Disclosed is a fluorine-substituted Pi(π)bridge selenide polymer acceptor material, its preparation and application. The selenide polymer acceptor material is named PYSe2FT and is synthesized by Knoevenagel condensation reaction and Still cross-coupling reaction; the material PYSe2FT takes a selenium-substituted core donor unit as a main structure, and combines a difluoro-substituted thiophene π-electronic connection unit, where the selenium-substituted core donor unit and the difluoro-substituted thiophene π-electronic connection unit can effectively regulate and control the molecular energy level, so that molecules generate good accumulation, thus making PYSe-2FT an excellent polymer acceptor material.

This disclosure relates generally to electrochromic polymers that include a plurality of π-conjugated chromophores in spaced relation with one another, and a plurality of conjugation-break spacers (CBSs), where at least one CBS separates adjacent chromophores. The chromophores may be colored in the neutral state, and multicolored to transmissive in different oxidization states.

The invention relates to novel conjugated polymers containing one or more 5,6-difluoro-benzo[1,2,5]thiadiazole-4,7-diylunits (hereinafter referred to as “FF-BTZ” units) and two or more different bridged bithiophene units, to methods for their preparation and educts or intermediates used therein, to polymer blends, mixtures and formulations containing them, to the use of the polymers, polymer blends, mixtures and formulations as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising, or being prepared from, these polymers, polymer blends, mixtures or formulations.

The present application can provide a preparation method that can effectively produce a polymer having desired molecular weight characteristics and solubility in a solvent, and having a monomer composition, which is designed freely and variously according to the purpose, without unnecessary components with excellent polymerization efficiency and conversion rates, and a dispersion comprising the polymer formed by the preparation method.

The present disclosure presents a disulfide containing monomer, its reduced form, its derivative, the synthesis method of this disulfide containing monomer, and the polymer containing the monomers disclosed thereof

Provided are a polymer semiconductor including a first structural unit represented by Chemical Formula 1 and a second structural unit represented by Chemical Formula 2, a stretchable polymer thin film including the same, and an electronic device. ##STR00001## Definitions of Chemical Formulas 1 and 2 are as described in the detailed description.

A method for manufacturing an electrolytic capacitor is provided. A conductive polymer solution is applied onto a porous main body. The porous main body includes a porous electrode body having an electrode material and a dielectric layer covering an outer surface of the electrode material. The conductive polymer solution contains conductive polymer particles whose average particle size ranges from 0.5 nm to 50 nm. A solid electrolyte is formed to completely or partially cover a surface of the dielectric layer. A material of the conductive polymer particles includes at least one of polythiophene having at least one sulfonic acid group and polyselenophene having at least one sulfonic acid group. An electrical conductivity of a dry membrane formed from the conductive polymer particles is higher than 25 S/cm. An amount of metal cations in the conductive polymer solution is less than 500 mg/kg.

In an embodiment, a composition is provided that includes an indenofluorene moiety; an alkyl radical, an aryl radical, or a heteroaryl radical chemically bound to the indenofluorene moiety; and an electron donor moiety bound to the indenofluorene moiety. In another embodiment, a device is provided that includes compositions described herein. In another embodiment, a method of forming a donor-acceptor small molecule or a donor-acceptor copolymer is provided that includes forming an indenofluorene moiety; forming an electron donor moiety; and reacting the indenofluorene moiety with the electron donor moiety in a cross-coupling reaction.

An electrochromic polymer is comprised of a repeat unit comprising one or more meta-conjugated linkers (MCLs) and one or more aromatic moieties (Ars). Each of the one or more MCLs is partially conjugated with the one or more Ars at meta positions of the MCLs to form a polymer backbone of the electrochromic polymer. The electrochromic polymer undergoes an optical switching and a color change in an electrochromic device, which shows a high transparency and a high optical contrast.

A thermally stable and solvent resistant conductive polymer composite and its manufacturing friendly preparation method are disclosed. The disclosed composite presents great electrical conductivity with thermal stability and solvent resistance. A method of mixing a host thiophene conjugated polymer and a crosslinkable silane precursor simultaneously introduces both dopant and rigid cross-linked siloxane network into polymer system. The thin film made by the disclosed thermally stable and solvent resistant conductive polymer composite can be applied to fabricate various devices.