The present invention discloses a conjugated polymer, which is a random copolymer, and with Formula I: ##STR00001##
Additionally, the present invention also discloses an organic photovoltaic device comprising the conjugated polymer.

A semiconductor mixed material comprises an electron donor, a first electron acceptor and a second electron acceptor. The first electron donor is a conjugated polymer. The energy gap of the first electron acceptor is less than 1.4 eV. At least one of the molecular stackability, π-π* stackability, and crystallinity of the second electron acceptor is smaller than the first electron acceptor. The electron donor system is configured to be a matrix to blend the first electron acceptor and the second electron acceptor. The present invention also provides an organic electronic device including the semiconductor mixed material.

A method of forming a polymer, the method begins by combining 4,7-bis(5-bromo-4-alkylthiophen-2-yl)-5-chloro-6-fluorobenzo[c][1,2,5]thiadiazole, [4-alkyl-5-[5-(trimethylstannyl)thiophen-2-yl]thiophen-2-yl]trimethylstannane, (3,3′-difluoro-[2,2′-bithiophene]-5,5′-diyl)bis(trimethylstannane), Pd.sub.2dba.sub.3 and P(o-tol).sub.3 to form the polymer: ##STR00001##
In this polymer R.sub.1 and R.sub.2 are independently selected from the group consisting of a straight-chain or branched carbyl, silyl, or hydrocarbyl, a branched or cyclic alkyl with 1 to 30 atoms, a fused substituted aromatic ring, and a fused unsubstituted aromatic ring; and the ratio of x is between 0.6 to 0.8 and y is between 0.2 and 0.4.

Resins comprising nanoparticles formed from π-conjugated cross-linked polymers are disclosed, together with their methods of manufacture and their applications in light emitting devices.

The present specification relates to a polymer including a first unit of Chemical Formula 1; a second unit of Chemical Formula 2; and a third unit of Chemical Formula 3 or 4, and an organic solar cell including the same.

The present application relates to an electrochromic composite, an electrochromic device comprising the same, and a method for manufacturing an electrochromic device.

Black-to-transmissive electrochromic polymers have superior properties such as absorbance of across the entire visible spectrum and an obvious color change from black to transmissive with an applied voltage. Methods for synthesizing or using the same include contacting monomers under polymerization conditions. Black-to-transmissive electrochromic polymer thin films include the black-to-transmissive electrochromic polymers, and electrochromic devices include the black-to-transmissive electrochromic polymers or thin films.

A random copolymer comprising the monomer units A, B and C. In this random copolymer A comprises

##STR00001##

B comprises

##STR00002##

and C comprises an aryl group. Additionally, R1 R2, R3 and R4 are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups. X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups.

A random copolymer comprising the monomer units A, B and C. In this random copolymer A comprises

##STR00001##

B comprises

##STR00002##

and C comprises an aryl group. Additionally, R1 R2, R3 and R4 are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups. X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups.

A random copolymer comprising the monomer units A, B and C. In this random copolymer A comprises

##STR00001##

B comprises

##STR00002##

and C comprises an aryl group. Additionally, R1 R2, R3 and R4 are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups. X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups.