A method of forming a polymer comprising a conjugated backbone and side-groups pendant from the conjugated backbone wherein the method comprises the steps of: polymerizing one or more monomers to form a precursor polymer comprising the conjugated backbone and precursor groups pendant from the conjugated backbone, and subsequently converting the precursor groups to the side-groups.

The present disclosure provides enynes, end-functionalized polymers, conjugates, methods of preparation, compositions, kits, and methods of use. The conjugates comprise at least (1) a peptide (e.g., an antibody), protein, nucleoprotein, mucoprotein, lipoprotein, glycoprotein, or polynucleotide; and (2) a polymer comprising a pharmaceutical agent. The conjugates may be useful in delivering (e.g., targeted delivering) the pharmaceutical agent to a subject in need thereof or cell or treating, preventing, or diagnosing a disease.

A polymer including a structural unit represented by the following formula (A). In the formula (A), P is independently a group represented by the following formula (P), a is an integer of 2 to 5, and b is an integer of 0 to 5. In the formula (P), A is independently a nitrogen atom or CR; X is a single bond, O, S, C(R).sub.2 or NR. R is independently a hydrogen atom, a substituted or unsubstituted alkyl group including 1 to 20 carbon atoms or the like, or a single bond used for bonding to another P or L, provided that at least one R contained in (P)a is represented by any one of the following formulas (3) to (7). ##STR00001##

1) Hydrocarbon-based polymer of formula (I):

##STR00001## in which F.sup.1 and F.sup.2 have the respective formulae (IIa) and (IIb) or (IIa) and (IIb):

##STR00002## a process for its preparation, and use as an adhesive.

Described herein, inter alia, are compositions of cell penetrating high density brush peptide polymer, drug delivery vehicles for delivering cell penetrating peptides and drugs. Also provided is a methodology for protecting active peptides from proteolysis by packaging them into high-density brush polymers via ring opening metathesis polymerization (ROMP), using an easily-prepared catalyst initiator. The graft-through polymerization of norbomyl-peptide monomers via ROMP can result in structures that resist proteolysis relative to their monomeric analogues in a manner dependent on their degree of polymerization (REFS). Polymerized peptides, while protected from proteolysis, maintain their intended biological function and are capable of any of the functions inherent to the peptide, such as binding a receptor or ligand, initiating a signaling pathway, penetrating a cell, or inducing a therapeutic effect.

Embodiments of the invention include methods and materials for preparing organic semiconducting layers, for example one used in an organic semiconductor device including a substrate with a nanostructured surface and an organic semiconductor film overlying the nanostructured surface. The semiconductor film is typically formed from macroscopically ordered polymer fibers made from selected conjugate polymer compounds. Such polymer fibers synthesized from selected conjugated polymer compounds and directionally aligned in organic semiconductor devices can provide these devices improved functional properties, including for example, unexpectedly high field effect saturation mobilities.

A method of forming a polymer comprising a conjugated backbone and side-groups pendant from the conjugated backbone wherein the method comprises the steps of: polymerising one or more monomers to form a precursor polymer comprising the conjugated backbone and precursor groups pendant from the conjugated backbone, and subsequently converting the precursor groups to the side-groups.

A method of fabricating an organic field effect transistor (OFET), including forming a source contact, a drain contact, and a gate connection to a channel comprising semiconducting polymers, wherein the gate connection applies a field to the semiconductor polymers across a dielectric layer to modulate conduction along the semiconducting polymers between the source contact and the drain contact; and treating the semiconducting polymers, wherein the treating includes a chemical treatment that controls a carrier density, carrier mobility, threshold voltage, and/or contact resistance of the OFET.

The present invention relates to a methoxyaryl surface modifier. In addition the present invention also relates to organic electronic devices comprising such methoxyaryl surface modifier.

Provided is a polymer comprising: a first unit represented by Chemical Formula 1; a second unit represented by Chemical Formula 1 and different from the first unit; a third unit represented by Chemical Formula 2; and an end group represented by Chemical Formula 3, and an organic light emitting device using the same,

##STR00001## wherein all the variables are described herein.