Methods of treating a subterranean formation including shale include preparing a treatment fluid by mixing an aqueous base fluid and a dry polyvinyl pyrrolidone (PVP) in flake or powder form having a molecular weight between about 500,000 and about 2,000,000 and introducing the treatment fluid in the subterranean formation.

A modified high density brine for use in subterranean drilling and completion operations. The modified high density brine includes a heavy brine and the addition of high density particles. The resultant modified high density brine eliminates the need for toxic, corrosive, and costly ZrBr.sub.2 or cesium formate additions or other ionic additives to boost the density of the modified high density brine to more than 14 lbs./gallon.

A modified high density brine for use in subterranean drilling and completion operations. The modified high density brine includes a heavy brine and the addition of high density particles. The resultant modified high density brine eliminates the need for toxic, corrosive, and costly ZrBr.sub.2 or cesium formate additions or other ionic additives to boost the density of the modified high density brine to more than 14 lbs./gallon.

Heavy fluids are made from calcium bromide and at least one hydrogen bond donor such as a low molecular weight polyol or an organic acid. The combination of a hydrogen bond donor and calcium bromide as a hydrogen bond acceptor in an appropriate molar ratio forms a higher density clear completion fluid at a low temperature not otherwise obtainable with heavy aqueous solutions of calcium bromide such as are used in oilfield wells. A method of making the fluid comprises mixing calcium bromide with the polyol(s) in the presence of water and then reducing the water content, thus forming a heavy fluid. A crystallization inhibitor such as nitrilotriacetamide or a particulate silicate is included in the formulation. When the heavy fluid “freezes,” its physical form is somewhat amorphous and pumpable rather than crystalline. The heavy fluid is useful as a drilling fluid as well as a completion fluid and for other purposes in oil recovery processes where extreme density is beneficial.

Heavy fluids are made from calcium bromide and at least one hydrogen bond donor such as a low molecular weight polyol or an organic acid. The combination of a hydrogen bond donor and calcium bromide as a hydrogen bond acceptor in an appropriate molar ratio forms a higher density clear completion fluid at a low temperature not otherwise obtainable with heavy aqueous solutions of calcium bromide such as are used in oilfield wells. A method of making the fluid comprises mixing calcium bromide with the polyol(s) in the presence of water and then reducing the water content, thus forming a heavy fluid. A crystallization inhibitor such as nitrilotriacetamide or a particulate silicate is included in the formulation. When the heavy fluid “freezes,” its physical form is somewhat amorphous and pumpable rather than crystalline. The heavy fluid is useful as a drilling fluid as well as a completion fluid and for other purposes in oil recovery processes where extreme density is beneficial.

A method of servicing a wellbore in a subterranean formation comprising: placing components of a wellbore servicing fluid in the wellbore and/or subterranean formation, wherein the components comprise a hydrophobically modified relative permeability modifier, a metal carbonate surface modifier, and a (e.g., aqueous) base fluid; and allowing the wellbore servicing fluid to modify the permeability of at least a portion of the wellbore and/or subterranean formation.

A method of servicing a wellbore in a subterranean formation comprising: placing components of a wellbore servicing fluid in the wellbore and/or subterranean formation, wherein the components comprise a hydrophobically modified relative permeability modifier, a metal carbonate surface modifier, and a (e.g., aqueous) base fluid; and allowing the wellbore servicing fluid to modify the permeability of at least a portion of the wellbore and/or subterranean formation.

The present application is directed to a nanocomposite organo gel having a continuous polymeric network structure, wherein polymer chains are held together by ionic interaction between polymer chain ends, interparticle chain entanglements, layered silicate surface modifier, ionic salt, and layered silicate. The present application is also directed to methods of making and using the nanocomposite organo gel.

The present application is directed to a nanocomposite organo gel having a continuous polymeric network structure, wherein polymer chains are held together by ionic interaction between polymer chain ends, interparticle chain entanglements, layered silicate surface modifier, ionic salt, and layered silicate. The present application is also directed to methods of making and using the nanocomposite organo gel.

A composition of a lubricant including a GTL hydrocarbon, fatty acid amine, and styrene block polymer.