The invention provides compositions comprising crosslinkable BCB-functionalized materials for use in OLEDs applications. The inventive compositions can be used to form hole-transporting materials for use in electroluminescent devices. In particular, the invention provides a composition comprising at least one compound selected from Structure A, as described herein.

##STR00001##

A polymer comprising units α, β, γ and δ wherein: unit α is present at 30 mole % to 60 mole % and is an optionally substituted arylene; unit β is present at 1 mole % to 30 mole % and is a unit comprising an optionally substituted fluorene; unit γ is present at 1 mole % to 40 mole % and comprises aryl substituted nitrogen, or an optionally substituted triazine; unit δ is present at 0.5 mole % to 15 mole % and comprises an iridium complex; and optionally up to 20 mole % of other units if the total of α, β, γ and δ is less than 100 mole %.

A light-emitting device having an anode, a cathode, a first organic layer disposed between the anode and the cathode, and a second organic layer disposed between the anode and the first organic layer and adjacent to the first organic layer is provided. The first organic layer contains a phosphorescent compound of formula (1), and the second organic layer contains a crosslinked body formed from a polymer compound having a crosslinkable group in which the average number of the crosslinkable groups in the polymer compound per molecular weight of 1000 is at least 0.5.

Composition for use in an organic light-emitting device, the composition having a fluorescent light-emitting material and a triplet-accepting material subject to the following energetic scheme: 2×T.sub.1A>S.sub.1A>S.sub.1E, or T.sub.1A+T.sub.1E>S.sub.1A>S.sub.1E in which: T1A represents a triplet excited state energy level of the triplet-accepting material; TIE represents a triplet excited state energy level of the light-emitting material; S.sub.1A represents a singlet excited state energy level of the triplet-accepting material; and S.sub.1E represents a singlet excited state energy level of the light-emitting material; and in which light emitted by the composition upon excitation includes delayed fluorescence.

A high molecular weight compound according to the present invention includes a substituted triarylamine structural unit represented by the following general formula (1), ##STR00001## where AR.sup.1, AR.sup.2, and L each independently represent a divalent aromatic hydrocarbon group or a divalent aromatic heterocyclic group, n is an integer of 1 to 3, Ar.sub.1 and Ar.sub.2 each independently represent an aryl group or a heteroaryl group, and R.sub.1, R.sub.2, and R.sub.3 each independently represent a hydrogen atom, a heavy hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, a nitro group, an alkyl group having 1 to 6 carbon atoms, an alkyloxy group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 10 carbon atoms, a cycloalkyloxy group having 5 to 10 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, an aryloxy group, or a heteroaryl group.

A polymer comprising repeat units of formula (I) and one or more co-repeat units: ##STR00001## Ar.sup.1 in each occurrence independently represent an aryl or heteroaryl group; R.sup.1 and R.sup.2 in each occurrence independently represent a substituent; p independently in each occurrence is 0 or a positive integer; Sp represents a spacer group comprising at least one carbon or silicon atom spacing the two groups Ar.sup.1 apart; and each group Ar.sup.1 is bound to an aromatic group of a co-repeat unit. The polymer may form a charge-transporting layer of an OLED or may be a host material used with a luminescent dopant in a light-emitting layer of an OLED.

Aspects of the present disclosure generally describe polyarylether ketones and methods of use. In some aspects, a composition includes one or more polymers of formulae (I), (II), or (III):

##STR00001##

A polymer comprising an optionally substituted repeat unit of formula (I): wherein R.sup.1 and R.sup.2 in each occurrence are independently selected from H or a substituent; R.sup.1 and R.sup.2 may be linked to form a ring; and A is an optionally substituted linear, branched or cyclic alkyl group. ##STR00001##

An organic electronic material containing a charge transport compound having a structural region represented by formula (I) and having a weight average molecular weight greater than 40,000.
—Ar—X—Y—Z  (I)
In the formula, Ar represents an arylene group or heteroarylene group of 2 to 30 carbon atoms, X represents a linking group, Y represents an aliphatic hydrocarbon group of 1 to 10 carbon atoms, and Z represents a substituted or unsubstituted polymerizable functional group.

An organic electronic material including a charge transporting polymer having a structure that is represented by Formula (1) and that is branched in three or more directions (in the formula, Rf's are each independently a fluoroalkyl group, a and b are 0 or 1, and a and b are not both 0 at the same time).