The invention relates to new conjugated semiconducting polymers containing thermally cleavable side groups. The thermally cleavable side groups are selected from among carbonate groups and carbamate groups, By thermally cleaving side groups, the solubility or the polymers can he reduced in a targeted manner. The polymers are used as semiconductors in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices, organic photodetectors (OPDs), organic light emitling diodes (OLEDs), and organic field effect transistors (OFETs).

An organic solar cell is provided. The organic solar cell includes a photoactive layer in which a low molecular weight conjugated compound as a first organic semiconductor material is mixed with an appropriate amount of a second organic semiconductor material. The first organic semiconductor material includes both electron donors and electron acceptors. The presence of the electron donors and the electron acceptors in the first organic semiconductor material improves the morphology of the photoactive layer, leading to high efficiency of the organic solar cell.

The present specification provides a copolymer and an organic solar cell including the same.

An object is to provide an organic semiconductor element having excellent carrier mobility and heat resistance of a semiconductor active layer, an organic semiconductor composition for obtaining this element, an organic semiconductor film, and a method of manufacturing an organic semiconductor element in which the composition is used, and another object is to provide a compound and an oligomer or a polymer that are suitably used in the organic semiconductor element, the organic semiconductor composition, the organic semiconductor film, and the method of manufacturing an organic semiconductor element.

The organic semiconductor element of the present invention includes a compound represented by Formula 1 below in a semiconductor active layer. In Formula 1, X represents a chalcogen atom, p and q each independently represent an integer of 0 to 2, and R.sup.1 and R.sup.2 each independently represent a halogen atom or a group represented by Formula W below.

##STR00001##

The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula (I), and compounds of formula (III), wherein Y, Y.sup.15, Y.sup.16 and Y.sup.17 are independently of each other a group of formula and their use as IR absorber, organic semiconductor in organic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers and compounds according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers and compounds according to the invention are used in organic field effect transistors, organic photovoltaics and photodiodes. ##STR00001##

The present specification provides a copolymer and an organic solar cell including the same.

The present invention relates to copolymers containing indenocarbazole derivatives having electron- and hole-transporting properties, in particular for use in the interlayer, emission layer and/or charge-transport layer of electroluminescent devices. The invention furthermore relates to a process for the preparation of the compounds according to the invention and to electronic devices comprising these compounds.

The present invention provides: a p-type organic semiconductor material which is able to be produced easily, while having high planarity in a polymer skeleton; and a photoelectric conversion layer, a photoelectric conversion element and an organic thin film solar cell, each of which uses this p-type organic semiconductor material and has high photoelectric conversion efficiency. The present invention specifically provides: a picene derivative which has at least one constituent unit represented by general formula (1); and a photoelectric conversion element which contains (A) the picene derivative serving as a p-type organic semiconductor material and (B) an n-type organic semiconductor material. The details of general formula (1) are as set forth in the description.

There is a conjugated polymer having a derivative of indacen-4-one having general formula (I): ##STR00001## wherein: R.sub.1 and R.sub.2, same or different, are selected from C.sub.1-C.sub.30 alkyl groups, linear or branched; optionally substituted cycloalkyl groups; optionally substituted aryl groups; optionally substituted heteroaryl groups; C.sub.1-C.sub.30 alkoxyl groups, linear or branched; R.sub.4—O—[CH.sub.2—CH.sub.2—O].sub.m— polyoxyethylene groups, wherein R.sub.4 is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched, and m is an integer ranging from 1 to 4; —R.sub.5—OR.sub.6 groups, wherein R.sub.5 is selected from C.sub.1-C.sub.30 alkylene groups, linear or branched, and R.sub.6 represents a hydrogen atom or is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched, or is selected from R.sub.4—[—OCH.sub.2—CH.sub.2—].sub.p— polyoxyethylene groups, wherein R.sub.4 has the same meanings as reported above and p is an integer ranging from 1 to 4; —COR.sub.7 groups, wherein R.sub.7 is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched; —COOR.sub.8 groups, wherein R.sub.8 is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched; or they represent a —CHO group or a cyano (—CN) group; R.sub.3 is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched; optionally substituted cycloalkyl groups; optionally substituted aryl groups; and C.sub.1-C.sub.30 alkoxyl groups, linear or branched; n is an integer ranging from 10 to 500. There is also a photovoltaic device (or solar device) having a support having the conjugated polymer having a derivative of indacen-4-one.

The present invention relates to new semiconducting compounds having at least one optionally substituted azino[1,2,3]thiadiazole moiety. The compounds disclosed herein can exhibit high carrier mobility and/or efficient light absorption/emission characteristics, and can possess certain processing advantages such as solution-processability and/or good stability at ambient conditions.