1, R.sup.2, and R.sup.3 are each independently selected from a group consisting of H, alkyl, alkenyl, alkynyl, and aryl; n ranges from 1 to 10; m ranges from 1 to 200; and p ranges from 2 to 1,000. The elastomeric materials prepared from modified silicone resins display robust mechanical properties following prolonged exposure to high temperatures (e.g., 316 C. or higher).

Methods and formulations for modified silicone resins of Formula (I) are presented: ##STR00001##
The R.sup.1, R.sup.2, and R.sup.3 are each independently selected from a group consisting of H, alkyl, alkenyl, alkynyl, and aryl; n ranges from 1 to 10; m ranges from 1 to 200; and p ranges from 2 to 1,000. The elastomeric materials prepared from modified silicone resins display robust mechanical properties following prolonged exposure to high temperatures (e.g., 316 C. or higher).

Methods and formulations for modified silicone resins of Formula (I) are presented:

##STR00001##

The R.sup.1, R.sup.2, and R.sup.3 are each independently selected from a group consisting of H, alkyl, alkenyl, alkynyl, and aryl; n ranges from 1 to 10; m ranges from 1 to 200; and p ranges from 2 to 1,000. The elastomeric materials prepared from modified silicone resins display robust mechanical properties following prolonged exposure to high temperatures (e.g., 316 C. or higher).

Methods and formulations for modified silicone resins of Formula (I) are presented:

##STR00001##

The R.sup.1, R.sup.2, and R.sup.3 are each independently selected from a group consisting of H, alkyl, alkenyl, alkynyl, and aryl; n ranges from 1 to 10; m ranges from 1 to 200; and p ranges from 2 to 1,000. The elastomeric materials prepared from modified silicone resins display robust mechanical properties following prolonged exposure to high temperatures (e.g., 316 C. or higher).

Disclosed is a hydrophilic silicone composition comprising an oral care substance. The composition is based on polysiloxanes having a high water-uptake capability. An aqueous solution or dispersion of the oral care substance can be soaked into the polysiloxane, whereby the resulting composition shows favorable release characteristics. The use of hydrophilically modified polysiloxanes, possibly in conjunction with unmodified hydrophobic polysiloxanes, allows for the convenient production of desired shapes, advantageously based on a dental imprint. The hydrophilic modification of the polysiloxane is particularly by including a hydrophilic vinyl monomer, particularly an alpha-olefinic soap, into the composition prior to curing.