Disclosed herein are thermoplastic composition comprising (a) about 15 wt % to about 95 wt % polymer component comprising: (i) either about 20 wt % to about 85 wt % poly(p-phenylene oxide) and about 10 wt % to about 65 wt % flow promoter or about 70 wt % to 100 wt % polypropylene, said polypropylene being homopolymer and/or copolymer; and (ii) greater than about 0 wt % to about 30 wt % impact modifier; (b) about 2 wt % to about 50 wt % of a laser activatable additive having a core-shell structure, wherein the core comprises an inorganic filler and the shell comprises a laser activatable component; and (c) about 3 wt % to about 70 wt % inorganic fillers.

Disclosed herein are thermoplastic composition comprising (a) about 15 wt % to about 95 wt % polymer component comprising: (i) either about 20 wt % to about 85 wt % poly(p-phenylene oxide) and about 10 wt % to about 65 wt % flow promoter or about 70 wt % to 100 wt % polypropylene, said polypropylene being homopolymer and/or copolymer; and (ii) greater than about 0 wt % to about 30 wt % impact modifier; (b) about 2 wt % to about 50 wt % of a laser activatable additive having a core-shell structure, wherein the core comprises an inorganic filler and the shell comprises a laser activatable component; and (c) about 3 wt % to about 70 wt % inorganic fillers.

Small diameter poly(phenylene ether) fibers can be consistently formed from a composition comprising specific amounts of a poly(phenylene ether), a processing aid, and optionally a poly(alkenyl aromatic). The processing aid can be LLDPE, a petroleum resin, or combinations thereof. The processing aid can optionally further comprise a phosphite or phosphonate. Flame retardants are minimized or excluded from the composition. The fibers can be melt spun without entanglement or breakage, and this improved processability enables small diameter fibers to be formed. The resulting fibers can be used in reinforcing structures for printed circuit boards.

Provided are a resin composition and a shaped product having excellent smoke generation properties and chemical resistance. The resin composition and the shaped product contain: a polyphenylene ether resin (I); a polypropylene resin (II); a hydrogenated block copolymer (III) that is a hydrogenated product of a block copolymer including a polymer block A and a polymer block B in which the total amount of vinyl bonding is 30-90%; and a phosphate ester compound (IV). Relative to 100 parts by mass, in total, of components (I) and (II), component (I) is 40-99 parts by mass, component (II) is 1-60 parts by mass, component (III) is 1-20 parts by mass, and component (IV) is 5-45 parts by mass. A partition ratio of component (IV) present in a fraction that dissolves in chloroform and component (IV) present in a fraction that dissolves in o-dichlorobenzene is 10 or more.

Provided are a resin composition and a shaped product having excellent smoke generation properties and chemical resistance. The resin composition and the shaped product contain: a polyphenylene ether resin (I); a polypropylene resin (II); a hydrogenated block copolymer (III) that is a hydrogenated product of a block copolymer including a polymer block A and a polymer block B in which the total amount of vinyl bonding is 30-90%; and a phosphate ester compound (IV). Relative to 100 parts by mass, in total, of components (I) and (II), component (I) is 40-99 parts by mass, component (II) is 1-60 parts by mass, component (III) is 1-20 parts by mass, and component (IV) is 5-45 parts by mass. A partition ratio of component (IV) present in a fraction that dissolves in chloroform and component (IV) present in a fraction that dissolves in o-dichlorobenzene is 10 or more.

