C09K19/3809

ANISOTROPIC THERMALLY CONDUCTIVE POLYMERS AND METHODS OF MAKING AND USING THE SAME
20230332047 · 2023-10-19 ·

Some variations provide an anisotropic thermally conductive polymer composition comprising a plurality of polarizable, thermotropic main-chain liquid-crystal polymer molecules with crystalline domains. The liquid-crystal polymer molecules are in a nematic phase or a smectic phase, and at least 80% of the crystalline domains are aligned along a crystal axis. A method of making an anisotropic thermally conductive polymer composition comprises: synthesizing or obtaining a polymer containing polarizable domains; heating the polymer to form a polymer melt; cooling the polymer melt to form a thermotropic liquid-crystal polymer; exposing the thermotropic liquid-crystal polymer to an electrical field, thereby aligning the polarizable domains along a crystal axis; and recovering the thermotropic liquid-crystal polymer as an anisotropic thermally conductive polymer composition. The polymer composition may be formed into an object characterized by thermal conductivity along the minimum dimension that is at least three times greater than thermal conductivity along the maximum dimension.

POROUS LIQUID CRYSTAL POLYMER SHEET, METAL LAYER-ATTACHED POROUS LIQUID CRYSTAL POLYMER SHEET, AND ELECTRONIC CIRCUIT BOARD
20230295507 · 2023-09-21 ·

A porous liquid crystal polymer sheet that includes: a resin sheet having pores and containing a first component composed of a liquid crystal polymer and a second component accounting for a highest weight percentage of the resin sheet except for the first component, wherein, when a region containing the second component is defined as a first region, and a region having a smaller content of the second component than the first region is defined as a second region in the porous liquid crystal polymer sheet, the first region has higher compressive strength than the second region, the second component has an average particle size smaller than an average pore size of the pores, and the second component is not in contact with an inside of the pores.

POROUS LIQUID CRYSTAL POLYMER SHEET, METAL LAYER-ATTACHED POROUS LIQUID CRYSTAL POLYMER SHEET, AND ELECTRONIC CIRCUIT BOARD
20230295506 · 2023-09-21 ·

A porous liquid crystal polymer sheet that includes a resin sheet containing a liquid crystal polymer and having pores. The porous liquid crystal polymer sheet has a melt viscosity of 20 Pa.Math.s or more under the conditions of a shear rate of 1000 s.sup.−1 and a measurement temperature that is 20° C. higher than a melting point of the resin sheet.

ANISOTROPIC THERMALLY CONDUCTIVE POLYMERS WITH DYNAMIC MOLECULAR WEIGHT, AND METHODS OF MAKING THE SAME
20230137249 · 2023-05-04 ·

Some variations provide an oligomer composition comprising: polarizable first thermotropic liquid-crystal oligomer molecules (preferably urethanes or ureas) containing first triggerable reactive end groups, wherein the first triggerable reactive end groups are selected from the group consisting of hydroxyl, isocyanate, blocked isocyanate, acrylate, epoxide, amine, vinyl, ester, thiol, conjugated diene, substituted alkene, furan, maleimide, anthracene, and combinations thereof, and wherein the polarizable first thermotropic liquid-crystal oligomer molecules are characterized by a weight-average molecular weight from about 200 g/mol to about 10,000 g/mol; optionally, a plurality of polarizable second thermotropic liquid-crystal oligomer molecules containing second triggerable reactive end groups, wherein the second triggerable reactive end groups are capable of reacting with the first triggerable reactive end groups; and optionally, a reactive coupling agent capable of reacting with the first triggerable reactive end groups. Methods are described for converting the oligomer composition into an anisotropic thermally conductive polymer. Many commercial uses are disclosed.

Liquid crystal polyester resin for laminate, liquid crystal polyester resin composition, laminate, and liquid crystal polyester resin film

A liquid crystal polyester resin for laminate, wherein, in a molecular weight distribution of an absolute molecular weight measured by a gel permeation chromatograph/light scattering method, an area fraction of a portion having an absolute molecular weight of 10,000 or less is 10 to 40%, and an area fraction of a portion having an absolute molecular weight of 50,000 or more is 3 to 20%, relative to 100% of the total peak area.

Liquid crystal polyester resin composition and electronic component material containing the same

The present disclosure relates to a liquid crystal polyester resin composition and an electronic component material comprising the same with low dust characteristics. Specifically, the present disclosure relates to a liquid crystal polyester resin composition for preventing dust generation comprising 65% by weight or more and 85% by weight or less of a liquid crystal polyester resin; more than 0.5% by weight and less than 10% by weight of a transition metal compound containing a Group 6 element of the periodic table; 2% by weight or more and 10% by weight or less of a barium compound; 2% by weight or more and 10% by weight or less of an organic filler; and 12% by weight or more and 30% by weight or less of a filler.

Porous liquid crystal polymer sheet and wiring circuit board

A porous liquid crystal polymer sheet and a wiring circuit board have excellent handleability and excellent low repulsive properties. The porous liquid crystal polymer sheet 1 has a porosity P of 20% or more and 90% or less. The porous liquid crystal polymer sheet 1 has a thickness T of 1 μm or more and 240 μm or less.

LIQUID CRYSTAL POLYMER COMPOSITION, LIQUID CRYSTAL POLYMER MOLDED BODY, AND ELECTRICAL AND ELECTRONIC EQUIPMENT
20230383188 · 2023-11-30 · ·

Provided is a liquid crystal polymer composition having excellent light-blocking properties and capable of increasing mechanical strength, such as shock resistance. The liquid crystal polymer composition contains a liquid crystal polymer (A), a particulate carbon material (B), and a reinforcing material (C), wherein the particulate carbon material (B) has a primary particle diameter of not less than 10 nm and not more than 50 nm, and a surface of the reinforcing material (c) is at least partly covered with a treated layer made of a hydrophobic surface treatment agent.

Liquid-crystalline resin composition and molded article

A liquid-crystalline resin composition is provided, containing: a liquid-crystalline resin; and a fibrous filler formed of crystalline polysaccharides, in which a 5% weight loss temperature of the fibrous filler is 280° C. or higher.

LIQUID CRYSTAL POLYMER PARTICLES, THERMOSETTING RESIN COMPOSITION, AND MOLDED ARTICLE
20220282034 · 2022-09-08 · ·

Disclosed are liquid crystal polymer particles capable of reducing dielectric loss tangent while suppressing surface roughness of the resin film, when added to a resin film. The liquid crystal polymer particles have a melting point of 270° C. or higher, wherein cumulative distribution 50% diametre D.sub.50 in the particle size distribution is 20 μm or less, and cumulative distribution 90% diametre D.sub.90 is 2.5 times or less of D.sub.50.