The invention relates to organic binder resins for aqueous coatings, comprising: a) a polymer P1, bearing reactive groups X1: hydroxyl and Y1: carboxyl with an OH number as a weight percentage of OH ranging from 2% to 5% and an acid number IA mg KOH/g of at least 10, said polymer P1 having a mass Mn1 of less than 25 000, and b) a polymer P2 bearing reactive groups X2: hydroxyl with an OH number as a weight percentage of OH ranging from 0.5% to 2.5%, groups Y2: carboxyl with an acid number IA in mg KOH/g<25, and groups Z2 chosen from acetoxy and/or diacetone and said polymer P2 having a mass Mn2 of greater than 500,000.

The invention also relates to a process for preparing said resin, to a metallic coating composition comprising said resin and metallic pigment, and to the use thereof.

The invention relates to organic binder resins for aqueous coatings, comprising: a) a polymer P1, bearing reactive groups X1: hydroxyl and Y1: carboxyl with an OH number as a weight percentage of OH ranging from 2% to 5% and an acid number IA mg KOH/g of at least 10, said polymer P1 having a mass Mn1 of less than 25 000, and b) a polymer P2 bearing reactive groups X2: hydroxyl with an OH number as a weight percentage of OH ranging from 0.5% to 2.5%, groups Y2: carboxyl with an acid number IA in mg KOH/g<25, and groups Z2 chosen from acetoxy and/or diacetone and said polymer P2 having a mass Mn2 of greater than 500,000.

The invention also relates to a process for preparing said resin, to a metallic coating composition comprising said resin and metallic pigment, and to the use thereof.

The invention relates to compositions of hydroxyl functional acrylic resins (acrylic polyols) comprising a mixture of α,α-branched alkane carboxylic glycidyl esters derived from butene oligomers characterized in that the sum of the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75% on total composition.

A thermal conducting sheet having a high adhesion between layers even if the thermal conducting sheet has a multilayer structure is provided. The thermal conducting sheet including a low-hardness layer and a reinforcing layer laminated on one side or both sides of the low-hardness layer. The reinforcing layer having a hardness greater than a hardness of the low-hardness layer. The low-hardness layer comprises: acrylic polymer, silicon carbide, aluminum hydroxide, magnesium hydroxide, and plasticizer.

A leather finishing composition includes water, a polymeric component, and a non-ionic surfactant component covalently bonded to the polymeric component. Advantageously, the leather finishing composition is substantially free of ionic groups. A method for applying the leather finishing composition to a leather substrate is provided.

To provide an antifogging agent composition having excellent sustainability of antifogging performance.

An anti fogging agent composition includes a copolymer (A), a polyfunctional blocked isocyanate compound (B), and a surfactant (C). The copolymer (A) is formed of 35 to 90 parts by weight of the monomer (A-1), 5 to 60 parts by weight of the monomer (A-2), and 5 to 30 parts by weight of the monomer (A-3) per 100 parts by weight of the copolymer (A). An NCO/OH ratio obtained by dividing an isocyanate group content (NCO) of the polyfunctional blocked isocyanate compound (B) by a hydroxyl group content (OH) of the copolymer (A) is within a range from 0.1 to 1.5. The surfactant (C) includes 1.00 to 10.0 parts by weight of the anionic surfactant (C-1) and 0.01 to 3.00 parts by weight of the cationic surfactant (C-2) per 100 parts by weight of the copolymer (A).

The present invention provides an adhesive film hardly suffering from fisheyes and having excellent mechanical strength and heat resistance as well as good adhesion properties, which can be suitably used as various surface protective films, etc. The present invention relates to an adhesive film comprising a polyester film and an adhesive layer formed on at least one surface of the polyester film, in which the adhesive layer comprises a (meth)acrylic resin comprising a (meth)acrylate unit that comprises an alkyl group having not less than 4 carbon atoms at an ester end thereof, a content of the (meth)acrylate unit in the (meth)acrylic resin being not less than 20% by weight; and an adhesion strength to a polymethyl methacrylate plate of the adhesive layer is not less than 1 mN/cm.

An ultraviolet curing type coating resin composition having all of respective beneficial features of excellent state in chemical resistance, under high temperature, against human skin protection creams containing a mixture of alkyl esters of benzoic acid, as represented by Neutrogena Cream (registered trademark), excellent state in gas barrier property against metal-corrosive gases as represented by sulfur-containing gases, and excellent state in flexibility that accommodates three-dimensional shape forming processing is demanded, includes an ultraviolet curing type coating resin composition containing an unsaturated-group-containing acrylic resin, with a weight average molecular weight of 5000 to 70000, a number of (meth)acrylate functional groups per molecule of 5 to 40, a hydroxyl value of 2 to 200 mgKOH/g, and with a glass transition temperature of 20 to 90° C., a volatile organic solvent, and a photopolymerization initiator.

An ultraviolet curing type coating resin composition having all of respective beneficial features of excellent state in chemical resistance, under high temperature, against human skin protection creams containing a mixture of alkyl esters of benzoic acid, as represented by Neutrogena Cream (registered trademark), excellent state in gas barrier property against metal-corrosive gases as represented by sulfur-containing gases, and excellent state in flexibility that accommodates three-dimensional shape forming processing is demanded, includes an ultraviolet curing type coating resin composition containing an unsaturated-group-containing acrylic resin, with a weight average molecular weight of 5000 to 70000, a number of (meth)acrylate functional groups per molecule of 5 to 40, a hydroxyl value of 2 to 200 mgKOH/g, and with a glass transition temperature of 20 to 90° C., a volatile organic solvent, and a photopolymerization initiator.

The object of the present disclosure is to provide a method for producing a crosslinked polymer by radical polymerization of a monomer composition, by which method a desired crosslinked polymer can be produced in a high solid content with good productivity (also at a low production cost), and a crosslinked polymer obtained by the production method and a coating composition containing the same. A method for producing a crosslinked polymer having a weight average molecular weight of 15000 to 200000, the method comprising step [I] of obtaining a crosslinked polymer (A) by conducting polymerization of a monomer composition comprising 2 to 30% by weight of a polyfunctional methacrylate having 2 to 4 functional groups (a) and 98 to 70% by weight of one or more polymerizable monomers selected from the group consisting of monofunctional (meth)acrylates, (meth)acrylic acid, and monofunctional vinyl aromatic compounds (b) in an organic solvent in the presence of a radical polymerization initiator in a temperature region where the radical polymerization initiator comes to have a half-life of 4 to 18 minutes.