Patent classifications
C09D133/12
Coating material for formation of matte hard coat, and decorative sheet using same
Embodiments provide a coating material containing: (A) 100 parts by mass of an acrylic curable resin; (B) 5-200 parts by mass of aluminum oxide particles having an average particle size of 1-100 μm; (C) 0.1-20 parts by mass of aluminum oxide fine particles having an average particle size of 1-100 nm; and (D) 1-100 parts by mass of a compound having two or more isocyanate groups per molecule. In one embodiment, the acrylic curable resin (A) includes: (a1) a structural unit derived from a hydroxy group-containing (meth)acrylic acid ester; (a2) a structural unit derived from a vinyl aromatic compound; and (a3) a structural unit derived from a (meth)acrylic acid alkyl ester. In one embodiment, the acrylic curable resin (A) may contain, in addition to the structural units (a1) and (a2): (a3-1) a structural unit derived from methyl methacrylate; and (a3-2) a structural unit derived from an aliphatic (including alicyclic) alkyl ester having 4 or more carbon atoms of a (meth)acrylic acid.
PHOTOSENSITIVE COMPOSITION, FILM, OPTICAL FILTER, SOLID-STATE IMAGING ELEMENT, AND IMAGE DISPLAY DEVICE
Provided are a photosensitive composition including a coloring material A including a pigment, a pigment derivative B, and a dispersant C, in which the pigment derivative B includes a pigment derivative B1 in which a maximum value of a molar absorption coefficient in a wavelength range of 400 to 700 nm is 3000 L.Math.mol.sup.−1.Math.cm.sup.−1 or less, the dispersant C includes a dispersant C1 having an ethylenically unsaturated bond-containing group, and a total content of the coloring material A and the pigment derivative B in a total solid content of the photosensitive composition is 50% by mass or more; a film formed of the photosensitive composition; an optical filter, a solid-state imaging element; and an image display device.
PHOTOSENSITIVE COMPOSITION, FILM, OPTICAL FILTER, SOLID-STATE IMAGING ELEMENT, AND IMAGE DISPLAY DEVICE
Provided are a photosensitive composition including a coloring material A including a pigment, a pigment derivative B, and a dispersant C, in which the pigment derivative B includes a pigment derivative B1 in which a maximum value of a molar absorption coefficient in a wavelength range of 400 to 700 nm is 3000 L.Math.mol.sup.−1.Math.cm.sup.−1 or less, the dispersant C includes a dispersant C1 having an ethylenically unsaturated bond-containing group, and a total content of the coloring material A and the pigment derivative B in a total solid content of the photosensitive composition is 50% by mass or more; a film formed of the photosensitive composition; an optical filter, a solid-state imaging element; and an image display device.
SEALING METHOD
An object of the present invention is to provide a sealing method using a cover film where a problem of odor is not likely to occur and quick drying properties and sealability are high.
The sealing method according to the present invention is a sealing method that is performed using at least a cover film and a sealing solvent, the cover film including a polymer layer provided on a transparent support, in which the sealing solvent is a solvent including at least one kind selected from the group consisting of an ester, an alcohol, a ketone, an ether, and an aromatic hydrocarbon, in a case where the sealing solvent is an ester, an alcohol, a ketone, or an ether, a boiling point of the sealing solvent is 80° C. to 170° C., and in a case where the sealing solvent is an aromatic hydrocarbon, a boiling point of the sealing solvent is 150° C. to 170° C.
WATERBORNE COATING COMPOSITION
The present invention generally relates to the field of cross-linkable aqueous vinyl polymer dispersions, to a coating composition comprising said cross-linkable aqueous vinyl polymer dispersions; to a paint formulation comprising said cross-linkable aqueous vinyl polymer dispersions; and to an article coated with the coating composition or the paint formulation. In particular, the present invention provides an aqueous vinyl polymer dispersion PD which comprises the following polymers: —1) an aqueous dispersion of a vinyl polymer P1 obtainable by free radical emulsion polymerization of a monomers mixture comprising: a) 5 to 20 wt % acid functional ethylenically unsaturated monomers M1 or precursors thereof; b) 5 to 25 wt % ethylenically unsaturated monomers M2 containing a polyethylene glycol or monoalkoxy polyethylene glycol moiety; c) up to 90 wt % of non-ionic ethylenically unsaturated monomers M3 other than M1 or M2; d) 0 to 10 wt % ethylenically unsaturated monomers M4 with a functional group for cross-linking after film-formation; e) 0 to 10 wt % of at least one chain transfer agent CTA; where the sum of the wt. % of M1+M2+M3+M4+CTA=100 wt %; —2) an aqueous dispersion or solution of a vinyl polymer P2 obtainable by free radical copolymerization of: a) from 25 to 95 wt % of a ethylenically unsaturated monomers M5 selected from the group of N-vinyl amides with general structure (I) where R.sub.1 and R.sub.2 are alkyl from C.sub.1 to C.sub.5 and may be connected to form a ring-structure, preferably N-vinyl pyrrolidone or N-vinyl caprolactam; b) from 5 to 75 wt % of non-ionic