Durable, anti-fouling, crosslinked zwitterionic coatings that are grafted to the surface of a substrate through covalent bonding are disclosed. When exposed to a light source, zwitterionic monomers react with a crosslinker and with activated radicals at the surface of the substrate, simultaneously forming the crosslinked zwitterionic coating and anchoring it to the surface of the substrate. Photomasking techniques can be used to micropattern the zwitterionic coatings. The zwitterionic coatings can be applied to a variety of substrates, including medical devices and systems.

An anti-fouling silicone composite sheet includes a substrate layer, and a silicone adhesive layer stacked on one surface of the substrate layer, and has a hardness of 5 or less measured with an Asker C hardness tester and an adhesive force of 5 N/25 mm or more with respect to a mortar test piece, in which a surface of the substrate layer which is located on a side opposite to the surface where the silicone adhesive layer is stacked is a surface anti-fouling-treated with a silicone hard coating agent containing a fluorine-containing silicone compound. An anti-fouling silicone composite sheet is capable of exhibiting anti-fouling performance and washability stably for a long period, easily attachable to an adherend, and followable even to cracking and shifting on the application surface; and a method for preventing graffiti by using the anti-fouling silicone composite sheet.

A process for forming a fingerprint-resistant coating on a substrate comprising activating the substrate by exposure to a plasma, and then depositing on the activated substrate at least one alkyl backbone monolayer, and hydroxyl-polyhedral oligomeric silsesquioxane (OH-POSS) nanoparticles.

Provided is an antifouling composition including a tetrafunctional silane-based compound (A) having a specified structure, a trifunctional silane-based compound having a specified structure, and at least one metal catalyst (C) selected from the group consisting of a titanium-based catalyst, an aluminum-based catalyst, a tin-based catalyst, and a zinc-based catalyst, the antifouling composition satisfying the following relational expression (1).

1.5≦y≦2x+1  Expression (1):

In the expression, x indicates the carbon number of an alkyl group that is selected for R.sup.2 in the formula (b) representing the silane-based compound (B) and indicates a number of 4 to 22; and y indicates a blending amount ratio (A)/(B) in a molar ratio of the silane-based compound (A) to the silane-based compound (B).

An article having antifouling properties and intended to be employed in aquatic uses, in particular marine uses. In particular there is provided an article having antifouling properties and intended to be employed in aquatic uses which comprises: a) a support, b) optionally, at least one primer coat on said support comprising at least one anticorrosive product, c) optionally, at least one intermediate primer coat promoting adhesion between the coats, d) at least one adhesion-promoting coat or tie coat, deposited on said primer coat or on said support when the primer coat is absent, and e) at least one antifouling coat or topcoat, deposited on said adhesion-promoting coat or tie coat.

A surface treatment composition including a perfluoropolyether group-containing silane compound and a solvent, wherein a proportion of the perfluoropolyether group-containing silane compound based on a total amount of the perfluoropolyether group-containing silane compound and the solvent is in the range from 30 to 99% by mass.

Silicone compositions and methods of using the compositions are provided. The silicone coatings can exhibit improved dirt pick-up resistance and cleanability. The silicone compositions include a polysiloxane, at least one surfactant, and optionally one or more of a pigment, a filler, a crosslinker, an adhesion promoter, a catalyst, additives or solvents.

A process for forming a fingerprint-resistant coating on a substrate comprising activating the substrate by exposure to a plasma, and then depositing on the activated substrate at least one alkyl backbone monolayer, and hydroxyl-polyhedral oligomeric silsesquioxane (OH—POSS) nanoparticles.

Provided are silicone-epoxy compositions, protective coatings formed from silicone-epoxy compositions, and methods of preparing the same.

In one aspect, the invention has an object of providing antifouling coating compositions which have high resistance to fouling, in particular, fouling by slime, can form coating films with excellent properties such as strength and rubber properties, exhibit appropriate viscosity (sprayability and coating film surface leveling properties during spray coating) and sagging resistance, and have high storage stability suppressing deteriorations of these properties. To achieve the object, the invention provides an antifouling coating composition including (A) a diorganopolysiloxane having at least two silanol groups in the molecule, (B) an organosilane and/or a partial hydrolyzate condensate thereof having at least two hydrolyzable groups in the molecule, and (C) a pyrithione metal salt. The antifouling coating composition can be prepared from a kit in the form of a multiple-component system including respective packages of a component including the component (A) and the component (C), and a component including the component (B). In the (kit for the preparation of the) antifouling coating composition, the pyrithione metal salt (C) functions as an effective ingredient for achieving excellent antifouling properties, in particular, anti-sliming properties, and also as an effective ingredient for improving storage stability.