C10G47/14

Process for activation and operation of a hydrocarbon upgrading catalyst
11034896 · 2021-06-15 · ·

The present invention provides a process for upgrading a Fischer-Tropsch product by hydrocracking in the presence of a hydrocracking catalyst in a reactor, wherein the process is initiated by a series of steps (i) to (iv). The hydrocracking catalyst is (i) contacted with a hydrogen-containing stream having a feed temperature of from 360° C. to 420° C.; (ii) the feed temperature of the hydrogen-containing stream is reduced to a temperature of from 220° C. to 280° C.; (iii) the catalyst is contacted with a Fischer-Tropsch product stream having a feed temperature of from 220° C. to 280° C., which is co-fed with the hydrogen-containing stream; and (iv) the catalyst is co-fed with a Fischer-Tropsch product stream and hydrogen-containing stream having feed temperatures of from 380° C. and 400° C. for at least four days and wherein the hydrocracking catalyst is not activated by sulfiding.

DISTILLATE HYDROCRACKING PROCESS TO PRODUCE ISOMERATE

A process of reforming a diesel feedstock to convert diesel to a gasoline blending component may include desulfurizing and denitrogenizing the diesel feedstock to reduce the sulfur and nitrogen content; and then hydrocracking the diesel feedstock over a metal containing zeolitic catalyst to produce an isomerate fraction. The diesel feedstock may have boiling points ranging from 200 to 360° C.

Two-step hydrocracking process for the production of naphtha comprising a hydrogenation step carried out upstream of the second hydrocracking step

The present invention is based on the use of a two-step hydrocracking process for the production of naphtha, comprising a step of hydrogenation placed upstream of the second hydrocracking step, the hydrogenation step treating the unconverted liquid fraction separated in the distillation step in the presence of a specific hydrogenation catalyst. Furthermore, the hydrogenation step and a second hydrocracking step are carried out under specific operating conditions and in particular under temperature conditions that are very specific with respect to one another.

MANUFACTURING HYRDOCRACKING CATALYST

A method including subjecting an ultra-stable Y-type zeolite having a low silica-to-alumina molar ratio (SAR), such as in a range of 3 to 6, to acid treatment and heteroatom incorporation contemporaneously to give a framework-modified ultra-stable Y-type zeolite.

Processing vacuum residuum and vacuum gas oil in ebullated bed reactor systems
10894922 · 2021-01-19 · ·

A process for upgrading vacuum residuum and vacuum gas oil hydrocarbons is disclosed. The process may include: contacting a heavy distillate hydrocarbon fraction and hydrogen with a zeolite selective hydrocracking catalyst in a first ebullated bed hydrocracking reaction zone to convert at least a portion of the vacuum gas oil to lighter hydrocarbons. Contacting a residuum hydrocarbon fraction and hydrogen with a non-zeolite base metal hydroconversion catalyst in a second ebullated bed hydroconversion reaction zone may produce a vapor stream containing unconverted hydrogen, acid gases and volatilized hydrocarbons which may be fed along with the vacuum gas oil in the first ebullated bed hydrocracking zone.

Processing vacuum residuum and vacuum gas oil in ebullated bed reactor systems
10894922 · 2021-01-19 · ·

A process for upgrading vacuum residuum and vacuum gas oil hydrocarbons is disclosed. The process may include: contacting a heavy distillate hydrocarbon fraction and hydrogen with a zeolite selective hydrocracking catalyst in a first ebullated bed hydrocracking reaction zone to convert at least a portion of the vacuum gas oil to lighter hydrocarbons. Contacting a residuum hydrocarbon fraction and hydrogen with a non-zeolite base metal hydroconversion catalyst in a second ebullated bed hydroconversion reaction zone may produce a vapor stream containing unconverted hydrogen, acid gases and volatilized hydrocarbons which may be fed along with the vacuum gas oil in the first ebullated bed hydrocracking zone.

Process which does simultaneous dehydrochlorination and hydrocracking of pyrolysis oils from mixed plastic pyrolysis while achieving selective hydrodealkylation of C9+ aromatics

A process for hydrodealkylating a hydrocarbon stream comprising (a) contacting the hydrocarbon stream with a hydroprocessing catalyst in a hydroprocessing reactor in the presence of hydrogen to yield a hydrocarbon product, wherein the hydrocarbon stream contains C.sub.9+ aromatic hydrocarbons; and (b) recovering a treated hydrocarbon stream from the hydrocarbon product, wherein the treated hydrocarbon stream comprises C.sub.9+ aromatic hydrocarbons, wherein an amount of C.sub.9+ aromatic hydrocarbons in the treated hydrocarbon stream is less than an amount of C.sub.9+ aromatic hydrocarbons in the hydrocarbon stream due to hydrodealkylating of at least a portion of C.sub.9+ aromatic hydrocarbons from the hydrocarbon stream during the step (a) of contacting.

Process which does simultaneous dehydrochlorination and hydrocracking of pyrolysis oils from mixed plastic pyrolysis while achieving selective hydrodealkylation of C9+ aromatics

A process for hydrodealkylating a hydrocarbon stream comprising (a) contacting the hydrocarbon stream with a hydroprocessing catalyst in a hydroprocessing reactor in the presence of hydrogen to yield a hydrocarbon product, wherein the hydrocarbon stream contains C.sub.9+ aromatic hydrocarbons; and (b) recovering a treated hydrocarbon stream from the hydrocarbon product, wherein the treated hydrocarbon stream comprises C.sub.9+ aromatic hydrocarbons, wherein an amount of C.sub.9+ aromatic hydrocarbons in the treated hydrocarbon stream is less than an amount of C.sub.9+ aromatic hydrocarbons in the hydrocarbon stream due to hydrodealkylating of at least a portion of C.sub.9+ aromatic hydrocarbons from the hydrocarbon stream during the step (a) of contacting.

Conversion of waste plastic to propylene and cumene

A process for producing propylene and cumene comprising converting plastics to hydrocarbon liquid and pyrolysis gas in pyrolyzer; feeding hydrocarbon liquid to hydroprocessor to yield hydrocarbon product and first gas stream; introducing hydrocarbon product to second separator to produce first C.sub.6 aromatics and refined product; feeding refined product to steam cracker to produce steam cracker product; introducing steam cracker product to third separator to produce second C.sub.6 aromatics, third propylene stream, second C.sub.2&C.sub.4 unsaturated stream, C.sub.1-4 saturated gas, and balance hydrocarbons product; introducing pyrolysis gas and/or first gas stream to first separator to produce first propylene stream, first C.sub.2&C.sub.4 unsaturated stream, and saturated gas stream; feeding first and/or second C.sub.2&C.sub.4 unsaturated stream to metathesis reactor to produce second propylene stream; feeding first and/or second C.sub.6 aromatics, and first, second, and/or third propylene stream to alkylation unit to produce cumene; and conveying balance hydrocarbons product to pyrolyzer and/or hydroprocessor.

Storage of Fischer-Tropsch effluents

Process for the production of middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis comprising at least one light fraction, known as condensate, and a heavy fraction, known as waxes, in which: the said light fraction is stored in a vessel (B) maintained under an inert atmosphere and in which the temperature inside the vessel is maintained at a value of less than 20 C.; the said heavy fraction is stored in a vessel (C) maintained under an inert atmosphere and in which the temperature inside the vessel is maintained at a value of between 80 and 230 C.