Patent classifications
C10G35/09
MULTI-METALLIC CATALYST DOPED WITH PHOSPHORUS AND YTTRIUM
The invention relates to a catalyst comprising a support, at least one noble metal M, tin, phosphorus and yttrium, the content of phosphorus element being less than or equal to 1% by weight, and the content of yttrium being less than or equal to 1% by weight relative to the mass of the catalyst. The invention also relates to the process for preparing the catalyst and to the use thereof in reforming.
MULTI-METALLIC CATALYST DOPED WITH PHOSPHORUS AND YTTERBIUM
The invention relates to a catalyst comprising a support, at least one noble metal M, tin, phosphorus and ytterbium, the content of phosphorus element being greater than or equal to 0.2% by weight and less than 0.4% by weight, and the content of ytterbium being less than or equal to 1% by weight relative to the mass of the catalyst. The invention also relates to the process for preparing the catalyst and to the use thereof in reforming.
NAPHTHA REFORMER YIELD USING MODIFIED ZEOLITIC CATALYSTS
This application relates to methods and systems for the conversion of hydrocarbon feedstocks, in particular, naphtha feedstocks, into a hydrocarbon product stream containing a high yield of high-octane gasoline and chemicals products. In particular, the conversion takes place over a series of functionally distinctive catalyst beds, at least one of which includes a modified zeolitic catalyst comprising a zeolite, a transition metal, and optionally a binder. Systems provided include a hydrocarbon feed stream, which may be full-range naphtha, a hydrocarbon product stream, and a plurality of functionally distinctive catalyst beds arranged in series, wherein at least one of the catalyst beds comprises a modified zeolitic catalyst. A hydrocarbon feed stream may be conveyed through the plurality of functionally distinctive catalyst beds, producing an intermediate hydrocarbon stream between each, under conditions effective to convert the hydrocarbon feed stream to a hydrocarbon product stream comprising high-octane gasoline, xylenes, benzene, and/or toluene
NAPHTHA REFORMER YIELD USING MODIFIED ZEOLITIC CATALYSTS
This application relates to methods and systems for the conversion of hydrocarbon feedstocks, in particular, naphtha feedstocks, into a hydrocarbon product stream containing a high yield of high-octane gasoline and chemicals products. In particular, the conversion takes place over a series of functionally distinctive catalyst beds, at least one of which includes a modified zeolitic catalyst comprising a zeolite, a transition metal, and optionally a binder. Systems provided include a hydrocarbon feed stream, which may be full-range naphtha, a hydrocarbon product stream, and a plurality of functionally distinctive catalyst beds arranged in series, wherein at least one of the catalyst beds comprises a modified zeolitic catalyst. A hydrocarbon feed stream may be conveyed through the plurality of functionally distinctive catalyst beds, producing an intermediate hydrocarbon stream between each, under conditions effective to convert the hydrocarbon feed stream to a hydrocarbon product stream comprising high-octane gasoline, xylenes, benzene, and/or toluene
Reforming catalyst and a process for preparation thereof
The present disclosure relates to a reforming catalyst and a process for preparing the same. The acidic functionality of the catalyst is suppressed by using a chloride free alumina and coating the chloride free alumina with Group V B metal oxide in the catalyst, which helps in minimizing the cracking reactions and achieving higher selectivity for liquid hydrocarbons and aromatic hydrocarbons.
Fuel upgrading by reforming and dehydrocracking
Zn-promoted and/or Ga-promoted cracking catalysts, such as cracking catalysts comprising an MSE framework zeolite or an MFI framework zeolite can provide unexpectedly superior conversion of branched paraffins when used as part of a catalyst during reforming of a hydrocarbon fuel stream. The conversion and reforming of the hydrocarbon fuel stream can occur, for example, in an internal combustion engine. The conversion and reforming can allow for formation of higher octane compounds from the branched paraffins.
Fuel upgrading by reforming and dehydrocracking
Zn-promoted and/or Ga-promoted cracking catalysts, such as cracking catalysts comprising an MSE framework zeolite or an MFI framework zeolite can provide unexpectedly superior conversion of branched paraffins when used as part of a catalyst during reforming of a hydrocarbon fuel stream. The conversion and reforming of the hydrocarbon fuel stream can occur, for example, in an internal combustion engine. The conversion and reforming can allow for formation of higher octane compounds from the branched paraffins.
Selective poisoning of aromatization catalysts to increase catalyst activity and selectivity
Spent aromatization catalysts containing a transition metal and a catalyst support are selectively poisoned in the disclosed reforming methods, resulting in improvements in overall aromatics yield and selectivity.
Selective poisoning of aromatization catalysts to increase catalyst activity and selectivity
Spent aromatization catalysts containing a transition metal and a catalyst support are selectively poisoned in the disclosed reforming methods, resulting in improvements in overall aromatics yield and selectivity.
Reforming catalyst and a method of preparation thereof
The present disclosure relates to a reforming catalyst composition comprising a spherical gamma AI.sub.2O.sub.3 support; at least one Group VB metal oxide sheet coated on to the AI.sub.2O.sub.3 support; and at least one active metal and at least one promoter metal impregnated on the AI.sub.2O.sub.3 coated support. The reforming catalyst composition of the present disclosure has improved activity, better selectivity for total aromatics during naphtha reforming and results in less coke formation. The reforming catalyst composition has improved catalyst performance with simultaneous modification of acidic sites as well as metallic sites through metal support interaction. The acid site cracking activity of the catalyst is inhibited because of the use of chloride free alumina support modified with solid acid such as Group VB metal oxide and impregnated with active metals. The present disclosure provides a process for naphtha reforming in the presence of the reforming catalyst composition of the present disclosure to obtain reformates of naphtha.