A variety of fluid loss control compositions and methods are provided for controlling fluid loss in a cementing operation. As described herein, polyelectrolyte complex nanoparticles and fluid loss control compositions containing polyelectrolyte complex nanoparticles can be effective for fluid loss control in a variety of cementing operations. Methods of making and methods of using the electrolyte complex nanoparticles and fluid loss control compositions containing polyelectrolyte complex nanoparticles are also provided. The polyelectrolyte complex nanoparticles can include a polycation polymer such as a branched chain polyethylenimine, and a polyanion polymer such as polyacrylic acid or poly(vinylsulfonic) acid. The polyelectrolyte complex nanoparticles can contain additional additives such as metal ions or fluid loss additives such as a cellulose polymer.

A variety of fluid loss control compositions and methods are provided for controlling fluid loss in a cementing operation. As described herein, polyelectrolyte complex nanoparticles and fluid loss control compositions containing polyelectrolyte complex nanoparticles can be effective for fluid loss control in a variety of cementing operations. Methods of making and methods of using the electrolyte complex nanoparticles and fluid loss control compositions containing polyelectrolyte complex nanoparticles are also provided. The polyelectrolyte complex nanoparticles can include a polycation polymer such as a branched chain polyethylenimine, and a polyanion polymer such as polyacrylic acid or poly(vinylsulfonic) acid. The polyelectrolyte complex nanoparticles can contain additional additives such as metal ions or fluid loss additives such as a cellulose polymer.

A method of servicing a wellbore may comprise providing a treatment fluid comprising a carrier fluid and hollow particles, wherein the hollow particles may comprise an outer wall that encapsulates a gas. The method may further comprise introducing the treatment fluid into a wellbore annulus and trapping at least a portion of the treatment fluid in the wellbore annulus. The carrier fluid may degrade the outer wall of the hollow particles in the wellbore annulus and release the encapsulated gas.

A method of servicing a wellbore may comprise providing a treatment fluid comprising a carrier fluid and hollow particles, wherein the hollow particles may comprise an outer wall that encapsulates a gas. The method may further comprise introducing the treatment fluid into a wellbore annulus and trapping at least a portion of the treatment fluid in the wellbore annulus. The carrier fluid may degrade the outer wall of the hollow particles in the wellbore annulus and release the encapsulated gas.

A cement composition can include water; cement, wherein less than 75 w/w % of the total amount of the cement is Portland cement; and a fluid loss additive, wherein the fluid loss additive comprises a polymer network having at least one branching point formed with a monomer and a cross-linking agent that comprises at least three active functional groups. The cement can also be a non-Portland cement. The monomer can be a vinyl ester-based monomer that is polymerized with the cross-linking agent to form the polymer network. The cement composition can be used in an oil and gas operation.

A cement composition can include water; cement, wherein less than 75 w/w % of the total amount of the cement is Portland cement; and a fluid loss additive, wherein the fluid loss additive comprises a polymer network having at least one branching point formed with a monomer and a cross-linking agent that comprises at least three active functional groups. The cement can also be a non-Portland cement. The monomer can be a vinyl ester-based monomer that is polymerized with the cross-linking agent to form the polymer network. The cement composition can be used in an oil and gas operation.

In order to substantially reduce friction during drilling operations, specialized lubricants need to be added to drilling fluid recipes. In general, lubricants reduce friction by forming a thin film of liquid that separates the solid surfaces in contact. The primary objective of this research is to evaluate the performance of enhanced activated sludge (EAS) as a lubricant in drilling fluids. EAS is activated sludge rich in lipids. The mixed consortium of microorganism in waste water treatment facilities in grown under a high carbon/nitrogen ratio to trigger lipid accumulation. Performance of EAS as drilling fluid additive was compared with commercial lubricants in terms of lubricity and flow properties. Lubricants were evaluated using water-based drilling mud at lubricant concentrations of 1.78, 3.11, 4.43, and 6.17 pounds per barrel (ppb). Experiments were carried out in a standard lubricity meter. The lubricity meter tests the ability of the lubricant in the drilling mud to reduce friction. Other parameters measured were plastic viscosity, gel strength, fluid loss, mud cake thickness, sand content, methylene blue test (MBT), alkalinity, and chlorides. These findings show that EAS will improve the properties of water-based drilling mud.

In order to substantially reduce friction during drilling operations, specialized lubricants need to be added to drilling fluid recipes. In general, lubricants reduce friction by forming a thin film of liquid that separates the solid surfaces in contact. The primary objective of this research is to evaluate the performance of enhanced activated sludge (EAS) as a lubricant in drilling fluids. EAS is activated sludge rich in lipids. The mixed consortium of microorganism in waste water treatment facilities in grown under a high carbon/nitrogen ratio to trigger lipid accumulation. Performance of EAS as drilling fluid additive was compared with commercial lubricants in terms of lubricity and flow properties. Lubricants were evaluated using water-based drilling mud at lubricant concentrations of 1.78, 3.11, 4.43, and 6.17 pounds per barrel (ppb). Experiments were carried out in a standard lubricity meter. The lubricity meter tests the ability of the lubricant in the drilling mud to reduce friction. Other parameters measured were plastic viscosity, gel strength, fluid loss, mud cake thickness, sand content, methylene blue test (MBT), alkalinity, and chlorides. These findings show that EAS will improve the properties of water-based drilling mud.

The embodiments described herein generally relate to methods and chemical compositions for use with wellbore treatment processes. In one embodiment, a composition is provided comprising a cementitious material, a drilling fluid, or combinations thereof, and an additive composition comprising one or more components selected from the group of an aqueous insoluble lignin, a coke fine, a random tetracopolymer having the formula styrene-butadiene-acrylic-fumaric acid, a polyvinyl acetate, a surfactant composition, and combinations thereof.

The embodiments described herein generally relate to methods and chemical compositions for use with wellbore treatment processes. In one embodiment, a composition is provided comprising a cementitious material, a drilling fluid, or combinations thereof, and an additive composition comprising one or more components selected from the group of an aqueous insoluble lignin, a coke fine, a random tetracopolymer having the formula styrene-butadiene-acrylic-fumaric acid, a polyvinyl acetate, a surfactant composition, and combinations thereof.