The present invention is related to high Impact strength thermoplastic compositions comprising: a) from 10 to 90% by weight of a rubber-modified monovinylidene aromatic (co)polymer; b) from 10 to 90% by weight of a polyphenylene ether; wherein: said rubber-modified monovinylidene aromatic (co)polymer a) comprising: I) a matrix comprising monovinylidene aromatic polymer, and II) from 5 to 25% by weight of rubber in the form of discrete rubber particles dispersed within the matrix, wherein the rubber particles comprise a blend of at least two polybutadienes as well as graft- and block copolymers of polybutadiene and monovinylidene aromatic polymer segments, said rubber particles exhibit: an average particle size by volume (D50) comprised between 0.8 and 5.5 ?m, measured by laser light scattering; said blend of at least two polybutadienes comprises: at least 50% by weight of one or more polybutadiene(s) with a cis-1,4 structure content of at least 80% by weight and at most 50% by weight of one or more polybutadiene(s) with a trans-1-4 structure content of at least 25% by weight and a 1,2-vinyl content of at least 5% by weight; said blend being characterized by a dynamic solution viscosity, comprised between 50 and 160 mPa.Math.s, as determined by Brookfield viscometer according to ISO 2555 at a concentration of 5.43% by weight in toluene; and said polyphenylene ether b) has a repeating structural formula (I) wherein R1 and R2 are independently selected from the group consisting of a hydrogen atom, a halogen atom, C1-4 alkyl radicals, C1-4 alkoxy radicals, C6-10 aromatic radicals which are unsubstituted or substituted by a C1-4 alkyl radical, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen and the phenyl nucleus, and wherein n is an integer of at least 50. The invention further is related to a method for the preparation of the high Impact strength thermoplastic compositions.

##STR00001##

The present invention is related to high Impact strength thermoplastic compositions comprising: a) from 10 to 90% by weight of a rubber-modified monovinylidene aromatic (co)polymer; b) from 10 to 90% by weight of a polyphenylene ether; wherein: said rubber-modified monovinylidene aromatic (co)polymer a) comprising: I) a matrix comprising monovinylidene aromatic polymer, and II) from 5 to 25% by weight of rubber in the form of discrete rubber particles dispersed within the matrix, wherein the rubber particles comprise a blend of at least two polybutadienes as well as graft- and block copolymers of polybutadiene and monovinylidene aromatic polymer segments, said rubber particles exhibit: an average particle size by volume (D50) comprised between 0.8 and 5.5 ?m, measured by laser light scattering; said blend of at least two polybutadienes comprises: at least 50% by weight of one or more polybutadiene(s) with a cis-1,4 structure content of at least 80% by weight and at most 50% by weight of one or more polybutadiene(s) with a trans-1-4 structure content of at least 25% by weight and a 1,2-vinyl content of at least 5% by weight; said blend being characterized by a dynamic solution viscosity, comprised between 50 and 160 mPa.Math.s, as determined by Brookfield viscometer according to ISO 2555 at a concentration of 5.43% by weight in toluene; and said polyphenylene ether b) has a repeating structural formula (I) wherein R1 and R2 are independently selected from the group consisting of a hydrogen atom, a halogen atom, C1-4 alkyl radicals, C1-4 alkoxy radicals, C6-10 aromatic radicals which are unsubstituted or substituted by a C1-4 alkyl radical, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen and the phenyl nucleus, and wherein n is an integer of at least 50. The invention further is related to a method for the preparation of the high Impact strength thermoplastic compositions.

##STR00001##

A thermoplastic composition includes: (a) about 30 wt % to about 60 wt % of a resin component including polyphenylene ether (PPE) and polystyrene (PS); (b) from about 35 wt % to about 65 wt % of a filler component; (c) from about 1 wt % to about 5 wt % of a flow promoter including at least a partially hydrogenated hydrocarbon resin; and (d) an elastomer component including from 2.5 wt % to 5 wt % rubber content in the composition excluding the filler component. The combined weight percent value of all components does not exceed 100 wt %, and all weight percent values are based on the total weight of the composition except as indicated in (d).

A thermoplastic composition includes: (a) about 30 wt % to about 60 wt % of a resin component including polyphenylene ether (PPE) and polystyrene (PS); (b) from about 35 wt % to about 65 wt % of a filler component; (c) from about 1 wt % to about 5 wt % of a flow promoter including at least a partially hydrogenated hydrocarbon resin; and (d) an elastomer component including from 2.5 wt % to 5 wt % rubber content in the composition excluding the filler component. The combined weight percent value of all components does not exceed 100 wt %, and all weight percent values are based on the total weight of the composition except as indicated in (d).

A composite resin material including: a first organic resin having a phenylene ether structure; and a second organic resin having a main skeleton composed of a polyester structure, one of the first organic resin and the second organic resin forming a continuous phase, the other one thereof being present within the continuous phase, as organic resin particles having an average particle diameter of 1 m or less.