The invention is a process of treating plastic waste, comprising converting one or more plastic polymers into a liquid form either by dissolving in an organic solvent or by melting, and degrading said polymer(s) with the aid of alkali hydroxide and hydrogen peroxide, optionally in the presence of a phase transfer catalyst.

A process of: providing a polyfunctional compound selected from polyisocyanate, polyacrylate, and polyepoxy; and reacting the polyfunctional compound with a hydroxyl- or amine-terminated silyl-containing compound. The polyfunctional compound and the silyl-containing compound are at least difunctional. A thermoset made by this process.

A process of: providing a polyfunctional compound selected from polyisocyanate, polyacrylate, and polyepoxy; and reacting the polyfunctional compound with a hydroxyl- or amine-terminated silyl-containing compound. The polyfunctional compound and the silyl-containing compound are at least difunctional. A thermoset made by this process.

A method of processing of shredded rubber-containing waste involves its preliminary preparation, thermal decomposition in a furnace, separation of decomposition products into vapor-gas mixture and solid residue, and separation of a heavy hydrocarbon fraction from the vapor-gas mixture. Preliminary preparation of the waste is carried out by its blowing with water vapor until a waste temperature reaches 100 C., and thermal decomposition is carried out in residual oil in the starting phase, and afterwards in the atomized generated heavy hydrocarbon fraction and superheated water vapor, their weight ratio being (0.1-0.5):1. The heavy hydrocarbon fraction is separated from the vapor-gas mixture with water by atomizing it into the vapor-gas mixture flow at the rate of 5-15% of the mass flow rate of the mixture, while metal is extracted from the solid residue by magnetic separation, after which a product containing zinc oxide is separated by dielectric separation.

A variety of methods/systems/apparatus/compositions are disclosed, including, in one embodiment, a method including introducing a polymeric material, an unsaturated compound, and an olefin cross metathesis catalyst into a reactor, wherein the polymeric material comprises a carbon black filler; reacting at least a portion of the polymeric material with the unsaturated compound in the presence of the olefin cross metathesis catalyst to produce at least metathesis oil and metathesis carbon black, wherein the metathesis oil comprises an olefin cross metathesis product of the polymeric material and the unsaturated compound; and separating at least a portion of the metathesis carbon black.

A variety of methods/systems/apparatus/compositions are disclosed, including, in one embodiment, a method including introducing a polymeric material, an unsaturated compound, and an olefin cross metathesis catalyst into a reactor, wherein the polymeric material comprises a carbon black filler; reacting at least a portion of the polymeric material with the unsaturated compound in the presence of the olefin cross metathesis catalyst to produce at least metathesis oil and metathesis carbon black, wherein the metathesis oil comprises an olefin cross metathesis product of the polymeric material and the unsaturated compound; and separating at least a portion of the metathesis carbon black.

A waste polyester material is prepared for recycling by dissolving the material in a solution comprising hexafluoroisopropyl (HFIPA) and a chlorinated hydrocarbon, such as dichloromethane (DCM) and/or an aromatic hydrocarbon, such as toluene or xylene, to form a dissolved polyester sample. The dissolved polyester may be prepared for recycling by evaporation, spray drying, and/or precipitation, which produces a purified solid polyester product. The dissolution solution, which is separated from the purified solid polyester product, is also recycled through distillation with purification.

A waste polyester material is prepared for recycling by dissolving the material in a solution comprising hexafluoroisopropyl (HFIPA) and a chlorinated hydrocarbon, such as dichloromethane (DCM) and/or an aromatic hydrocarbon, such as toluene or xylene, to form a dissolved polyester sample. The dissolved polyester may be prepared for recycling by evaporation, spray drying, and/or precipitation, which produces a purified solid polyester product. The dissolution solution, which is separated from the purified solid polyester product, is also recycled through distillation with purification.

A method of processing of shredded rubber-containing waste involves its preliminary preparation, thermal decomposition in a furnace, separation of decomposition products into vapor-gas mixture and solid residue, and separation of a heavy hydrocarbon fraction from the vapor-gas mixture. Preliminary preparation of the waste is carried out by its blowing with water vapor until a waste temperature reaches 100 C., and thermal decomposition is carried out in residual oil in the starting phase, and afterwards in the atomized generated heavy hydrocarbon fraction and superheated water vapor, their weight ratio being (0.1-0.5):1. The heavy hydrocarbon fraction is separated from the vapor-gas mixture with water by atomizing it into the vapor-gas mixture flow at the rate of 5-15% of the mass flow rate of the mixture, while metal is extracted from the solid residue by magnetic separation, after which a product containing zinc oxide is separated by dielectric separation.

Systems and methods are provided for integration of polymeric waste co-processing in cokers to produce circular chemical products from coker naphtha, including a method of producing circular chemical products comprising: providing a coker naphtha that is at least partially derived from polymeric waste, wherein the coker naphtha has a total halide content of about 1 wppm to about 0.5 wt %, a 2-3 ring aromatic content of about 0 wt % to about 5 wt %, and a sulfur content of about 750 ppm to about 2 wt %; and converting the coker naphtha into at least a polymer.