A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes an emulsion-polymerized latex copolymer having copolymer chains of one or more ethylenically-unsaturated monomers and one or more styrene offset monomers. Preferably, the coating composition is substantially free of BPA, PVC, and styrene. The method may also include curing the sprayed coating composition, thereby providing the coating on the interior surface of the food or beverage container.

The present invention relates to a solventborne, pigmented coating composition having a solids fraction of at least 35%, which comprises, based on the total amount of the coating composition, 0.1 to 1.5 wt % of at least one copolymer (A), where the copolymer (A) is obtainable by copolymerization of a mixture of olefinically unsaturated monomers (a) in at least one organic solvent, the mixture of monomers (a) to be polymerized consists of (a1) 10 to 60 mol % of at least one monomer of the formula (I) below

##STR00001##

where R.sub.1═C.sub.1 to C.sub.4 alkoxy, R.sub.2═C.sub.1 to C.sub.4 alkyl, and m=0 to 2, and also (a2) 40 to 90 mol % of at least one further olefinically unsaturated monomer, and the copolymer (A) possesses a glass transition temperature T.sub.g of at least −30° C. The present invention also relates to a method for producing a multicoat paint system using the coating composition, and to the multicoat paint systems themselves.

The present invention relates to a solventborne, pigmented coating composition having a solids fraction of at least 35%, which comprises, based on the total amount of the coating composition, 0.1 to 1.5 wt % of at least one copolymer (A), where the copolymer (A) is obtainable by copolymerization of a mixture of olefinically unsaturated monomers (a) in at least one organic solvent, the mixture of monomers (a) to be polymerized consists of (a1) 10 to 60 mol % of at least one monomer of the formula (I) below

##STR00001##

where R.sub.1═C.sub.1 to C.sub.4 alkoxy, R.sub.2═C.sub.1 to C.sub.4 alkyl, and m=0 to 2, and also (a2) 40 to 90 mol % of at least one further olefinically unsaturated monomer, and the copolymer (A) possesses a glass transition temperature T.sub.g of at least −30° C. The present invention also relates to a method for producing a multicoat paint system using the coating composition, and to the multicoat paint systems themselves.

The present invention relates to a solventborne, pigmented coating composition having a solids fraction of at least 35%, which comprises, based on the total amount of the coating composition, 0.1 to 1.5 wt % of at least one copolymer (A), where the copolymer (A) is obtainable by copolymerization of a mixture of olefinically unsaturated monomers (a) in at least one organic solvent, the mixture of monomers (a) to be polymerized consists of (a1) 10 to 60 mol % of at least one monomer of the formula (I) below

##STR00001##

where R.sub.1═C.sub.1 to C.sub.4 alkoxy, R.sub.2═C.sub.1 to C.sub.4 alkyl, and m=0 to 2, and also (a2) 40 to 90 mol % of at least one further olefinically unsaturated monomer, and the copolymer (A) possesses a glass transition temperature T.sub.g of at least −30° C. The present invention also relates to a method for producing a multicoat paint system using the coating composition, and to the multicoat paint systems themselves.

A polymeric material having a negative photoelastic constant. The polymeric material comprises: (a) a polymer comprising polymerized units of 2-vinylpyridine, 4-vinylpyridine, methyl methacrylate or a combination thereof; (b) a C.sub.9-C.sub.25 aliphatic polycyclic compound; and (c) an organic compound having a boiling point of at least 200° C.

A polymeric material having a negative photoelastic constant. The polymeric material comprises: (a) a polymer comprising polymerized units of 2-vinylpyridine, 4-vinylpyridine, methyl methacrylate or a combination thereof; (b) a C.sub.9-C.sub.25 aliphatic polycyclic compound; and (c) an organic compound having a boiling point of at least 200° C.

A polymeric material having a negative photoelastic constant. The polymeric material comprises: (a) a polymer comprising polymerized units of 2-vinylpyridine, 4-vinylpyridine, methyl methacrylate or a combination thereof; (b) a C.sub.9-C.sub.25 aliphatic polycyclic compound; and (c) an organic compound having a boiling point of at least 200° C.

A three-dimensional object is formed by 3D printing, especially by a binder jetting method, in which particulate material in a powder bed is bonded by a printed adhesive. The particulate materials may be inorganic materials, for example sand or a metal powder, or particulate polymeric materials, for example polymethacrylates or polyamides. For this purpose, polymethacrylates may take the form, for example, of suspension polymers, called bead polymers. Powder bed compositions comprising core-(shell)-shell particles can be used for 3D printing, wherein the core-(shell)-shell particles can swell in contact with the binder during the printing operation.

A three-dimensional object is formed by 3D printing, especially by a binder jetting method, in which particulate material in a powder bed is bonded by a printed adhesive. The particulate materials may be inorganic materials, for example sand or a metal powder, or particulate polymeric materials, for example polymethacrylates or polyamides. For this purpose, polymethacrylates may take the form, for example, of suspension polymers, called bead polymers. Powder bed compositions comprising core-(shell)-shell particles can be used for 3D printing, wherein the core-(shell)-shell particles can swell in contact with the binder during the printing operation.

A resin composition includes an acrylic resin and a graft copolymer having a gel content of 65% to 84%, wherein the graft copolymer is a multistage-polymerized graft copolymer obtained by a multistage polymerization including the polymerization stages (I) to (III). In the polymerization stage (I), a first monomer mixture and a polyfunctional monomer are polymerized in a presence of a primary alkyl mercaptan-based chain transfer agent and/or a secondary alkyl mercaptan-based chain transfer agent to obtain a first hard polymer. In the polymerization stage (II), a second monomer mixture and a polyfunctional monomer are poloymerized to obtain a soft polymer. In the polymerization stage (III), a third monomer mixture and a polyfunctional monomer are polymerized to obtain a second hard polymer.