Aspects of the present disclosure generally describe polyarylether ketones and methods of use. In some aspects, a composition includes one or more polymers of formulae (I), (II), or (III):

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A high molecular weight compound according to the present invention includes a substituted triarylamine structural unit represented by a general formula (1) below, ##STR00001## where Ar.sup.1 and Ar.sup.2 are a divalent aromatic hydrocarbon group or a divalent aromatic heterocyclic group, R.sup.1 and R.sup.2 represent a hydrogen atom, a heavy hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, a nitro group, an alkyl group, a cycloalkyl group, an alkenyl group, an alkyloxy group, or a cycloalkyloxy group, X, Y and Z are, on the condition that at least one of them is an aryl group or a heteroaryl group, an aryl group, a heteroaryl group, or a group similar to the groups represented by R.sup.1 and R.sup.2 above.

The invention relates to a blend containing an electron acceptor and an electron donor, the acceptor being an n-type semiconductor which is a small molecule that does not contain a fullerene moiety, the electron donor being a p-type semiconductor which is a conjugated polymer comprising donor and acceptor units in random sequence, to a formulation containing such a blend, to the use of the blend in organic electronic (OE) devices, especially organic photovoltaic (OPV) devices, perovskite-based solar cell (PSC) devices, organic photodetectors (OPD) and organic light emitting diodes (OLED), and to OE, OPV, PSC, OPD and OLED devices comprising the blend.

Disclosed is a graft copolymer containing a polyfluorene-based polymer as a main chain and a polyvinylidene fluoride (PVDF) as a side chain, and an element including the same. The graft copolymer contains both the polyfluorene-based polymer and the PVDF, so that the graft copolymer may increase miscibility between polymers to prepare a composite having excellent performance, prepare an uniform thin film through a solution process, and be used as a single material that exhibits both piezoelectric properties and luminescence properties.

A polymer for organic electroluminescent devices having high luminous efficiency and applicable to a wet process is provided. This polymer for organic electroluminescent devices is characterized in that it includes a polymer of a polyphenylene main chain represented by General Formula (1) which is used in at least one layer of an organic layer in an organic electroluminescent device formed by laminating an anode, the organic layer, and a cathode on a substrate, and which has thermally activated delayed fluorescence characteristics (TADF characteristics) (where x is a phenylene group or a linked phenylene group, L is a single bond, an aromatic hydrocarbon group, or an aromatic heterocyclic group, and A is an aromatic hydrocarbon group, an aromatic heterocyclic group, or a linked aromatic group, and satisfies S1(A)−T1(A)≤0.50 (eV)).

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An object is to provide a cured product having excellent heat resistance and dielectric properties (low dielectric properties) and prepregs, circuit boards, build-up films, semiconductor sealing materials, and semiconductor devices having these pieces of performance by using a curable resin having a specific structure. Specifically, provided is a curable resin having a structural unit (1) represented by General Formula (1) below and a terminal structure (2) represented by General Formula (2) below. In Formulae (1) and (2) above, the details of R.sub.1, R.sub.2, R.sub.3, k, and X are as described herein.

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Disclosed is a graft copolymer containing a polyfluorene-based polymer as a main chain and a polyvinylidene fluoride (PVDF) as a side chain, and an element including the same. The graft copolymer contains both the polyfluorene-based polymer and the PVDF, so that the graft copolymer may increase miscibility between polymers to prepare a composite having excellent performance, prepare an uniform thin film through a solution process, and be used as a single material that exhibits both piezoelectric properties and luminescence properties.

The invention provides for polymer structures and their preparation and resulting novel functionalities including open-shell character and high intrinsic conductivity with wide-range tenability. Electrical conductivity can be further modulated by introducing or blending with materials, fillers, dopants, and/or additives. The materials or resultant composites of the invention can be processed by various techniques into different forms to realize multiple applications.

1) Hydrocarbon-based copolymer comprising two end groups preceded by an ester function and chosen from a 2-oxo-1,3-dioxolan-4-yl (or cyclocarbonate), a dithiocyclocarbonate, an exo-vinylene cyclocarbonate and a 2-oxo-1,3-dioxolen-4-yl, the main chain of which comprises units (I) and (II) ##STR00001## in which R.sup.0 is notably a methyl radical; and the number-average molecular mass Mn of which is between 400 and 100 000 g/mol. 2) Process for preparing said copolymer, comprising: (i) a step of heating a statistical bipolymer A chosen from a poly(butadiene-isoprene), a poly(butadiene-myrcene) and a poly(butadiene-farnesene); and then (ii) a step of heating the product formed, in the presence of a chain-transfer agent. 3) Use as adhesive, as a mixture with an amine compound comprising at least two amine groups.

[Object] To provide a polymer material having excellent hole injection/transport performance, electron blocking capability, high heat resistance, and high stability in a thin-film state for use in a polymer organic EL device, and provide an organic EL device having a low drive voltage, high light emission efficiency, and a long lifetime using this polymer material.

[Solving Means] A compound according to the present invention is a high-molecular-weight compound having at least one substituted triarylamine structural unit represented by the following general formula (1), further including a structural unit having at least one aromatic hydrocarbon ring or a structural unit having a triarylamine skeleton in addition to the at least one substituted triarylamine structural unit, and having a weight average molecular weight of 10,000 or more and 1,000,000 or less in terms of polystyrene and no a crosslinker, characterized in that the high-molecular-weight compound is used in an organic EL device as a constituent material of at least one organic layer.

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