This disclosure relates generally to electrochromic polymers that include a plurality of -conjugated chromophores in spaced relation with one another, and a plurality of conjugation-break spacers (CBSs), where at least one CBS separates adjacent chromophores. The chromophores may be colored in the neutral state, and multicolored to transmissive in different oxidization states.

An organic semiconducting donor-acceptor (D-A) small molecule, as well as a semiconductor device that can incorporate the D-A small molecule, are disclosed. The D-A small molecule can have electron deficient substituents and R group substituents that can be C.sub.1-C.sub.20 linear alkyl chains, C.sub.2-C.sub.24 branched alkyl chains, hydrogen atoms, etc. The D-A small molecule can be can be synthesized in a reaction between a dithienofuran (DTF) core monomer and an electron deficient monomer. Additionally, the D-A small molecule can be part of an organic semiconducting copolymer. A semiconductor device that can incorporate the D-A small molecule in a photoactive layer is also disclosed herein. Additionally, 3,4-dibrominated furan compound that can, in some embodiments, be a precursor for the D-A small molecule is disclosed. The 3,4-dibrominated furan compound can be synthesized in a reaction involving a furan-2,5-dicarboxylic dimethyl ester (FDME), which can have a bio-renewable precursor.

The present invention comprises a conjugated polymer for optoelectronic devices, comprising a structural unit of formula (I) or formula (II):
-[A-D1-A-D2]n-(I)
-[A1-D1-A2-D2]n-(II)
wherein A is an acceptor group; A1 and A2 are acceptor M groups which differ from one another; D1 and D2 are donor groups which differ from one another; and n is an integer between 30 and 1000.

There is provided a monomer liquid for conductive polymer production, comprising: at least one monomer selected from the group consisting of thiophene or its derivatives, pyrrole or its derivative and aniline or its derivative; and at least one kind selected from the group consisting of a naphthalene sulfonic acid type heterocyclic compound and a benzene sulfonic acid type heterocyclic compound in which no hydroxyl group is directly connected to the benzene ring, wherein said at least one kind is dispersed in said at least one monomer. Also, there is provided a production of an electrolyte capacitor by using the monomer liquid for conductive polymer production is explained. In particular, imidazoles are favorable as the naphthalene sulfonic acid type heterocyclic compound and the benzene sulfonic acid type heterocyclic compound.

The present invention relates to a phenyl-derivative compound substituted with at least two electron acceptors and at least two electron donors. Formula (I) R.sup.AaR.sup.DbR.sup.ScC.sub.6 wherein a is 2, 3 or 4; b is 2, 3 or 4; c is 0, 1 or 2; a+b?c=6; R.sup.A is at each occurrence independently a group with ?M-effect; R.sup.B is at each occurrence independently a group with +?M-effect; R.sup.S is as defined in claim 1. Said compound is suited for use in organic electronic devices, particularly in organic electroluminescent devices.

This disclosure relates generally to electrochromic polymers that include a plurality of -conjugated chromophores in spaced relation with one another, and a plurality of conjugation-break spacers (CBSs), where at least one CBS separates adjacent chromophores. The chromophores may be colored in the neutral state, and multicolored to transmissive in different oxidization states.

An organic semiconducting donor-acceptor (D-A) small molecule, as well as a semiconductor device that can incorporate the D-A small molecule, are disclosed. The D-A small molecule can have electron deficient substituents and R group substituents that can be C.sub.1-C.sub.20 linear alkyl chains, C.sub.2-C.sub.24 branched alkyl chains, hydrogen atoms, etc. The D-A small molecule can be can be synthesized in a reaction between a dithienofuran (DTF) core monomer and an electron deficient monomer. Additionally, the D-A small molecule can be part of an organic semiconducting copolymer. A semiconductor device that can incorporate the D-A small molecule in a photoactive layer is also disclosed herein. Additionally, 3,4-dibrominated furan compound that can, in some embodiments, be a precursor for the D-A small molecule is disclosed. The 3,4-dibrominated furan compound can be synthesized in a reaction involving a furan-2,5-dicarboxylic dimethyl ester (FDME), which can have a bio-renewable precursor.

An organic semiconducting donor-acceptor (D-A) small molecule, as well as a semiconductor device that can incorporate the D-A small molecule, are disclosed. The D-A small molecule can have electron deficient substituents and R group substituents that can be C.sub.1-C.sub.20 linear alkyl chains, C.sub.2-C.sub.24 branched alkyl chains, hydrogen atoms, etc. The D-A small molecule can be can be synthesized in a reaction between a dithienofuran (DTF) core monomer and an electron deficient monomer. Additionally, the D-A small molecule can be part of an organic semiconducting copolymer. A semiconductor device that can incorporate the D-A small molecule in a photoactive layer is also disclosed herein. Additionally, 3,4-dibrominated furan compound that can, in some embodiments, be a precursor for the D-A small molecule is disclosed. The 3,4-dibrominated furan compound can be synthesized in a reaction involving a furan-2,5-dicarboxylic dimethyl ester (FDME), which can have a bio-renewable precursor.

A novel soluble green polythiophene electrochromic material, poly[2,3-bis(3,4-dialkoxyphenyl)-5,8-bis(3,4-ethylenedioxythienyl)quinoxaline], as shown by formula (I), ##STR00001## wherein, n is an integer from 40 to 200, R=C.sub.mH.sub.2m+1, wherein m is an integer from 8 to 14.

A solid electrolytic capacitor is obtained by a method which includes dissolving a polymerizable material for being converted into a conductive polymer in a water-soluble organic solvent to obtain a solution, adding the solution to water while homogenizing the solution to obtain a sol, immersing an anode body having a dielectric layer in the surface of the anode body in the sol, and applying voltage using the anode body as a positive electrode and a counter electrode as a negative electrode placed in the sol to electropolymerize the polymerizable material. An electropolymerizable liquid for producing a conductive polymer, the liquid composed of a sol comprising water, a water-soluble organic solvent, and a polymerizable material for being converted into the conductive polymer.