The present invention relates to a liquid crystal composition, which is a liquid crystal composition containing a compound represented by General Formula (II-1) as an anti-oxidizing agent for a liquid crystal composition containing the compound represented by General Formula (II-1) and also as a first component, and a compound represented by General Formula (K) as a second component. The compound represented by General Formula (II-1) enables obtainment of a working effect of the anti-oxidizing agent, and therefore it allows provision of a liquid crystal composition containing the anti-oxidizing agent which has improved reliability like low temperature stability, while the high dielectric anisotropy is maintained.

The disclosure provides a reactive perpendicular aligned organosilicon material and a manufacture method of a liquid crystal display panel, a general structural formula of the reactive perpendicular aligned organosilicon material is A-R, A is SiCl.sub.3; R represents a linear chained or a branched chained alkyl group with 520 C atoms, a CH.sub.2 group in the alkyl group is substituted by a phenyl group, a naphthenic base, CONH, COO, OCO, S, CO or CHCH, or a F atom or a Cl atom substitutes for a H atom in the alkyl group. A Cl atom in the reactive perpendicular aligned organosilicon material and OH on a surface of the substrate without a PI film can form a hydrogen bond, leading to vertical arrangement of liquid crystal molecules.

The invention relates to compounds of the formula I,

##STR00001##

in which

R, A, Z, m, L.sup.1, L.sup.2, L.sup.3 and X have the meanings indicated in Claim 1, to a process for the preparation thereof, and to liquid-crystalline media comprising at least one compound of the formula I and to electro-optical displays containing a liquid-crystalline medium of this type.

The present invention relates to polymerisable compounds, to processes and intermediates for the preparation thereof, to liquid-crystal (LC) media comprising them, and to the use of the polymerisable compounds and LC media for optical, electro-optical and electronic purposes, in particular in LC displays, especially in LC displays of the polymer sustained alignment type, or a stabilisers in LC media and LC displays.

A compound represented by the General Formula (I) as defined herein, in which, in the General Formula (I), P.sup.1 and P.sup.2 each independently represent a hydrogen atom, CN, NCS, or a polymerizable group, Sp.sup.1 and Sp.sup.2 each independently represent a single bond or a divalent linking group as defined herein, Z.sup.1, Z.sup.2 and Z.sup.3 each independently represent a particular linking group as defined herein, X.sup.1 and X.sup.2 each independently represent a single bond or S as defined herein, k represents an integer of 2 to 4, m and n each independently represent an integer of 0 to 3 as defined herein, A.sup.1, A.sup.2, A.sup.3, and A.sup.4 each independently represent a particular group as defined herein is provided.

A polymerizable composition excellent in solubility and having high storage stability with no crystal precipitation or the like; a polymerizable composition capable of being formed into a polymer excellent in alignment performance and leveling performance, hardly having defects, cissing and unevenness and hardly causing appearance failure owing to surfactant offset; and a polymer, an optically anisotropic body, a display element, a light-emitting element and the like using the polymerizable composition are provided. Specifically, the invention provides a polymerizable composition containing a) one or two or more polymerizable compounds each having one polymerizable group or two or more polymerizable groups and satisfying a formula (I) Re(450 nm)/Re(550 nm)<1.0 (I), and b) one or two or more compounds represented by the general formula (B). In addition, the invention provides a polymer, an optically anisotropic body, a display element, a light-emitting element and the like using the polymerizable composition.

There is provided a polymerizable composition, by which discoloration or alignment defects are less likely to occur when a filmy polymer, which is obtained by adding a polymerizable compound to the polymerizable composition and polymerizing this composition, is irradiated with ultraviolet light. There are also provided a polymer obtained by polymerizing the polymerizable composition, and an optically anisotropic body using the polymer. The present invention provides a polymerizable low-wavelength dispersive or polymerizable reverse-wavelength dispersive compound having a partial structure represented by Formula (Z-0). Further, the present invention provides a composition containing the compound; a polymer obtained by polymerizing the composition; and an optically anisotropic body obtained by using the polymer.

##STR00001##

To suppress a phenomenon where an optical axis of the optically anisotropic layer is tilted when the optically anisotropic layer is produced by using a liquid crystalline compound showing smectic phase as a materials showing a higher level of orderliness. An optically anisotropic layer wherein a polymerizable composition, containing one or more polymerizable rod-like liquid crystal compound showing a smectic phase, is fixed in a state of smectic phase, and a direction of maximum refractive index of the optically anisotropic layer is inclined at 10 or smaller to the surface of the optically anisotropic layer, a method for manufacturing the same, a laminate and a method for manufacturing the same, a polarizing plate, a liquid crystal display device, and an organic EL display device.

An object of the present invention is to provide a composition that realizes high n, has a wide liquid crystal phase temperature range, small viscosity, excellent low-temperature solubility, and high resistivity and voltage holding ratio, and is stable against heat and light, and to provide a liquid crystal composition having an excellent lens effect and excellent chemical stability using the composition, and a liquid crystal display device and a liquid crystal lens that use the liquid crystal composition. The present invention provides a liquid crystal composition that contains one or two or more compounds represented by general formula (i) and one or two or more compounds represented by general formula (ii), a liquid crystal display device using the liquid crystal composition, a liquid crystal lens using the liquid crystal composition, and a birefringence lens for stereoscopic image display using the liquid crystal composition.

Compounds of formula I ##STR00001##
their use in liquid-crystalline media, for example, for the phase shifting of microwaves for tunable phased-array antennae, and their use for high-frequency components, in particular antennae, especially for the gigahertz range.