C09K2211/1096

ORGANIC MOLECULES FOR OPTOELECTRONIC DEVICES
20230124349 · 2023-04-20 ·

The invention relates to an organic molecule, in particular for the application in optoelectronic devices. According to the invention, the organic molecule has a structure of formula (I) wherein R.sup.I, R.sup.II, R.sup.III, R.sup.IV, R.sup.V, R.sup.VI, R.sup.VII, R.sup.VIII, R.sup.IX, R.sup.X and R.sup.XI are independently selected from the group consisting of: hydrogen, deuterium, halogen, C.sub.1-C.sub.12-alkyl, wherein optionally one or more hydrogen atoms are independently substituted by R.sup.5; C.sub.6-C.sub.18-aryl, wherein optionally one or more hydrogen atoms are independently substituted R.sup.5; R.sup.5 is at each occurrence independently selected from the group consisting of: hydrogen, deuterium C.sub.1-C.sub.12-alkyl, C.sub.6-C.sub.18-aryl, wherein optionally one or more hydrogen atoms are independently substituted by C.sub.1-C.sub.5-alkyl substituents; at least one of R.sup.I, R.sup.II, R.sup.III, R.sup.IV, R.sup.V and at least one of R.sup.VI, R.sup.VII, R.sup.VIII, R.sup.IX or R.sup.X is selected from the group of: C.sub.1-C.sub.12-alkyl, wherein optionally one or more hydrogen atoms are independently substituted by R.sup.5; C.sub.6-C.sub.18-aryl, wherein optionally one or more hydrogen atoms are independently substituted by R.sup.5; and each hydrogen may independently be substituted by deuterium or halogen.

##STR00001##

Metal-complex-based electrochromic device

An object of the present invention is to provide a novel electrochromic device (ECD). Disclosed is an electrochromic device (ECD) comprising two metal-complex-based electrochromic thin films individually acting as a working electrode and a counter electrode; (i) one of the two metal-complex-based electrochromic thin films being a film of a cathodically coloring metallo-supramolecular polymer comprising at least one organic ligand having a plurality of metal coordination positions and a metal ion of at least one transition metal and/or lanthanoid metal with the at least one organic ligand and the metal ion being arranged alternately, and the other of the two metal-complex-based electrochromic thin films being a film of an anodically coloring metal hexacyanoferrate (MHCF) represented by the formula: M(II).sub.3[Fe(III)CN.sub.6].sub.2 (where M=Fe, Ni or Zn), and (ii) the electrochromic device having a first conducting substrate; the film of the cathodically coloring metallo-supramolecular polymer; an electrolyte; the film of the anodically coloring metal hexacyanoferrate (MHCF); and a second conducting substrate being arranged in this order.

ORGANIC MOLECULES FOR OPTOELECTRONIC DEVICES
20230159567 · 2023-05-25 ·

The disclosure pertains to an organic molecule for use in optoelectronic devices. The organic molecule has a structure of Formula I:

##STR00001## wherein X is selected from the group consisting of a direct bond, NR.sup.1, O, S, SiR.sup.1R.sup.2 and CR.sup.1R.sup.2; Y is selected from the group consisting of a direct bond, NR.sup.3, O, S, SiR.sup.3R.sup.4 and CR.sup.3R.sup.4; and R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are each independently selected from the group consisting of: hydrogen, deuterium, N(R.sup.5).sub.2, OR.sup.5, SR.sup.5, Si(R.sup.5).sub.3, B(OR.sup.5).sub.2, OSO.sub.2R.sup.5, CF.sub.3, CN, halogen, C.sub.1-C.sub.40-alkyl, C.sub.1-C.sub.40-alkoxy, C.sub.1-C.sub.40-thioalkoxy, C.sub.2-C.sub.40-alkenyl, C.sub.2-C.sub.40-alkynyl, C.sub.6-C.sub.60-aryl, and C.sub.3-C.sub.57-heteroaryl.

