The present disclosure relates to compositions comprising 2,3,3,3-tetrafluoropropene that may be useful as heat transfer compositions, aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, extinguishing agents, and fire suppression agents in liquid or gaseous form. Additionally, the present disclosure relates to compositions comprising 1,1,2,3-tetrachloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane, which may be useful in processes to produce 2,3,3,3-tetrafluoropropene.

Described herein is a perfluorinated aminoolefin compound of general formula (I): CFY═CXN(R.sub.f)CF.sub.2R.sub.f′ where: (a) R.sub.f and R.sub.f′ are (i) independently selected from a linear or branched perfluoroalkyl group having 1-8 carbon atoms, optionally comprising at least one catenated O or N atom, or (ii) bonded together to form a perfluorinated ring structure having 4-8 ring carbon atoms, optionally comprising at least one catenated O atom; and (b) X and Y are (i) independently selected from a perfluoroalkyl group having 1-4 carbon atoms, or (ii) bonded together to form a perfluorinated ring structure having 5-6 ring carbon atoms. Such compounds may be used in heat transfer, foam blowing or immersion cooling applications, or as a working fluid in a Rankine cycle, a coating or lubricant, or as a dielectric fluid. Also disclosed herein is a method for making such compounds.

Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, CHF=CHCl, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.

Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244 db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243 fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, CHF═CHCl, HFO-1141, HCFO-1242 zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.

Disclosed is a blowing agent composition comprising a hydrofluoroolefins (HFO) and a branched hydrocarbon, and a foamable polymer composition comprising the blowing agent composition. Also disclosed is a method of making a polymer foam utilizing a blowing agent composition comprising an HFO and a branched hydrocarbon.

Provided is a phenolic resin foam laminate board in which a flexible surface material is arranged on at least upper and lower surfaces of a phenolic resin foam. The phenolic resin foam contains HCFO-1224yd(Z), has a density of not less than 20 kg/m.sup.3 and not more than 55 kg/m.sup.3, a closed cell ratio of 80% or more, an average cell diameter of not less than 60 μm and not more than 200 μm, a percentage of an area seeping out from the surface material is 30% or less, and content of HCFO-1224yd(Z) per space volume of 22.4×10.sup.−3 m.sup.3 in the phenolic resin foam is not less than 0.06 mol and not more than 0.35 mol.

A composition and method for making extruded polystyrene (XPS) foam is provided. The composition includes an infrared attenuation agent composition comprising conductive polymers to achieve an XPS foam having an improved thermal insulation performance. In some exemplary embodiments, the conductive polymers comprise doped polypyrrole and doped polyaniline. In some exemplary embodiments, the XPS foam includes a carbon dioxide-based blowing agent.

The present invention is related to a process for the production of a vinyl aromatic (co)polymer comprising the steps of: a) mixing a fraction (A) comprising one or more monomers selected from the group consisting of styrene, alpha-methyl styrene, acrylonitrile, methyl (meth)acrylate, (meth)acrylic acid and butadiene with a fraction (B) comprising post-consumer recycled vinyl aromatic (co)polymer, wherein the weight ratio of fraction (B) to fraction (A) is comprised between 0.01/1 and 1/1, preferably between 0.05/1 and 0.5/1 b) subjecting the resulting mixture to a free-radical polymerization and polymerizing to a monomer conversion up to 90%, to obtain a polymerized mixture comprising vinyl aromatic (co)polymer; c) vacuum devolatizing the polymerized mixture and recovering vinyl aromatic (co)polymer characterized by a weight average molecular weight comprised between 100,000 and 400,000 g/mol;
wherein one or more bromine derivative capture agents are added before, and/or during and/or after at least one of the steps a) to c); and
wherein 100 parts of one or more bromine derivative capture agents comprises at least 50 parts by weight of hydrotalcite of the formula:

[Mg.sub.1-x Al.sub.x(OH).sub.2].sup.x+(CO.sub.3).sub.x/2.mH.sub.2O

wherein: 0<x≤0.5, and m is a positive number.

The present invention is also related to expandable and extruded expanded vinyl aromatic (co)polymer compositions obtained from vinyl aromatic (co)polymers comprising post-consumer and/or post-industrial vinyl aromatic (co)polymer and to a process for the production of said expandable and extruded expanded vinyl aromatic (co)polymer compositions.

A phenolic foam and method for manufacturing same are described herein. The foam is formed from a foamable phenolic resin composition, and a blowing agent, the phenolic foam comprising 1 to 5% by weight of red phosphorus based on the weight of the phenolic foam wherein said phenolic foam has a density of from 10 kg/m.sup.3 to 100 kg/m.sup.3, a closed cell content of at least 85% as determined in accordance with ASTM D6226 and wherein said foam has a FIGRA.sub.0.2 MJ of 120 W/s or less, when measured according to EN13823 and a thermal conductivity of 0.023 W/m.K or less, at 10° C., in accordance with EN 13166:2012. The foam has excellent thermal insulation performance and excellent fire performance.

Methods, foams and blowing agents for forming for forming extruded polystyrene foam wherein the blowing agent comprises (i) from about 40% by weight to about 70% by weight of one or more HFOs three or four carbon atoms and/or an HFCOs having three or four carbon atoms being selected from the group consisting of 1224yd(Z), 1233zd(E), 1336mzz(Z) and combinations of these; and (ii) from about 30% to about 60% by weight of isobutane, methyl formate and combinations of these.