Disclosed herein is an aqueous cathodically depositable electrodeposition coating material composition including at least one cathodically depositable polymer and at least one alkoxylated polyethyleneimine. Additionally disclosed herein is a method for at least partially coating an electrically conductive substrate by cathodic electrodeposition coating of the prementioned electrodeposition material. Further disclosed herein is a method of using at least one alkoxylated polyethyleneimine for improving the edge corrosion protection of electrically conductive substrates bearing a baked coating film obtained from the aqueous cathodically depositable electrodeposition coating material composition.

The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles that have a Z-average particle diameter of 5 to 500 nm and are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A), wherein the emulsion polymerization takes place in the presence of one or more emulsifiers (E) having the following general formula: R.sup.1(R.sup.2)(R.sup.3), where: R is a moiety that contains at least one aromatic group and at least one aliphatic group, has 15 to 40 carbon atoms, and contains at least one functional group selected from hydroxy groups, thiol groups, and primary or secondary amino groups and/or comprises at least one carbon-carbon multiple bond; and R.sup.1, R.sup.2, and R.sup.3 are, independently of each other, identical or different aliphatic moieties having 1 to 14 carbon atoms. The invention also relates to a method for producing the primary dispersions, coating agents comprising the primary dispersions, use of the primary dispersions to produce electrocoats, and conductive substrates that have been coated with the coating agent compositions.

A method for coating a substrate includes the steps of: forming a conductive coating layer on a surface of a substrate so as to form a semi-product; submerging a conductive sheet and the semi-product into an electrophoresis medium that includes charged colloid particles; and applying a voltage on the conductive sheet or the semi-product to form an electric field among the conductive sheet, the semi-product, and the electrophoresis medium, so that the colloid particles move along the electric field toward the semi-product and an electrophoretic covering layer formed by the charged colloid particles is thus deposited on the electrophoretic covering layer.

An object of the present invention is to provide a copolymer having the characteristic of developing high viscosity, and lowering its viscosity with an increase in rate of shear, particularly a copolymer having the characteristic of developing viscosity, and lowering its viscosity with an increase in rate of shear even in an aqueous coating composition that contains a surfactant. The present invention provides a copolymer obtainable by copolymerization of a monomer component (m) that includes: (m-1), a macromonomer having (i) a backbone that comprises a polymer chain having a number average molecular weight of 1,000 to 10,000 obtainable by polymerizing a monomer component (I) that contains 5 to 100 mass % of a C4-C24 alkyl-containing polymerizable unsaturated monomer (a), and (ii) a polymerizable unsaturated group; and (m-2) a polymerizable unsaturated monomer containing a hydrophilic group.

It is an object of the present invention is to provide an electrodeposition coating composition and an electrodeposition coating method that enable the formation of a cured electrodeposition coating film that develops excellent throwing power and exhibits a good appearance. An electrodeposition coating composition of the present invention comprising: at least one compound (A) selected from the group consisting of a zinc compound (A-1) and a bismuth compound (A-2); an aminated resin (B); and a curing agent (C), wherein a milligram equivalent (MEQ (A)) of an acid per 100 g of a resin solid content in the composition is 27 or more; a coulombic efficiency of the composition is 30 mg/C or less; a film resistance of a 15-m-thick uncured electrodeposition coating film formed using the composition is 400 k.Math.cm.sup.2 or more; and a coating film viscosity of an electrodeposition coating film obtained from the composition is 3000 Pa.Math.s or less at 50 C.

The invention relates to pigment- and/or filler-containing formulations, comprising one or more solids selected from the group of the pigments and fillers, and an emulsifier (EQ), which has the following formula: R.sup.1N(R.sup.2)(R.sup.3)(R.sup.4)X(EQ), where: R.sup.1 is a moiety that contains at least one aromatic group and at least one aliphatic group, has 15 to 40 carbon atoms, and contains at least one functional group selected from hydroxy groups, thiol groups, and primary or secondary amino groups and/or comprises at least one carbon-carbon multiple bond; R.sup.2, R.sup.3, and R.sup.4 are, independently of each other, identical or different aliphatic moieties having 1 to 14 carbon atoms; and X stands for the acid anion of an organic or inorganic acid HX. The invention further relates to coating agents comprising said formulations, the use of said formulations to produce electrocoats, and conductive substrates coated with said coating agent compositions.

The invention relates to aqueous, cationically stabilized primary dispersions comprising dispersed polymer particles that have a Z-average particle diameter of 5 to 500 nm and are obtainable by emulsion polymerization of at least one olefinically unsaturated monomer (A), wherein the emulsion polymerization takes place in the presence of one or more emulsifiers (E) having the following general formula: R.sup.1(R.sup.2)(R.sup.3), where: R is a moiety that contains at least one aromatic group and at least one aliphatic group, has 15 to 40 carbon atoms, and contains at least one functional group selected from hydroxy groups, thiol groups, and primary or secondary amino groups and/or comprises at least one carbon-carbon multiple bond; and R.sup.1, R.sup.2, and R.sup.3 are, independently of each other, identical or different aliphatic moieties having 1 to 14 carbon atoms. The invention also relates to a method for producing the primary dispersions, coating agents comprising the primary dispersions, use of the primary dispersions to produce electrocoats, and conductive substrates that have been coated with the coating agent compositions.

A method for fabricating an electron field emission cathode, the field emission cathode including a substrate having a field emission layer engaged therewith, where the field emission layer incorporates modified carbon nanotubes and a matrix material to improve field emission characteristics of the cathode and field emission cathode devices implementing such cathodes.

An object of the present invention is to provide a preparation method for improving the edge part rust prevention property in the preparation of a cationic electrodeposition coating composition containing a bismuth compound as a curing catalyst. The present invention provides a method for preparing a cationic electrodeposition coating composition, including a step of preparing a resin emulsion (i) containing an aminated resin (A) and a blocked isocyanate curing agent (B), a step of preparing a pigment dispersion paste (ii) containing a bismuth-metal oxide mixture liquid (C) containing a bismuth compound (c1), a metal oxide (c2), a monohydroxycarboxylic acid (c3) having 3 to 5 carbon atoms in total and a solvent; a pigment dispersion resin (D); a polyvalent acid (E); and a pigment (F), and a step of mixing the resin emulsion (i) and the pigment dispersion paste (ii).

The present disclosure is directed to an electrodeposited coating or a coated metal substrate comprising the electrodeposited coating, wherein the electrodeposited coating comprises: a plate-like pigment present in a pigment-to-binder ratio of at least 0.4:1; and an electrodeposited binder comprising: a first resin domain having a first glass transition temperature; and a second resin domain having a second glass transition temperature, wherein the first glass transition temperature is at least 10 C., greater than the second glass transition temperature, and the second glass transition temperature is greater than 50 C., and/or the first glass transition temperature is at least 80 C. and the second glass transition temperature is from 50 C. to 70 C. Also disclosed are electrodepositable coating compositions and methods of coating substrates.