C10B55/10

FLUIDIZED COKING WITH OXYGEN-CONTAINING STRIPPING GAS
20200148960 · 2020-05-14 ·

Systems and methods are provided for using an oxygen-containing gas as at least part of the stripping gas for the stripping zone or section in a fluidized coker. By using an oxygen-containing gas as the stripping gas, heat can be added to the stripping zone selectively based on combustion of coke and/or hydrocarbons with the oxygen in the stripping gas. This can allow the temperature of the stripping zone to be increased relative to the temperature of the coking zone of a fluidized coking system. The flow of oxygen can be controlled to achieve a desirable temperature in the stripper while the reactor temperature is independently set by preheating of the feed and/or hot coke circulation to the reaction zone.

FLUIDIZED COKING WITH OXYGEN-CONTAINING STRIPPING GAS
20200148960 · 2020-05-14 ·

Systems and methods are provided for using an oxygen-containing gas as at least part of the stripping gas for the stripping zone or section in a fluidized coker. By using an oxygen-containing gas as the stripping gas, heat can be added to the stripping zone selectively based on combustion of coke and/or hydrocarbons with the oxygen in the stripping gas. This can allow the temperature of the stripping zone to be increased relative to the temperature of the coking zone of a fluidized coking system. The flow of oxygen can be controlled to achieve a desirable temperature in the stripper while the reactor temperature is independently set by preheating of the feed and/or hot coke circulation to the reaction zone.

SYSTEM FOR CONVERSION OF CRUDE OIL TO PETROCHEMICALS AND FUEL PRODUCTS INTEGRATING DELAYED COKING OF VACUUM RESIDUE

Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and gas oil steam cracking. Feeds to the mixed feed steam cracker include light products and naphtha from hydroprocessing zones within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline aromatics extraction zone within the battery limits. Feeds to the gas oil steam cracker include gas oil range intermediates from the vacuum gas oil hydroprocessing zone. Furthermore, vacuum residue is processed in a delayed coker unit to produce coker naphtha, which is hydrotreated and passed as additional feed to aromatics extraction zone and/or the mixed feed steam cracker, and coker gas oil range intermediates as additional feed to the gas oil hydroprocessing zone.

SYSTEM FOR CONVERSION OF CRUDE OIL TO PETROCHEMICALS AND FUEL PRODUCTS INTEGRATING DELAYED COKING OF VACUUM RESIDUE

Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and gas oil steam cracking. Feeds to the mixed feed steam cracker include light products and naphtha from hydroprocessing zones within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline aromatics extraction zone within the battery limits. Feeds to the gas oil steam cracker include gas oil range intermediates from the vacuum gas oil hydroprocessing zone. Furthermore, vacuum residue is processed in a delayed coker unit to produce coker naphtha, which is hydrotreated and passed as additional feed to aromatics extraction zone and/or the mixed feed steam cracker, and coker gas oil range intermediates as additional feed to the gas oil hydroprocessing zone.

Efficient process for converting heavy oil to gasoline

Methods and systems are provided for making gasoline. The method includes converting a resid-containing feed to a first fuel gas and a fluid coke in a fluidized bed reactor; gasifying the fluid coke with steam and air to produce a second fuel gas, said second fuel gas comprising a syngas; contacting the first fuel gas with a first conversion catalyst under first effective conversion conditions to form an effluent comprising C.sub.5+ hydrocarbon compounds; and converting the syngas to gasoline boiling range hydrocarbons by converting the syngas to a methanol intermediate product.

Efficient process for converting heavy oil to gasoline

Methods and systems are provided for making gasoline. The method includes converting a resid-containing feed to a first fuel gas and a fluid coke in a fluidized bed reactor; gasifying the fluid coke with steam and air to produce a second fuel gas, said second fuel gas comprising a syngas; contacting the first fuel gas with a first conversion catalyst under first effective conversion conditions to form an effluent comprising C.sub.5+ hydrocarbon compounds; and converting the syngas to gasoline boiling range hydrocarbons by converting the syngas to a methanol intermediate product.

WASTE UPGRADING AND RELATED SYSTEMS
20200063038 · 2020-02-27 ·

A method upgrading waste to produce fuel can include: introducing a hydrocarbon feed stream into a 450 C. to 1050 C. coking zone of a reactor containing a fluidized bed of coke particles maintained at coking temperatures to produce a vapor phase hydrocarbon product while coke is deposited on the coke particles; allowing the coke particles to pass downwards to a stripper section of the reactor; introducing a steam stream into the stripper section; transferring the coke particles from the stripper section to a gasifier/burner; contacting the coke particles in the gasifier/burner an oxygen-containing gas in an oxygen-limited atmosphere at 850 C. to 1200 C. to heat the coke particles and form a fuel gas product that comprises carbon monoxide and hydrogen; recycling the heated coke particles from the gasifier/burner to the coking zone of the reactor; and introducing at least one waste stream to the reactor and/or the gasifier/burner.

FLUIDIZED COKING WITH REDUCED COKING VIA LIGHT HYDROCARBON ADDITION

Systems and methods are provided for adding a heated stream of light hydrocarbons to a fluidized coking environment to improve liquid product yield and/or reduce coke production. The light hydrocarbons can correspond to C.sub.1-C.sub.10 hydrocarbons and/or hydrogen. The light hydrocarbons can be heated so that the light hydrocarbons are exposed to an activation temperature of 535 C. to 950 C. and/or an activation temperature higher than the temperature in the coking zone by 50 C. or more for an activation time prior to entering the fluidized coking reactor and/or the coking zone in the fluidized coking environment.

FLUIDIZED COKING WITH REDUCED COKING VIA LIGHT HYDROCARBON ADDITION

Systems and methods are provided for adding a heated stream of light hydrocarbons to a fluidized coking environment to improve liquid product yield and/or reduce coke production. The light hydrocarbons can correspond to C.sub.1-C.sub.10 hydrocarbons and/or hydrogen. The light hydrocarbons can be heated so that the light hydrocarbons are exposed to an activation temperature of 535 C. to 950 C. and/or an activation temperature higher than the temperature in the coking zone by 50 C. or more for an activation time prior to entering the fluidized coking reactor and/or the coking zone in the fluidized coking environment.

FLUIDIZED COKING WITH CATALYTIC GASIFICATION
20190352571 · 2019-11-21 ·

Systems and methods are provided for integrating a fluidized coking process with a catalyst-enhanced coke gasification process. The catalyst for the gasification process can correspond to calcium oxide, a thermally decomposable calcium salt, a potassium salt such as potassium carbonate, or a combination thereof. Examples of suitable calcium salts can include, but are not limited to, calcium hydroxide, calcium nitrate, and calcium carbonate. The calcium oxide, potassium salts, and/or thermally decomposable calcium salts can be introduced into the integrated system, for example, as part of the feed into the coker. It has been unexpectedly discovered that using catalytic gasification as part of an integrated fluidized coking and gasification process can result in an overhead gas stream from the gasifier with increased energy content and/or overhead gas pressure.