FLUORESCENT LABELING AGENT AND FLUORESCENT DYE

A fluorescent labeling agent contains a fluorescent dye represented by general formula (1). General formula (1): Q-Z—R.sub.1-R.sub.2-R.sub.3 (In the formula, Q represents the residue of a fluorescent dye. Z represents a direct bond, alkylene group, or arylene group. R.sub.1 represents a direct bond, —O—, —OP(═O)R.sub.4—, —OC(═O)—, —OS(═O).sub.2—, —OSiR.sub.5R.sub.6—, —C(═O)—, or —C(═O)NH—. R.sub.2 represents a group selected from the group consisting of alkylene groups, arylene groups, and heterocyclic groups, or represents a group provided by combining these groups. R.sub.3 represents —COOM.sub.1, —NR.sub.7R.sub.8, or —N.sup.+R.sub.9R.sub.10R.sub.11. Here, R.sub.4 represents a hydrogen atom, hydroxyl group, alkyl group, aryl group, alkoxy group, aryloxy group, or heterocyclic group. R.sub.5 and R.sub.6 each independently represent an alkyl group, aryl group, or heterocyclic group. R.sub.7-R.sub.11 each independently represent a hydrogen atom, alkyl group, or aryl group. M.sub.1 represents a monovalent cation.)

Oxazine compound and application thereof

Disclosed are an oxazine compound and an application thereof. The oxazine compound has a structure of a general formula F. The oxazine compound described in the disclosure is a photo/acoustic dynamic active organic molecule with near-infrared absorption-emission function as well as photosensitivity and acoustic sensitivity. Maximum absorption and emission wavelengths of the compound are both greater than 660 nanometers, and a triplet-state conversion rate of the compound is high; and under illumination or ultrasound, the compound can produce reactive oxygen species with high efficiency, which has a good killing effect on cancer cells and cancer tissues, and almost has no toxic or side effects on normal tissues while achieving photo/acoustic dynamic therapy on tumors.

Tetradentate metal complexes with carbon group bridging ligands

Platinum, palladium, and gold complexes suitable for use as phosphorescent emitters or as delayed fluorescent and phosphorescent emitters having the structure of Formula VIII. ##STR00001##

THERMALLY ACTIVATED DELAYED FLUORESCENT MATERIAL, PREPARING METHOD THEREOF, AND ORGANIC ELECTROLUMINESCENT DEVICE

A method of preparing a thermally activated delayed fluorescent material is disclosed. The method includes steps of adding a catalyst, an alkaline substance, and a solvent into a first reactant, i.e. a bromide of cyclopenta[def]fluorene-4,8-dione, and a second reactant, where a substitution reaction occurs so as to obtain a reaction solution, and removing an impurity from the reaction solution to obtain the thermally activated delayed fluorescent

##STR00001##

material, having a structural formula of: . By using the cyclopenta[def]fluorene-4,8-dione as acceptor units, the triplet state energy level of the acceptor units is reduced, and the property of the intramolecular charge transfer state is enhanced, so that the light-emitting molecules are redshifted.

ORGANIC ELECTROLUMINESCENT DEVICE

Provided is a blue light emitting organic EL device having high emission efficiency and a long lifetime. This organic EL device comprises one or more light emitting layers between an anode and a cathode opposite to each other, wherein at least one of the light emitting layers contains a first host, a second host, and a light emitting dopant; the first host is a carbazole compound or a bicarbazole compound; the second host is an indolocarbazole compound; and the light emitting dopant is a polycyclic aromatic compound represented by the general formula (4) or a polycyclic aromatic compound having this structure as a partial structure. In the formula, Y.sup.4 is B, P, P═O, P═S, AL, Ga, As, Si—R.sup.4, or Ge—R.sup.41, and X.sup.4 is O, N—Ar.sup.4, S, or Se.

MATERIALS FOR ELECTRONIC DEVICES

The invention relates to compounds comprising functional substituents in a specific spatial arrangement, devices containing same, and the preparation and use thereof.

Organic molecules for use in optoelectronic devices
11683978 · 2023-06-20 · ·

An organic molecule having a structure of Formula I for the application in optoelectronic devices: ##STR00001##
wherein m is an integer from 1 to 2; n is an integer from 0 to 4; o is an integer from 0 to 2; with the sum (m+n+o) being an integer from 1 to 5; and X is selected from the group consisting of hydrogen, CN and CF.sub.3.