C08G2261/3327

CARBON-IODINE CONJUGATED POLYMER AND PREPARATION THEREOF, AND USE THEREOF FOR PREPARING LOCALIZATION MARKER
20230399456 · 2023-12-14 ·

Described are a carbon-iodine conjugated polymer and preparation thereof, an imaging marker thereof, and uses thereof for preparing a localization marker, and belongs to the technical field of imaging markers. The conjugated structure enables the polymer to have strong absorption in a visible light region, and high iodine content of up to 84.1% corresponds to the strong imaging ability thereof. During surgery, on the basis of the dual guidance of a polymer-based image marker and naked eye observation, the marker can better facilitate determination of tumor resection margins, achieving precise resection of tumors and minimizing damage to surrounding normal tissues. During cyberknife-based treatment, the polymer can replace clinical gold markers to provide ray marker guidance. Absence of metal artifacts improves ray imaging quality and the accuracy of radiation dose distribution, good biocompatibility enhances the stability of the relative position of the marker, and radiotherapy side effects can be further reduced.

METHOD FOR SYNTHESIZING POLYOLEFIN MATERIAL WITH CONTROLLED DEGREE OF BRANCHING

A method for synthesizing polyolefin materials with a controlled degree of branching includes the following steps: polymerizing cyclic olefin monomers under catalyst conditions. The cyclic olefin monomer is shown in formula I, where n0, n is an integer. By changing monomers and reaction parameters such as reaction temperature, solvent type, catalyst concentration, monomer concentration and reaction time, the degree of branching, the molecular weight and molecular weight distribution of polyolefin can be controlled. Compared with the existing process, the present invention is a new polymerization process, which can prepare the hyperbranched polyolefin with precise and controllable branching structure. The polyolefin material prepared according to the present invention has advantages of a controlled degree of branching, low viscosity and good fluidity, which has broad application in coating, lubricant, polymer and process flow improvement technologies.

LAMINATED FILM, METHOD FOR PRODUCING SAME, AND POLARIZING PLATE
20210054131 · 2021-02-25 · ·

A layered film includes first, second, and third layers formed of first, second, and third resins, respectively, and provided in this order. The second resin contains an alkoxysilyl group-modified product of a hydrogenated product of a block copolymer; has 0.020% by weight or less of a moisture content as measured by the Karl-Fischer method after immersed in water at 37 C. for 24 hours and then allowed to stand at 23 C. and a humidity of 70% for 24 hours; and has a flexural modulus lower than flexural moduli of the first and third resins. One or both of the first and third resins contain a polymer containing an alicyclic structure. The first resin has a specific water vapor transmission rate. A ratio of a sum of thicknesses of the first and third layers relative to a thickness of the second layer is in a specific range.

TWO COMPONENT MASS POLYMERIZABLE COMPOSITIONS CONTAINING POLYCYCLOOLEFIN MONOMERS AND ORGANORUTHENIUM CARBIDE PRECATALYST
20210079156 · 2021-03-18 · ·

Embodiments in accordance with the present invention encompass a two component composition containing in one component a latent organo-ruthenium carbide catalyst, and in another component a photoactive acid generator or a thermally active acid generator, and either of the components containing a mixture of photoactive compound along with one or more monomers which undergo ring open metathesis polymerization (ROMP) when said components are mixed together and exposed to a suitable radiation (or heat) to form a three-dimensional (3D) object. The three-dimensional objects so formed exhibits improved mechanical properties, particularly, high heat distortion temperature, impact strength, elongation to break, among others. Accordingly, compositions of this invention are useful as 3D inkjet materials for forming high impact strength objects of various sizes with microscale features lower than 100 microns, among various other uses.

THIN FILM TRANSISTOR AND THIN FILM TRANSISTOR ARRAY AND ELECTRONIC DEVICE

Disclosed are a thin film transistor includes a gate electrode, an active layer including a semiconductor material and a first elastomer, a gate insulator between the gate electrode and the active layer, and a source electrode and a drain electrode electrically connected to the active layer, wherein each of the semiconductor material and the first elastomer has a hydrogen bondable moiety, and the semiconductor material and the first elastomer are subjected to a dynamic intermolecular bonding by a hydrogen bond and a thin film transistor array and an electronic device including the same.

MULTICOLORED ELECTROCHROMIC POLYMER COMPOSITIONS AND METHODS OF MAKING AND USING THE SAME
20230416452 · 2023-12-28 ·

This disclosure relates generally to electrochromic polymers that include a plurality of -conjugated chromophores in spaced relation with one another, and a plurality of conjugation-break spacers (CBSs), where at least one CBS separates adjacent chromophores. The chromophores may be colored in the neutral state, and multicolored to transmissive in different oxidization states.

SHELF LIFE MASS POLYMERIZABLE POLYCYCLOOLEFIN COMPOSITIONS AS OPTICAL MATERIALS
20210206789 · 2021-07-08 · ·

Embodiments in accordance with the present invention encompass compositions encompassing a latent organo-ruthenium compound and a pyridine compound along with one or more monomers which undergo ring open metathesis polymerization (ROMP) when said composition is exposed to suitable actinic radiation to form a substantially transparent film. Surprisingly, the compositions are very stable at ambient conditions to temperatures up to 80 C. for several days and undergo mass polymerization when subject only to actinic radiation. Accordingly, compositions of this invention are useful in various opto-electronic applications, including as 3D printing materials, coatings, encapsulants, fillers, leveling agents, among others.

PRODUCTION OF KETONE-BASED BIOPOLYMERS FROM CATALYTIC FAST PYROLYSIS OF BIOMASS

The present disclosure relates to a composition that includes

##STR00001##

where R.sub.1 and R.sub.2 include at least one of a hydrogen, a hydroxyl group, and/or an alkyl group, R.sub.3 and R.sub.4 include at least one of hydrogen, a hydroxyl group, an alkyl group, and/or a ketone, and 1n2000.

RESIN MATERIAL FOR FORMING UNDERLAYER FILM, RESIST UNDERLAYER FILM, METHOD OF PRODUCING RESIST UNDERLAYER FILM, AND LAMINATE

Provided is a resin material for forming an underlayer film which is used to form a resist underlayer film used in a multi-layer resist process, the resin material including a cyclic olefin polymer (I), in which a temperature at an intersection between a storage modulus (G) curve and a loss modulus (G) curve in a solid viscoelasticity of the resin material for forming an underlayer film which is as measured under conditions of a measurement temperature range of 30 C. to 300 C., a heating rate of 3 C./min, and a frequency of 1 Hz in a nitrogen atmosphere in a shear mode using a rheometer is higher than or equal to 40 C. and lower than or equal to 200.

Solvent for producing organic transistor

Provided is a solvent for organic transistor production. The solvent has excellent solubility for organic semiconductor materials and enables formation of an organic transistor having high crystallinity. The solvent according to the present invention for organic transistor production includes a solvent A represented by Formula (a). In the formula, Ring Z represents a ring selected from an aromatic carbon ring, a 5- to 7-membered alicyclic carbon ring, and a 5- to 7-membered heterocyclic ring; R.sup.1 represents a group selected from oxo, thioxy, OR.sup.a, SR.sup.a, O(CO)R.sup.a, R.sup.bO(CO)R.sup.a, and substituted or unsubstituted amino; and R.sup.2 represents a group selected from hydrogen, C.sub.1-C.sub.7 alkyl, aryl, and OR.sup.a, where R.sup.1 and R.sup.2 may be linked to each other to form a ring with one or more carbon atoms constituting Ring Z. ##STR00001##