A phosphor is specified. The phosphor has the general molecular formula: (MA).sub.a(MB).sub.b(MC).sub.c(MD).sub.d(TA).sub.e(TB).sub.f(TC).sub.g(TD).sub.h(TE).sub.i(TF).sub.j(XA).sub.k(XB).sub.l(XC).sub.m(XD).sub.n:E. In this case, MA is selected from a group of monovalent metals, MB is selected from a group of divalent metals, MC is selected from a group of trivalent metals, MD is selected from a group of tetravalent metals, TA is selected from a group of monovalent metals, TB is selected from a group of divalent metals, TC is selected from a group of trivalent metals, TD is selected from a group of tetravalent metals, TE is selected from a group of pentavalent elements, TF is selected from a group of hexavalent elements, XA is selected from a group of elements which comprises halogens, XB is selected from a group of elements which comprises O, S and combinations thereof, -E=Eu, Ce, Yb and/or Mn, XC═N and XD=C. The following furthermore hold true: a+b+c+d=t; e+f+g+h+i+j=u; k+l+m+n=v; a+2b+3c+4d+e+2f+3g+4h+5i+6j−k−2l−3m−4n=w; 0.8≤t≤1; 3.5≤u≤4; 3.5≤v≤4; (−0.2)≤w≤0.2 and 0≤m<0.875 v and/or v≥l>0.125 v.

Provided is a sintered body that has high heat dissipation and from which light can be emitted when excited by an excitation light source, a light emitting device, a wavelength conversion member, and a method for manufacturing the sintered body.

The sintered body includes aluminum nitride and europium, has a thermal diffusivity of 27.0 mm.sup.2/s or greater as measured by a laser flash method at 25° C., and emits green light when excited by an excitation light source.

The invention provides a method for providing a luminescent particle (100) with a hybrid coating, the method comprising: (i) providing a luminescent core (102) comprising a primer layer (105) on the luminescent core (102); (ii) providing a main ALD coating layer (120) onto the primer layer (105) by application of a main atomic layer deposition process, the main ALD coating layer (120) comprising a multilayer (1120) with two or more layers (1121) having different chemical compositions, and wherein in the main atomic layer deposition process a metal oxide precursor is selected from a group of metal oxide precursors comprising Al, Zn, Hf, Ta, Zr, Ti, Sn, Nb, Y, Ga, and V; (iii) providing a main sol-gel coating layer (130) onto the main ALD-coating layer (120) by application of a main sol-gel coating process, the main sol-gel coating layer (130) having a chemical composition different from one or more of the layers (1121) of the multilayer (1120).

Solution for use in filling micrometer-size cavities (10), the solution comprising a first solvent, a first polymer (102) having a first molecular weight, a second polymer (103) having a second molecular weight, luminophores (101) and a surfactant, the second molecular weight being 10 to 50 times greater than the first molecular weight.

The invention provides a lighting device configured to provide red lighting device light, the lighting device comprising: (i) a first light source configured to provide first light source light having a peak wavelength (λls); (ii) a first red luminescent material configured to absorb at least part of the first light source light and to convert into first red luminescent material light having a first red emission peak wavelength (λm1), the first red luminescent material having an excitation maximum (λx1); (iii) a second red luminescent material configured to absorb at least part of the first light source light and to convert into second red luminescent material light having a second red emission peak wavelength (λm2), the second red luminescent material having a second excitation maximum (λx2); and wherein the first luminescent material and the second luminescent material are Eu2+ based, and wherein λm1<λm2, λx1<λls and λx2>λls.

A method of producing a nitride fluorescent material is provided. The nitride fluorescent material undergoes less change in chromaticity under a high-temperature and high-humidity condition and are excellent in durability. The nitride fluorescent material has a composition containing: at least one element selected from the group consisting of Ca, Sr, Ba, and Mg; at least one element selected from the group consisting of Li, Na, and K; at least one element selected from the group consisting of Eu, Ce, Tb, and Mn; Al; and N. The method includes: preparing a calcined product having the composition, bringing the calcined product in contact with a fluorine-containing substance, and heat-treating the calcined product at a temperature of 200° C. or more and 500° C. or less. A light emitting device using the nitride fluorescent material is also provided.

