Thermoset compositions and methods for forming three-dimensional articles via an additive fabrication process, and articles made therefrom are disclosed herein. In an embodiment, a composition comprises a first network-forming component comprising a first oligomer comprising a backbone and having at least 2 polymerizable groups, one or more first network monomers, and a first network initiator. The backbone of the first oligomer comprises a polyepoxide based on Bisphenol A, F, or S, a polyepoxide based on hydrogenated Bisphenol A, F, or S, a polycarbonate, or a polyimide. The composition may further comprise a second network-forming component.

Provided is an ink composition, in particular an inkjet ink composition for use in inkjet printing such as drop on demand inkjet printing or continuous inkjet printing, which is suitable for producing codes on non-porous substrates. The ink composition has a C.sub.1-6 alcohol solvent, a C.sub.3-12 ester solvent, a siloxane surfactant, and a capping resin selected from a rosin resin and a terpene phenolic resin. The ink compositions have short drying times in combination with long decap times and/or good latency.

Provided is an ink composition, in particular an inkjet ink composition for use in inkjet printing such as drop on demand inkjet printing or continuous inkjet printing, which is suitable for producing codes on non-porous substrates. The ink composition has a C.sub.1-6 alcohol solvent, a C.sub.3-12 ester solvent, a siloxane surfactant, and a capping resin selected from a rosin resin and a terpene phenolic resin. The ink compositions have short drying times in combination with long decap times and/or good latency.

The water-soluble resin for printing of the present invention includes a monomer unit A having a sulfonate group; and a monomer unit B having no hydrophilic group, and a percentage of the monomer unit A based on a total of all monomer units is 5 to 35 mol %. According to the water-soluble resin for printing of the present invention, a printed matter from which a printing layer can be safely and efficiently removed with neutral water and which is excellent in water resistance can be realized.

A system for applying a coating composition to a substrate utilizing a high transfer efficiency applicator is provided herein. The system includes a storage device for storing instructions for performing a matching protocol, and one or more data processors configured to execute the instructions to, receive, by one or more data processors, target image data of a target coating, the target image data generated by an electronic imaging device, and apply the target image data to a matching protocol to generate application instructions. The system further includes a high transfer efficiency applicator defining a nozzle orifice. The high transfer efficiency applicator is configured to expel the coating composition through the nozzle orifice to the substrate to form a coating layer. The high transfer efficiency applicator is configured expel the coating composition based on the application instructions.

A system for applying a coating composition to a substrate utilizing a high transfer efficiency applicator is provided herein. The system includes a storage device for storing instructions for performing a matching protocol, and one or more data processors configured to execute the instructions to, receive, by one or more data processors, target image data of a target coating, the target image data generated by an electronic imaging device, and apply the target image data to a matching protocol to generate application instructions. The system further includes a high transfer efficiency applicator defining a nozzle orifice. The high transfer efficiency applicator is configured to expel the coating composition through the nozzle orifice to the substrate to form a coating layer. The high transfer efficiency applicator is configured expel the coating composition based on the application instructions.

Provided herein are methods and compositions comprising a non-toxic ferromagnetic ink composition. Also provided herein are plastic objects containing a surface coating of a food-safe ferromagnetic ink composition. The coating imparts functionality to a plastic object such that the object is capable of being mechanically separated from waste stream using a commercial magnetic separator. The food-safe ink composition, which can be printed using high-speed flexographic, intaglio, offset printing or pad printing, combined with heat transfer printing or hot foil stamping consists of an ingestible magnetically susceptible pigment capable of rendering the printed template with magnetically active properties. The surface of the plastic object described can consist of geometric designs which increase printable surface area without significant changes in dimensions of the said object.

Provided herein are methods and compositions comprising a non-toxic ferromagnetic ink composition. Also provided herein are plastic objects containing a surface coating of a food-safe ferromagnetic ink composition. The coating imparts functionality to a plastic object such that the object is capable of being mechanically separated from waste stream using a commercial magnetic separator. The food-safe ink composition, which can be printed using high-speed flexographic, intaglio, offset printing or pad printing, combined with heat transfer printing or hot foil stamping consists of an ingestible magnetically susceptible pigment capable of rendering the printed template with magnetically active properties. The surface of the plastic object described can consist of geometric designs which increase printable surface area without significant changes in dimensions of the said object.

A printable substrate including a polymer substrate and a coating layer is provided. The coating layer covers the polymer substrate. The thickness of the coating layer is 0.1 μm to 30 μm. The surface impedance value of the coating layer is 10.sup.7 ohms to 10.sup.12 ohms. The maximum printable temperature of the printable substrate is 100° C. to 190° C. After printing on the coating layer of the printable substrate, the result of an adhesion test for the printable substrate is 3B to 5B.

A printable substrate including a polymer substrate and a coating layer is provided. The coating layer covers the polymer substrate. The thickness of the coating layer is 0.1 μm to 30 μm. The surface impedance value of the coating layer is 10.sup.7 ohms to 10.sup.12 ohms. The maximum printable temperature of the printable substrate is 100° C. to 190° C. After printing on the coating layer of the printable substrate, the result of an adhesion test for the printable substrate is 3B to 5B.