The present invention provides a binder composition comprising a first binder comprising by dry weight based on total dry weight of the first binder, from 5% to 98% of polymer particles, from 0.3% to 10% of a first polysaccharide, from 0.01% to 5% of a crosslinker, from 0.3% to 6% of a water-soluble metal cation, and from 0.05% to 3% of a cationic polyelectrolyte. The binder composition may further comprise a second binder comprising by dry weight based on total dry weight of the second binder, from 0.3% to 20% of the first polysaccharide, from 0.5% to 20% of a second polysaccharide. And in that case, the wet weight ratio of the first binder to the second binder is from 1:20 to 20:1. The present invention further provides a paint formulation comprising the binder composition.

Compositions are provided which comprises an active hydrogen-containing resin, a flexibilizer and at least one curing agent. The cured compositions possess enhanced flexibility while maintaining hardness, and are highly suitable for applications such as coatings, adhesives, sealants, gaskets, industrial rubber goods, and the like.

Compositions are provided which comprises an active hydrogen-containing resin, a flexibilizer and at least one curing agent. The cured compositions possess enhanced flexibility while maintaining hardness, and are highly suitable for applications such as coatings, adhesives, sealants, gaskets, industrial rubber goods, and the like.

A pressure sensitive adhesive particle includes a styrene resin that contains, as polymerization components, styrene and a vinyl monomer other than styrene; and a (meth)acrylate resin that contains, as polymerization components, at least two (meth)acrylates that account for 90 mass % or more of all polymerization components of the (meth)acrylate resin, in which the pressure sensitive adhesive particle has a sea phase that contains the styrene resin, and island phases that are dispersed in the sea phase and contain the (meth)acrylate resin, the pressure sensitive adhesive particle has at least two glass transition temperatures, and a difference between the lowest glass transition temperature and the highest glass transition temperature is 30° C. or more, and in a cross section of the pressure sensitive adhesive particle, an area ratio of the island phases is 30% or more and 85% or less.

A pressure sensitive adhesive particle includes a styrene resin that contains, as polymerization components, styrene and a vinyl monomer other than styrene; and a (meth)acrylate resin that contains, as polymerization components, at least two (meth)acrylates that account for 90 mass % or more of all polymerization components of the (meth)acrylate resin, in which the pressure sensitive adhesive particle has a sea phase that contains the styrene resin, and island phases that are dispersed in the sea phase and contain the (meth)acrylate resin, the pressure sensitive adhesive particle has at least two glass transition temperatures, and a difference between the lowest glass transition temperature and the highest glass transition temperature is 30° C. or more, and in a cross section of the pressure sensitive adhesive particle, an area ratio of the island phases is 30% or more and 85% or less.

Pressure-responsive particles include pressure-responsive base particles and resin particles, in which the pressure-responsive base particles contain a styrene-based resin that contains styrene and other vinyl monomers as polymerization components and a (meth)acrylic acid ester-based resin that contains at least two kinds of (meth)acrylic acid esters as polymerization components, a ratio of a mass of the (meth)acrylic acid esters to a total mass of polymerization components is 90% by mass or more in the (meth)acrylic acid ester-based resin, the pressure-responsive particles have at least two glass transition temperatures, a difference between a lowest glass transition temperature and a highest glass transition temperature is 30° C. or higher, and a ratio of a mass of the resin particles to a total mass of the pressure-responsive particles is 0.05% by mass or more and 2.0% by mass or less.

Pressure-responsive particles include pressure-responsive base particles and resin particles, in which the pressure-responsive base particles contain a styrene-based resin that contains styrene and other vinyl monomers as polymerization components and a (meth)acrylic acid ester-based resin that contains at least two kinds of (meth)acrylic acid esters as polymerization components, a ratio of a mass of the (meth)acrylic acid esters to a total mass of polymerization components is 90% by mass or more in the (meth)acrylic acid ester-based resin, the pressure-responsive particles have at least two glass transition temperatures, a difference between a lowest glass transition temperature and a highest glass transition temperature is 30° C. or higher, and a ratio of a mass of the resin particles to a total mass of the pressure-responsive particles is 0.05% by mass or more and 2.0% by mass or less.

Pressure-responsive particles include pressure-responsive base particles and silica particles, in which the pressure-responsive base particles contain a styrene-based resin that contains styrene and other vinyl monomers as polymerization components and a (meth)acrylic acid ester-based resin that contains at least two kinds of (meth)acrylic acid esters as polymerization components and in which a ratio of a mass of the (meth)acrylic acid esters to a total mass of polymerization components is 90% by mass or more, the pressure-responsive particles have at least two glass transition temperatures, a difference between a lowest glass transition temperature and a highest glass transition temperature is 30° C. or higher, and a ratio of a surface coating rate Cs2 by the silica particles after application of the following first stress to a surface coating rate Cs1 by the silica particles before application of stress satisfies a relationship of 0.4≤Cs2/Cs1≤0.8, first stress: 10 g of the pressure-responsive particles and 90 g of resin-coated ferrite particles are put in a V-shaped mixer with a rotary container having a volume of 0.5 L and rotated at a rotation speed of 40 rpm for 20 minutes at a temperature of 20° C. and a relative humidity of 50%.

Pressure-responsive particles include pressure-responsive base particles and silica particles, in which the pressure-responsive base particles contain a styrene-based resin that contains styrene and other vinyl monomers as polymerization components and a (meth)acrylic acid ester-based resin that contains at least two kinds of (meth)acrylic acid esters as polymerization components and in which a ratio of a mass of the (meth)acrylic acid esters to a total mass of polymerization components is 90% by mass or more, the pressure-responsive particles have at least two glass transition temperatures, a difference between a lowest glass transition temperature and a highest glass transition temperature is 30° C. or higher, and a ratio of a surface coating rate Cs2 by the silica particles after application of the following first stress to a surface coating rate Cs1 by the silica particles before application of stress satisfies a relationship of 0.4≤Cs2/Cs1≤0.8, first stress: 10 g of the pressure-responsive particles and 90 g of resin-coated ferrite particles are put in a V-shaped mixer with a rotary container having a volume of 0.5 L and rotated at a rotation speed of 40 rpm for 20 minutes at a temperature of 20° C. and a relative humidity of 50%.

A pressure sensitive adhesive particle includes a sea-island structure constituted by a sea containing a resin A and islands containing a resin B1 and a resin B2, in which a viscosity of the resin B1 at 100° C. is smaller than a viscosity of the resin B2 at 100° C.