A lighting device is specified. The lighting device comprises a phosphor having the general molecular formula (MA).sub.a(MB).sub.b(MC).sub.c(MD).sub.d(TA).sub.e(TB).sub.f(TC).sub.g(TD).sub.h(TE).sub.i(TF).sub.j(XA).sub.k(XB).sub.l(XC).sub.m(XD).sub.n:E. In this case, MA is selected from a group of monovalent metals, MB is selected from a group of divalent metals, MC is selected from a group of trivalent metals, MD is selected from a group of tetravalent metals, TA is selected from a group of monovalent metals, TB is selected from a group of divalent metals, TC is selected from a group of trivalent metals, TD is selected from a group of tetravalent metals, TE is selected from a group of pentavalent elements, TF is selected from a group of hexavalent elements, XA is selected from a group of elements which comprises halogens, XB is selected from a group of elements which comprises O, S and combinations thereof, XC=N and XD=C and E=Eu, Ce, Yb and/or Mn. The following furthermore hold true: a+b+c+d=t; e+f+g+h+i+j=u; k+l+m+n=v; a+2b+3c+4d+e+2f+3g+4h+5i+6j−k−2l−3m−4n=w; 0.8≤t≤1; −3.5≤u≤4; 3.5≤v≤4; (−0.2) w≤0.2 and 0≤m<0.875 v and/or v≥l>0.125 v.

The invention provides a lighting device (100) comprising: a first solid state light source (10), configured to provide UV radiation (11) having a wavelength selected from the range of 380-420 nm; a second solid state light source (20), configured to provide blue light (21) having a wavelength selected from the range of 440-470 nm; a wavelength converter element (200), wherein the wavelength converter element (200) comprises: a first luminescent material (210), configured to provide upon excitation with the blue light (21) of the second solid state light source (20) first luminescent material light (211) having a wavelength selected from the green and yellow wavelength range, and wherein the first luminescent material excitability for UV radiation (11) is lower than for blue light (21); and a second luminescent material (220), configured to provide upon excitation with the blue light (21) of the second solid state light source (20) second luminescent material light (221) having a wavelength selected from the orange and red wavelength range, and wherein the second luminescent material excitability for UV radiation (11) is lowerthan for blue light (21).

The invention provides a method for providing a luminescent particle with a hybrid coating, the method comprising: (i) providing a luminescent core comprising a primer layer on the luminescent core; (ii) providing a main ALD coating layer onto the primer layer by application of a main atomic layer deposition process, the main ALD coating layer comprising a multilayer with two or more layers having different chemical compositions, and wherein in the main atomic layer deposition process a metal oxide precursor is selected from a group of metal oxide precursors comprising Al, Zn, Hf, Ta, Zr, Ti, Sn, Nb, Y, Ga, and V; (iii) providing a main sol-gel coating layer onto the main ALD-coating layer by application of a main sol-gel coating process, the main sol-gel coating layer having a chemical composition different from one or more of the layers of the multilayer.

A white LED including red phosphor, at least one blue LED chip and at least one green LED chip, wherein a red light, a blue light and a green light are mixed simultaneously to produce a white light. The red phosphor comprises a first red phosphor and a second red phosphor. The first red phosphor is made from a substance having structure formula M.sub.2AX.sub.6:Mn.sup.4+, wherein the element M is selected from Li, Na, K, Rb or Cs, the element A is selected from Ti, Si, Ge or Zr, and the element X is selected from F, Cl or Br; the ratio of the second red phosphor to the red phosphor ranges from 0.01% to 15%. Further provided is a backlight module. The adjustably colored points of a device comprising M.sub.2AX.sub.6:Mn.sup.4+ are achieved by adding a second red phosphor to the red phosphor comprising M.sub.2AX.sub.6:Mn.sup.4+.