The present invention discloses an novel organic material is represented by the following formula (A) and organic EL device using the organic material as hole blocking layer (HBL), electron transport layer (ETL) or phosphorescent host can efficiently lower driving voltage, lower power consumption and increase the efficiency. ##STR00001##
The same definition as described in the present invention.

The present invention generally discloses an organic optoelectronic material and organic electroluminescent (herein referred to as organic EL) device, organic photovoltaics (herein referred to as OPV) device and organic thin-film transistor (herein referred to as OTFT) device using the organic optoelectronic material. More specifically, the present invention relates to the organic optoelectronic material formula (1), and an organic EL device, OPV device and OTFT device employing the organic optoelectronic material can improve performance.

The present invention provides an organic thin film light emitting device having high luminous efficiency and durable life realized by using a benzindolocarbazole derivative as represented by either general formula (1-1) or (1-2) given below: [Chemical compound 1] wherein R.sup.1 to R.sup.24 may be identical to or different from each other and are selected from the group consisting of a hydrogen atom, alkyl group, cycloalkyl group, heterocyclic group, amino group, alkenyl group, cycloalkenyl group, alkynyl group, alkoxy group, alkylthio group, aryl ether group, aryl thioether group, aryl group, heteroaryl group, halogen atom, carbonyl group, carboxyl group, oxycarbonyl group, carbamoyl group, silyl group, and —P(═O)R.sup.25R.sup.26; R.sup.25 and R.sup.26 represent either an aryl group or a heteroaryl group; R.sup.25 and R.sup.26 may be condensed to form a ring; L.sup.1 to L.sup.4 independently represent a single bond, a substituted or unsubstituted arylene group, or a substituted or unsubstituted heteroarylene group; and A.sup.1 to A.sup.4 independently represent an amino group, aryl group, heterocyclic group, or heteroaryl group.

The present disclosure relates to an organic electroluminescent compound, and an organic electroluminescent material and an organic electroluminescent device comprising the same. The organic electroluminescent compound of the present disclosure has excellent color purity, solubility, and thermal stability. By comprising the organic electroluminescent compound and the organic electroluminescent material of the present disclosure, an organic electroluminescent device showing low driving voltage, excellent current and power efficiencies, and significantly improved lifespan can be provided.

An iridium complex is disclosed. The iridium complex includes two primary ligands selected from 2-(4,6-difluoromethyl and trifluoromethyl pyridine-3-) butypyridine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-4-) butypyridine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-3-) butypyrimidine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-4-) butypyrimidine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-3-) butypyrazine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-4-) butypyrazine, and the derivatives of 2-(4,6-difluoromethyl and trifluoromethyl pyridine-3-) butytriazine and 2-(4,6-difluoromethyl and trifluoromethyl pyridine-4-) butytriazine. The iridium complex further includes an auxiliary acetylacetone ligand. Such new iridium complex in the invention not only owns the high luminous efficiency, stable chemical property, easy sublimation purification and is other advantages, but also has good device performance. By embellishing the molecular structure of the primary ligand, it could adjust the light intensity and efficiency of complexes within the scope of green light wavelength, which provides the convenience for the design and production of organic light emitting device and lighting source.

An iridium complex is disclosed. The iridium complex takes 2-(5-phenyl-1,3,4-oxadiazoles-2-) phenol as the auxiliary ligand, and main ligand of the iridium complex molecule includes the following ligands: 2-(4,6-difluoromethyl and trifluoromethyl pyridine-3-) butypyridine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-4-) butypyridine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-3-) butypyridine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-4-) butypyrazine, and 2-(4,6-difluoromethyl and trifluoromethyl pyridine-3-) butytriazine and 2-(4,6-difluoromethyl and trifluoromethyl pyridine-4-) butytriazine derivatives. Such new iridium complex in the invention not only owns the high luminous efficiency, stable chemical property, easy sublimation purification and other advantages, but also has good device performance.

An iridium complex is disclosed. The iridium complex with tetraphenylphosphorane as an auxiliary ligand takes any one of 2-(4,6-bi trifluoromethyl)pyridine, 2-(4,6-bi trifluoromethyl)pyrimidine, 2-(4,6-bi trifluoromethyl)pyrazinyl and 2-(4,6-bi trifluoromethyl) triazine derivatives as primary ligands in its molecule. The new type of iridium complex covered by the present invention has not only such advantages as high luminous efficiency, high electron mobility, stable chemical property, easy for sublimation and purification but also good performance of devices. By modifying the molecular structure of the primary ligands, it allows to adjust the luminous intensity and efficiency of the complex, thus facilitating the design and production of organic light-emitting diode and illumination source. Meanwhile, the synthesis method of a series new type of iridium complexes of the present invention is simple with high yield and is flexible in chemical modification of ligands.

An iridium complex is disclosed. The iridium complex includes the following ligands: 2-(4,6-difluoromethyl and trifluoromethyl pyridine-3-) butypyridine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-4-) butypyridine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-3-) butypyrimidine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-4-) butypyrimidine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-3-) butypyrazine, 2-(4,6-difluoromethyl and trifluoromethyl pyridine-4-) butypyrazine, and the derivatives of 2-(4,6-difluoromethyl and trifluoromethyl pyridine-3-) butytriazine and 2-(4,6-difluoromethyl and trifluoromethyl pyridine-4-) butytriazine. Such new iridium complex in the invention not only owns the high luminous efficiency, stable chemical property, easy sublimation purification and other advantages, but also has good device performance. By embellishing the molecular structure of ligand, it could adjust the light intensity and efficiency of complexes within the scope of green light wavelength, which provides the convenience for the design and production of organic light emitting device and lighting source.

A delayed fluorescence material containing a mixture of an acceptor compound and a donor compound that satisfies the following formulae (1) to (4):
T.sub.1.sup.A−S.sub.1>0.2 eV  (1)
T.sub.1.sup.D−S.sub.1≧0.2 eV  (2)
|LUMO.sup.A|>2.0 eV  (3)
|HOMO.sup.D|≦5.3 eV  (4)
wherein T.sub.1.sup.A represents the excited triplet energy of the acceptor compound; T.sub.1.sup.D represents the excited triplet energy defined of the donor compound; S.sub.1 represents the excited singlet energy of the exciplex; LUMO.sup.A represents the energy level of LUMO of the acceptor compound; and HOMO.sup.D represents the energy level of HOMO of the donor compound.

An object is to provide a light-emitting element which uses a plurality of kinds of light-emitting dopants and has high emission efficiency. In one embodiment of the present invention, a light-emitting device, a light-emitting module, a light-emitting display device, an electronic device, and a lighting device each having reduced power consumption by using the above light-emitting element are provided. Attention is paid to Förster mechanism, which is one of mechanisms of intermolecular energy transfer. Efficient energy transfer by Förster mechanism is achieved by making an emission wavelength of a molecule which donates energy overlap with a local maximum peak on the longest wavelength side of a graph obtained by multiplying an absorption spectrum of a molecule which receives energy by a wavelength raised to the fourth power.