ethylenically unsaturated monomers M3′ other than M5; c) from 0 to 5 wt % of ethylenically unsaturated monomers M4′ with a functional group for cross-linking after film-formation; d) from 0 to 10 wt % acid functional ethylenically unsaturated monomers M1′ or precursors thereof; e) from 0 to 5 wt % of at least one chain transfer agent CTA′; where the sum of the wt. % of: M5+M3′+M4′+M1′+CTA′=100 wt %; —3) a film-forming vinyl polymer P3 under the form of an aqueous dispersion comprising: i) from 20 to 60 wt % of a water-soluble or water dispersible crosslinkable vinyl oligomer OL obtained by emulsion polymerizing a monomer mixture comprising: 1) at least one acid functional ethylenically unsaturated monomer M1″; 2) at least one ethylenically unsaturated monomer M4″ with functionality for crosslinking upon film-formation, other than M1″; 3) at least one ethylenically unsaturated monomer M3″ other than M1″ and M2″, and 5) optionally, at least one chain transfer agent CTA″, and ii) from 40 to 80 wt % of a high molecular weight vinyl polymer P4 prepared
WATERBORNE COATING COMPOSITION
The present invention generally relates to the field of cross-linkable aqueous vinyl polymer dispersions, to a coating composition comprising said cross-linkable aqueous vinyl polymer dispersions; to a paint formulation comprising said cross-linkable aqueous vinyl polymer dispersions; and to an article coated with the coating composition or the paint formulation. In particular, the present invention provides an aqueous vinyl polymer dispersion PD which comprises the following polymers: —1) an aqueous dispersion of a vinyl polymer P1 obtainable by free radical emulsion polymerization of a monomers mixture comprising: a) 5 to 20 wt % acid functional ethylenically unsaturated monomers M1 or precursors thereof; b) 5 to 25 wt % ethylenically unsaturated monomers M2 containing a polyethylene glycol or monoalkoxy polyethylene glycol moiety; c) up to 90 wt % of non-ionic ethylenically unsaturated monomers M3 other than M1 or M2; d) 0 to 10 wt % ethylenically unsaturated monomers M4 with a functional group for cross-linking after film-formation; e) 0 to 10 wt % of at least one chain transfer agent CTA; where the sum of the wt. % of M1+M2+M3+M4+CTA=100 wt %; —2) an aqueous dispersion or solution of a vinyl polymer P2 obtainable by free radical copolymerization of: a) from 25 to 95 wt % of a ethylenically unsaturated monomers M5 selected from the group of N-vinyl amides with general structure (I) where R.sub.1 and R.sub.2 are alkyl from C.sub.1 to C.sub.5 and may be connected to form a ring-structure, preferably N-vinyl pyrrolidone or N-vinyl caprolactam; b) from 5 to 75 wt % of non-ionic ethylenically unsaturated monomers M3′ other than M5; c) from 0 to 5 wt % of ethylenically unsaturated monomers M4′ with a functional group for cross-linking after film-formation; d) from 0 to 10 wt % acid functional ethylenically unsaturated monomers M1′ or precursors thereof; e) from 0 to 5 wt % of at least one chain transfer agent CTA′; where the sum of the wt. % of: M5+M3′+M4′+M1′+CTA′=100 wt %; —3) a film-forming vinyl polymer P3 under the form of an aqueous dispersion comprising: i) from 20 to 60 wt % of a water-soluble or water dispersible crosslinkable vinyl oligomer OL obtained by emulsion polymerizing a monomer mixture comprising: 1) at least one acid functional ethylenically unsaturated monomer M1″; 2) at least one ethylenically unsaturated monomer M4″ with functionality for crosslinking upon film-formation, other than M1″; 3) at least one ethylenically unsaturated monomer M3″ other than M1″ and M2″, and 5) optionally, at least one chain transfer agent CTA″, and ii) from 40 to 80 wt % of a high molecular weight vinyl polymer P4 prepared
AN ALCOHOL TOLERABLE ACRYLATE POLYMER AND ITS APPLICATION
Described herein is a waterborne emulsion, a method for making the waterborne emulsion, and an application of the waterborne emulsion as a binder for inks. The waterborne emulsion includes an acidic polymer stabilizer and a base polymer. The ink made using the waterborne emulsion shows excellent alcohol tolerance and wet wrinkle resistance.
AN ALCOHOL TOLERABLE ACRYLATE POLYMER AND ITS APPLICATION
Described herein is a waterborne emulsion, a method for making the waterborne emulsion, and an application of the waterborne emulsion as a binder for inks. The waterborne emulsion includes an acidic polymer stabilizer and a base polymer. The ink made using the waterborne emulsion shows excellent alcohol tolerance and wet wrinkle resistance.
Preparation of Cerium (III) Carbonate Dispersion
The present invention relates to a composition comprising a polymer and cerium (III) carbonate. The composition is useful in coatings formulations that include pigments, dyes, or tints, or a combination thereof, to promote color retention and attenuate unwanted color formation in coatings formed from these formulations.
Preparation of Cerium (III) Carbonate Dispersion
The present invention relates to a composition comprising a polymer and cerium (III) carbonate. The composition is useful in coatings formulations that include pigments, dyes, or tints, or a combination thereof, to promote color retention and attenuate unwanted color formation in coatings formed from these formulations.