To provide a semiconductor light emitting device which is capable of accomplishing a broad color reproducibility for an entire image without losing brightness of the entire image.

A light source provided on a backlight for a color image display device has a semiconductor light emitting device comprising a solid light emitting device to emit light in a blue or deep blue region or in an ultraviolet region and phosphors, in combination. The phosphors comprise a green emitting phosphor and a red emitting phosphor. The green emitting phosphor and the red emitting phosphor are ones, of which the rate of change of the emission peak intensity at 100? C. to the emission intensity at 25? C., when the wavelength of the excitation light is 400 nm or 455 nm, is at most 40%.

To provide a semiconductor light emitting device which is capable of accomplishing a broad color reproducibility for an entire image without losing brightness of the entire image. A light source provided on a backlight for a color image display device has a semiconductor light emitting device comprising a solid light emitting device to emit light in a blue or deep blue region or in an ultraviolet region and phosphors, in combination. The phosphors comprise a green emitting phosphor and a red emitting phosphor. The green emitting phosphor and the red emitting phosphor are ones, of which the rate of change of the emission peak intensity at 100? C. to the emission intensity at 25? C., when the wavelength of the excitation light is 400 nm or 455 nm, is at most 40%.

The present invention relates to a metal fluoride red phosphor and an application of the phosphor as a light emitting element, the metal fluoride red phosphor having a tetragonal crystal structure of a novel composition, and emitting light in the red color wavelength by being excited by ultraviolet rays or a blue excitation source, thereby being usefully applicable to a light emitting element such as a light emitting diode, a laser diode, a surface emitting laser diode, an inorganic electroluminescence element, and an organic electroluminescence element.

The present invention provides a method for producing a fluoride fluorescent material, comprising: contacting a fluoride particles represented by the following general formula (I):
K.sub.2[M.sub.1aMn.sup.4+.sub.aF.sub.6](I)
wherein M is at least one member selected from the group consisting of elements belonging to Groups 4 and 14 of the Periodic Table, and a satisfies the relationship: 0<a<0.2; with a solution containing alkaline earth metal ions in the presence of a reducing agent to form an alkaline earth metal fluoride on the surface of the fluoride particles.

A fluoride phosphor including a sheet-like crystal and a manufacturing method and an application therefore are disclosed. The fluoride phosphor has a chemical formula A.sub.2[MF.sub.6]:Mn.sup.4+, with Mn.sup.4+ as an activator. The A is Li, Na, K, Rb, Cs, NH4 or a combination thereof. The M is Ge, Si, Sn, Ti, Zr or a combination thereof. The sheet-like crystal has a thickness d. A crystal flat surface of the sheet-like crystal has a maximum length a. The maximum length a is defined as a distance between two end points on an edge of the crystal flat surface and farthest from each other. 8a/d35.

According to one embodiment, a scintillator includes a host material having the chemical formula: A.sub.2BX.sub.6, where A includes a monovalent ion, B includes a tetravalent ion, and X includes a halide ion.

The present invention provides a phosphor with a preferred orientation represented by the following formula: A.sub.2[MF.sub.6]:Mn.sup.4+, wherein A is selected from a group consisting of Li, Na, K, Rb, Cs, and NH.sub.4, M is selected from a group consisting of Ge, Si, Sn, Ti, and Zr. The preferred orientation is a (001)/(011) preferred orientation. The present invention also provides a method for fabricating the above phosphor. The present invention further provides a light-emitting element package structure employing the same.

To provide a semiconductor light emitting device which is capable of accomplishing a broad color reproducibility for an entire image without losing brightness of the entire image. A light source provided on a backlight for a color image display device has a semiconductor light emitting device comprising a solid light emitting device to emit light in a blue or deep blue region or in an ultraviolet region and phosphors, in combination. The phosphors comprise a green emitting phosphor and a red emitting phosphor. The green emitting phosphor and the red emitting phosphor are ones, of which the rate of change of the emission peak intensity at 100? C. to the emission intensity at 25? C., when the wavelength of the excitation light is 400 nm or 455 nm, is at most 40%.

Synthesizing a color stable Mn.sup.4+ doped phosphor by contacting a gaseous fluorine-containing oxidizing agent with a precursor of: A.sub.aB.sub.bC.sub.cD.sub.dX.sub.x:Mn.sup.4+; A.sub.aiB.sub.biC.sub.ciD.sub.dX.sub.xY.sub.d:Mn.sup.4+; A.sup.1.sub.3G.sub.2?m?nMn.sub.mMg.sub.nLi.sub.3F.sub.12O.sub.p; or AZF.sub.4:Mn.sup.4+. Where A is Li, Na, K, Rb, Cs, or a combination; B is Be, Mg, Ca, Sr, Ba, or a combination; C is Sc, Y, B, Al, Ga, In, Tl, or a combination; D is Ti, Zr, Hf, Rf, Si, Ge, Sn, Pb, or a combination; X is F or a combination of F and one of Br, Cl, and I; Y is O, or a combination of O and one of S and Se; A.sup.1 is Na or K, or a combination; G is Al, B, Sc, Fe, Cr, Ti, In, or a combination; Z is La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Sc, Y, In, or a combination.

The present invention provides a method for producing a fluoride fluorescent material, comprising: contacting a fluoride particles represented by the following general formula (I):

K.sub.2[M.sub.1aMn.sup.4+.sub.aF.sub.6](I)

wherein M is at least one member selected from the group consisting of elements belonging to Groups 4 and 14 of the Periodic Table, and a satisfies the relationship: 0<a<0.2; with a solution containing alkaline earth metal ions in the presence of a reducing agent to form an alkaline earth metal fluoride and less than tetravalent manganese ions on the surface of the fluoride particles.