The present invention relates to an ink-jet printing method including the step of ejecting a water-based ink containing pigment-containing water-insoluble polymer particles and water onto a printing medium to print characters or images on the printing medium, in which the pigment is at least one pigment selected from the group consisting of C.I. Pigment Red 177, C.I. Pigment Red 254, C.I. Pigment Green 7, C.I. Pigment Green 36 and C.I. Pigment Blue 15:6; the water-insoluble polymer constituting the particles contains a constitutional unit derived from an ionic monomer, a constitutional unit derived from a hydrophobic monomer and a constitutional unit derived from a monomer capable of forming a graft chain; and the printing medium is a low-water absorbing printing medium.

Polyurethanes containing at least one bisphosphonate group, as well as related compositions, articles, and methods, are disclosed.

Polyurethanes containing at least one bisphosphonate group, as well as related compositions, articles, and methods, are disclosed.

Curable ink compositions include a curable aromatic monomer composition, and surface treated metal oxide nanoparticles. The surface treated metal oxide nanoparticles are surface treated with a mixture of at least two silane-functional surface treatment agents, at least one aromatic-containing silane-functional surface treatment agent and at least one silane-functional surface treatment agent comprising a co-polymerizable group. The curable ink composition is inkjet printable, having a viscosity of 30 centipoise or less at a temperature of from room temperature to 60° C., and is free from solvents. The curable ink composition, when printed and cured, has a refractive index of 1.55 or greater, and is optically clear.

A fluid set can include an ink composition having an acidic pH and a crosslinker composition having a basic pH from pH 8 to pH 10. The ink composition can include from 60 wt % to 90 wt % water, from 5 wt % to 30 wt % organic co-solvent, from 1 wt % to 6 wt % pigment, a sulfonated dispersant, and an acrylic polymer binder. The crosslinker composition can include from 70 wt % to 95 wt % water, from 1 wt % to 25 wt % organic co-solvent, and from 0.5 wt % to 5 wt % polycarbodiimide.

There are provided an aqueous pigment dispersion containing a pigment, hydrophilic fumed silica, and an aqueous medium; an ink jet recording ink containing such an aqueous pigment dispersion; and a printed article using the aqueous pigment dispersion. The average particle size of the hydrophilic fumed silica is preferably not more than 250 nm. The amount of the hydrophilic fumed silica is preferably in the range of 20 to 300 mass % relative to the amount of the pigment. The amount of the pigment is preferably in the range of 0.5 to 30 mass % relative to the amount of the whole aqueous pigment dispersion.

There are provided an aqueous pigment dispersion containing a pigment, hydrophilic fumed silica, and an aqueous medium; an ink jet recording ink containing such an aqueous pigment dispersion; and a printed article using the aqueous pigment dispersion. The average particle size of the hydrophilic fumed silica is preferably not more than 250 nm. The amount of the hydrophilic fumed silica is preferably in the range of 20 to 300 mass % relative to the amount of the pigment. The amount of the pigment is preferably in the range of 0.5 to 30 mass % relative to the amount of the whole aqueous pigment dispersion.

The present invention relates to a solvent-based inkjet ink containing at least a pigment, an organic solvent, a binder resin and a dispersant, wherein the dispersant has a weight average molecular weight (Mw) of at least 5,000 but less than 50,000, an acid value (mgKOH/g) of 5 to 20, and an amine value (mgKOH/g) of 5 to 50. The present invention enables a dispersion of low viscosity and good stability to be generated in an extremely short dispersion time, and is able to provide an inkjet ink which forms an ink coating film that suffers no whitening and has superior resistance (abrasion resistance and alcohol resistance).

The present invention relates to a solvent-based inkjet ink containing at least a pigment, an organic solvent, a binder resin and a dispersant, wherein the dispersant has a weight average molecular weight (Mw) of at least 5,000 but less than 50,000, an acid value (mgKOH/g) of 5 to 20, and an amine value (mgKOH/g) of 5 to 50. The present invention enables a dispersion of low viscosity and good stability to be generated in an extremely short dispersion time, and is able to provide an inkjet ink which forms an ink coating film that suffers no whitening and has superior resistance (abrasion resistance and alcohol resistance).

An aqueous dispersion of resin particles comprising a dispersing group covalently bonded to the resin and at least one repeating unit of formula I, II and/or III and which is obtainable by contacting a compound A comprising 2 functional groups selected from the group of functional groups —X—C(=0)-CHR1-C(=0)-R2, —X—C(=0)-C≡C—R2; or —X—C(=0)-CR1=CR2-NR11 R12, wherein X, R1, R2, R3, R11 and R12 have the same meaning as that defined in the claims, with a compound B comprising at least two —NH.sub.2, —NH.sub.3.sup.+ or —N═C=0, with a crosslinking agent C. The invention also includes a method of producing the aqueous dispersion and further relates to an aqueous ink jet ink comprising the resin particles.

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