The present disclosure relates to a laminated structure comprising a film comprising a light-emitting perovskite compound, a first substrate, and a second substrate, in which the film is positioned between the first substrate and the second substrate.

A scintillation crystal can include a cesium halide that is co-doped with thallium and another element. In an embodiment, the scintillation crystal can include CsX:Tl, Me, where X represents a halogen, and Me represents a Group 5A element. In a particular embodiment, the scintillation crystal may have a cesium iodide host material, a first dopant including a thallium cation, and a second dopant including an antimony cation.

A scintillator, a preparation method therefor, and an application thereof are disclosed wherein the scintillator has a chemical formula of Tl.sub.aA.sub.bB.sub.c:yCe, wherein: A is at least one rare earth element selected from trivalent rare earth elements; B is at least one halogen element selected from halogen elements; a=1, b=2 and c=7, a=2, b=1 and c=5, or a=3, b=1 and c=6; and y is greater than or equal to 0 and less than or equal to 0.5. According to another embodiment, the scintillator has a chemical formula of Tl.sub.aA.sub.bB.sub.c:yEu, wherein: A is an alkaline earth metal element; B is a halogen element; a=1, b=2 and c=5, or a=1, b=1 and c=3; and y is greater than or equal to 0 mol % and less than or equal to 50 mol %.

The present invention relates to a mixture of a compound (1) and a compound (2). The compound (1) is a light-emitting perovskite compound which includes components A, B, and X, and the compound (2) is a light-emitting indium compound or light-emitting cadmium compound. The component A indicates a component positioned at each vertex of a hexahedron having the component B at the center in a perovskite type crystal structure and is a monovalent cation, the component X indicates a component positioned at each vertex of an octahedron having the component B at the center in the perovskite type crystal structure and is one or more kinds of anions selected from the group consisting of a halide ion and a thiocyanate ion, and the component B indicates a component positioned at the centers of the hexahedron where the component A is disposed at each vertex and the octahedron where the component X is disposed at each vertex in the perovskite type crystal structure and is a metal ion.

A scintillator panel includes a substrate made of an organic material, a barrier layer formed on the substrate and including thallium iodide as a main component, and a scintillator layer formed on the barrier layer and including cesium iodide as a main component. According to this scintillator panel, moisture resistance can be improved by providing the barrier layer between the substrate and the scintillator layer.

Mixed halide scintillation materials of the general formula AB.sub.(1−y)M.sub.yX′.sub.wX″.sub.(3−w), where 0≤y≤1, 0.05≤w≤1, A may be an alkali metal, B may be an alkali earth metal, and X′ and X″ may be two different halogen atoms, and of the general formula A.sub.(1−y)BM.sub.yX′.sub.wX″.sub.(3−w), where 0≤y≤1, 0.05≤w≤1, A maybe an alkali metal, B may be an alkali earth metal, and X′ and X″ are two different halogen atoms. The scintillation materials of formula (1) include a divalent external activator, M, such as Eu.sup.2+ or Yb.sup.2+. The scintillation materials of formula (2) include a monovalent external activator, M, such as Tl.sup.+, Na.sup.+ and In.sup.+.

A scintillator panel includes a substrate made of an organic material, a barrier layer formed on the substrate and including thallium iodide as a main component, and a scintillator layer formed on the barrier layer and including cesium iodide as a main component. According to this scintillator panel, moisture resistance can be improved by providing the barrier layer between the substrate and the scintillator layer.

The present invention discloses a multi-element perovskite material, and a single crystal, powder and a film thereof, as well as the applications thereof in photoluminescence and electroluminescence, in which the multi-element perovskite material is a multi-element fully-inorganic salt of non-lead metal halide and has a perovskite structure; and the chemical formula of the multi-element perovskite material is Cs.sub.2Na.sub.xAg.sub.1-xIn.sub.yBi.sub.1-yCl.sub.6, wherein 0≤x≤1, 0≤y≤1. Meanwhile, based on the very strong self-trapped exciton states of the double perovskite, the present invention proposes a high-efficiency single-phase broadband phosphor and an electroluminescent device.

A scintillation crystal can include a cesium halide that is co-doped with thallium and another element. In an embodiment, the scintillation crystal can include CsX:Tl, Me, where X represents a halogen, and Me represents a Group 5A element. In a particular embodiment, the scintillation crystal may have a cesium iodide host material, a first dopant including a thallium cation, and a second dopant including an antimony cation.

The present invention relates to a mixture of a compound (1) and a compound (2). The compound (1) is a light-emitting perovskite compound which includes components A, B, and X, and the compound (2) is a light-emitting indium compound or light-emitting cadmium compound. The component A indicates a component positioned at each vertex of a hexahedron having the component B at the center in a perovskite type crystal structure and is a monovalent cation, the component X indicates a component positioned at each vertex of an octahedron having the component B at the center in the perovskite type crystal structure and is one or more kinds of anions selected from the group consisting of a halide ion and a thiocyanate ion, and the component B indicates a component positioned at the centers of the hexahedron where the component A is disposed at each vertex and the octahedron where the component X is disposed at each vertex in the perovskite type crystal structure and is a metal ion.