Provided is a blend of a petroleum feedstock and 1-20 wt. % of plastic, based on the weight of the blend, with the plastic comprising polyethylene and/or polypropylene, and the plastic in the blend comprising finely dispersed microcrystalline particles having an average particle size of 10 micron to less than 100 microns. A process for preparing a blend of plastic and petroleum is provided, comprising mixing together a petroleum feed and a plastic comprising polyethylene and/or polypropylene and heating the mixture above the melting point of the plastic, but less than 500° F. Then cooling the plastic melt and petroleum feedstock liquid blend with mixing to a temperature below the melting point of the plastic.

Provided is a blend of a petroleum feedstock and 1-20 wt. % of plastic, based on the weight of the blend, with the plastic comprising polyethylene and/or polypropylene, and the plastic in the blend comprising finely dispersed microcrystalline particles having an average particle size of 10 micron to less than 100 microns. A process for preparing a blend of plastic and petroleum is provided, comprising mixing together a petroleum feed and a plastic comprising polyethylene and/or polypropylene and heating the mixture above the melting point of the plastic, but less than 500° F. Then cooling the plastic melt and petroleum feedstock liquid blend with mixing to a temperature below the melting point of the plastic.

Pre-treating a waste polyester material with dichloromethane (DCM) produces a purified polyester for reuse. The purified polyester can be recycled via any chemical or mechanical recycling process. Where the waste polyester material includes non-polyester contaminants, the DCM-treated polyester material produces a slurry that includes the DCM, a solid component that includes a polyester monomer product for reuse, and a waste liquid component where the non-polyester contaminants can be filtered from the top of the liquid component.

Pre-treating a waste polyester material with dichloromethane (DCM) produces a purified polyester for reuse. The purified polyester can be recycled via any chemical or mechanical recycling process. Where the waste polyester material includes non-polyester contaminants, the DCM-treated polyester material produces a slurry that includes the DCM, a solid component that includes a polyester monomer product for reuse, and a waste liquid component where the non-polyester contaminants can be filtered from the top of the liquid component.

A waste polyester material is prepared for recycling by dissolving the material in a solution comprising hexafluoroisopropyl (HFIPA) and a chlorinated hydrocarbon, such as dichloromethane (DCM) and/or an aromatic hydrocarbon, such as toluene or xylene, to form a dissolved polyester sample. The dissolved polyester may be prepared for recycling by evaporation, spray drying, and/or precipitation, which produces a purified solid polyester product. The dissolution solution, which is separated from the purified solid polyester product, is also recycled through distillation with purification.

A waste polyester material is prepared for recycling by dissolving the material in a solution comprising hexafluoroisopropyl (HFIPA) and a chlorinated hydrocarbon, such as dichloromethane (DCM) and/or an aromatic hydrocarbon, such as toluene or xylene, to form a dissolved polyester sample. The dissolved polyester may be prepared for recycling by evaporation, spray drying, and/or precipitation, which produces a purified solid polyester product. The dissolution solution, which is separated from the purified solid polyester product, is also recycled through distillation with purification.

Methods for recycling oligomeric units derived from a first polymer into a second polymer are provided herein. Methods of preparing oligomeric macromonomers from oligomeric units are further provided. Methods of polymerizing oligomeric macromonomers are further provided.

Methods for recycling oligomeric units derived from a first polymer into a second polymer are provided herein. Methods of preparing oligomeric macromonomers from oligomeric units are further provided. Methods of polymerizing oligomeric macromonomers are further provided.

A process of: providing a polyfunctional compound selected from polyisocyanate, polyacrylate, and polyepoxy; and reacting the polyfunctional compound with a hydroxyl- or amine-terminated silyl-containing compound. The polyfunctional compound and the silyl-containing compound are at least difunctional. A thermoset made by this process.

A process of: providing a polyfunctional compound selected from polyisocyanate, polyacrylate, and polyepoxy; and reacting the polyfunctional compound with a hydroxyl- or amine-terminated silyl-containing compound. The polyfunctional compound and the silyl-containing compound are at least difunctional. A thermoset made by this process.