There is provided p-type organic polymers of general formula I. The polymers may be useful as semi-conducting material. Thus, thin films and devices comprising such polymers are also provided.

A polymer compound comprising a structural unit represented by the formula (1): ##STR00001##
wherein Ring A and Ring B represent each independently a heterocyclic ring, and the heterocyclic ring may have a substituent, Ring C represents an aromatic hydrocarbon ring obtained by condensing two or more benzene rings, the aromatic hydrocarbon ring has at least one of an alkyl group, an alkoxy group, an alkylthio group, an amino group or a hydroxyl group, and these groups may have a substituent, Z.sup.1 and Z.sup.2 represent each independently a group represented by the formula (Z-1), a group represented by the formula (Z-2), a group represented by the formula (Z-3), a group represented by the formula (Z-4) or a group represented by the formula (Z-5), ##STR00002##
wherein R represents an alkyl group, an alkoxy group, an alkylthio group, an aryl group or a mono-valent heterocyclic group, and these groups may have a substituent, and when there exist a plurality of R, these may be the same or different.

An organic compound, a donor-acceptor conjugated polymer, a formulation and a thin film, wherein a solution of the donor-acceptor conjugated polymer exhibits a peak optical absorption spectrum red shift of at least 100 nm when the donor-acceptor conjugated polymer solution is cooled from 140° C. to room temperature.

The invention relates to new conjugated semiconducting polymers containing thermally cleavable side groups. The thermally cleavable side groups are selected from among carbonate groups and carbamate groups, By thermally cleaving side groups, the solubility or the polymers can he reduced in a targeted manner. The polymers are used as semiconductors in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices, organic photodetectors (OPDs), organic light emitling diodes (OLEDs), and organic field effect transistors (OFETs).

An organic solar cell is provided. The organic solar cell includes a photoactive layer in which a low molecular weight conjugated compound as a first organic semiconductor material is mixed with an appropriate amount of a second organic semiconductor material. The first organic semiconductor material includes both electron donors and electron acceptors. The presence of the electron donors and the electron acceptors in the first organic semiconductor material improves the morphology of the photoactive layer, leading to high efficiency of the organic solar cell.

The present specification provides a copolymer and an organic solar cell including the same.

The present invention provides: a p-type organic semiconductor material which is able to be produced easily, while having high planarity in a polymer skeleton; and a photoelectric conversion layer, a photoelectric conversion element and an organic thin film solar cell, each of which uses this p-type organic semiconductor material and has high photoelectric conversion efficiency. The present invention specifically provides: a picene derivative which has at least one constituent unit represented by general formula (1); and a photoelectric conversion element which contains (A) the picene derivative serving as a p-type organic semiconductor material and (B) an n-type organic semiconductor material. The details of general formula (1) are as set forth in the description.

There is a conjugated polymer having a derivative of indacen-4-one having general formula (I): ##STR00001## wherein: R.sub.1 and R.sub.2, same or different, are selected from C.sub.1-C.sub.30 alkyl groups, linear or branched; optionally substituted cycloalkyl groups; optionally substituted aryl groups; optionally substituted heteroaryl groups; C.sub.1-C.sub.30 alkoxyl groups, linear or branched; R.sub.4—O—[CH.sub.2—CH.sub.2—O].sub.m— polyoxyethylene groups, wherein R.sub.4 is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched, and m is an integer ranging from 1 to 4; —R.sub.5—OR.sub.6 groups, wherein R.sub.5 is selected from C.sub.1-C.sub.30 alkylene groups, linear or branched, and R.sub.6 represents a hydrogen atom or is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched, or is selected from R.sub.4—[—OCH.sub.2—CH.sub.2—].sub.p— polyoxyethylene groups, wherein R.sub.4 has the same meanings as reported above and p is an integer ranging from 1 to 4; —COR.sub.7 groups, wherein R.sub.7 is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched; —COOR.sub.8 groups, wherein R.sub.8 is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched; or they represent a —CHO group or a cyano (—CN) group; R.sub.3 is selected from C.sub.1-C.sub.30 alkyl groups, linear or branched; optionally substituted cycloalkyl groups; optionally substituted aryl groups; and C.sub.1-C.sub.30 alkoxyl groups, linear or branched; n is an integer ranging from 10 to 500. There is also a photovoltaic device (or solar device) having a support having the conjugated polymer having a derivative of indacen-4-one.

The present invention relates to new semiconducting compounds having at least one optionally substituted azino[1,2,3]thiadiazole moiety. The compounds disclosed herein can exhibit high carrier mobility and/or efficient light absorption/emission characteristics, and can possess certain processing advantages such as solution-processability and/or good stability at ambient conditions.

An organic photoelectric conversion device having an anode, a cathode, an active layer disposed between the anode and the cathode, and a hole injection layer disposed between the anode and the active layer, wherein the anode is an electrode containing an electrically conductive nanosubstance and the hole injection layer is a layer showing a of 80% or more in measurement of the residual film rate after a water rinse treatment.