Patent classifications
C10G47/14
Process for producing BTX from a C5-C12 hydrocarbon mixture
The present invention relates to a process for producing chemical grade BTX from a mixed feedstream comprising C5-C12 hydrocarbons by contacting said feedstream in the presence of hydrogen with a catalyst having hydrocracking/hydrodesulphurization activity. Particularly, a process for producing BTX from a feedstream comprising C5-C12 hydrocarbons is provided comprising the steps of: (a) contacting said feedstream in the presence of hydrogen with a combined hydrocracking/hydrodesulphurization catalyst to produce a hydrocracking product stream comprising BTX; and (b) separating the BTX from the hydrocracking product stream. The hydrocracking/hydrodesulphurization catalyst comprises 0.1-1 wt-% hydrogenation metal in relation to the total catalyst weight. The hydrocracking/hydrodesulphurization catalyst further comprises a zeolite having a pore size of 5-8 and a silica (SiO.sub.2) to alumina (Al.sub.2O.sub.3) molar ratio of 5-200. The hydrocracking/hydrodesulphurization conditions include a temperature of 450-580 C., a pressure of 300-5000 kPa gauge and a Weight Hourly Space Velocity of 0.1-10 h.sup.1.
Process for producing BTX from a C5-C12 hydrocarbon mixture
The present invention relates to a process for producing chemical grade BTX from a mixed feedstream comprising C5-C12 hydrocarbons by contacting said feedstream in the presence of hydrogen with a catalyst having hydrocracking/hydrodesulphurization activity. Particularly, a process for producing BTX from a feedstream comprising C5-C12 hydrocarbons is provided comprising the steps of: (a) contacting said feedstream in the presence of hydrogen with a combined hydrocracking/hydrodesulphurization catalyst to produce a hydrocracking product stream comprising BTX; and (b) separating the BTX from the hydrocracking product stream. The hydrocracking/hydrodesulphurization catalyst comprises 0.1-1 wt-% hydrogenation metal in relation to the total catalyst weight. The hydrocracking/hydrodesulphurization catalyst further comprises a zeolite having a pore size of 5-8 and a silica (SiO.sub.2) to alumina (Al.sub.2O.sub.3) molar ratio of 5-200. The hydrocracking/hydrodesulphurization conditions include a temperature of 450-580 C., a pressure of 300-5000 kPa gauge and a Weight Hourly Space Velocity of 0.1-10 h.sup.1.
Process and apparatus employing microchannel process technology
- Anna Lee Tonkovich ,
- Ravi Arora ,
- John Brophy ,
- Francis P. Daly ,
- Soumitra Deshmukh ,
- Maddalena Fanelli ,
- Kai Tod Paul Jarosch ,
- Timothy J. LaPlante ,
- Richard Q. Long ,
- Terry Mazanec ,
- Daniel Francis Ryan ,
- Laura J. Silva ,
- Wayne W. Simmons ,
- Bruce Strangeland ,
- Yong Wang ,
- Thomas YUSCHAK ,
- Steven T. Perry ,
- Jeffrey Dale Marco ,
- Michael Alan Marchiando ,
- Robert Lewis Litt
This invention relates to a process for conducting a hydrocracking or a hydrotreating process in a microchannel reactor. This invention also relates to a process and apparatus for flowing a vapor and liquid into a plurality of microchannels in a microchannel processing unit.
Process and apparatus employing microchannel process technology
- Anna Lee Tonkovich ,
- Ravi Arora ,
- John Brophy ,
- Francis P. Daly ,
- Soumitra Deshmukh ,
- Maddalena Fanelli ,
- Kai Tod Paul Jarosch ,
- Timothy J. LaPlante ,
- Richard Q. Long ,
- Terry Mazanec ,
- Daniel Francis Ryan ,
- Laura J. Silva ,
- Wayne W. Simmons ,
- Bruce Strangeland ,
- Yong Wang ,
- Thomas YUSCHAK ,
- Steven T. Perry ,
- Jeffrey Dale Marco ,
- Michael Alan Marchiando ,
- Robert Lewis Litt
This invention relates to a process for conducting a hydrocracking or a hydrotreating process in a microchannel reactor. This invention also relates to a process and apparatus for flowing a vapor and liquid into a plurality of microchannels in a microchannel processing unit.
Process of hydroconversion-distillation of heavy and/or extra-heavy crude oils
A process for hydroconversion-distillation of heavy and/or extra-heavy crude oils, which comprises four stages: 1) desalting and separation of the feedstock; 2) catalytic hydrotreating of light fraction (optional); 3) catalytic hydroconversion of heavy fraction, and 4) distillation of hydrotreated products
to provide products that can be processed in conventional refining schemes designed to operate with light and intermediate crude oils.
Process of hydroconversion-distillation of heavy and/or extra-heavy crude oils
A process for hydroconversion-distillation of heavy and/or extra-heavy crude oils, which comprises four stages: 1) desalting and separation of the feedstock; 2) catalytic hydrotreating of light fraction (optional); 3) catalytic hydroconversion of heavy fraction, and 4) distillation of hydrotreated products
to provide products that can be processed in conventional refining schemes designed to operate with light and intermediate crude oils.
Mesoporous composite of molecular sieves for hydrocracking of heavy crude oils and residues
A hydrocracking catalyst having a support of a composite of mesoporous materials, molecular sieves and alumina, is used in the last bed of a multi-bed system for treating heavy crude oils and residues and is designed to increase the production of intermediate distillates having boiling points in a temperature range of 204? C. to 538? C., decrease the production of the heavy fraction (>538? C.), and increase the production of gasoline fraction (<204? C.). The feedstock to be processed in the last bed contains low amounts of metals and is lighter than the feedstock that is fed to the first catalytic bed.
Preparation of catalyst
A process for preparing a hydrocarbon conversion catalyst that comprises a specially made silica-alumina composition and a metal or metal compound selected from Group VIB and Group VIII metals. The silica-alumina composition is made by preparing an aqueous mixture containing aluminum sulfate followed by adding alkali metal aluminate to the mixture to inhance the pH to within specified range and then adding aluminum sulfate to the mixture to lower the pH. Then alkali metal silicate is added followed by several other pH swings to provide a mixture containing silica-alumina. The resulting mixture is treated with an alkaline solution to provide a precipitate solid that is recovered to obtain a silica-alumina composition containing of from 30 to 70% wt silica and of from 70 to 30% wt of alumina.
Preparation of catalyst
A process for preparing a hydrocarbon conversion catalyst that comprises a specially made silica-alumina composition and a metal or metal compound selected from Group VIB and Group VIII metals. The silica-alumina composition is made by preparing an aqueous mixture containing aluminum sulfate followed by adding alkali metal aluminate to the mixture to inhance the pH to within specified range and then adding aluminum sulfate to the mixture to lower the pH. Then alkali metal silicate is added followed by several other pH swings to provide a mixture containing silica-alumina. The resulting mixture is treated with an alkaline solution to provide a precipitate solid that is recovered to obtain a silica-alumina composition containing of from 30 to 70% wt silica and of from 70 to 30% wt of alumina.
HYDROCRACKING OPERATION WITH REDUCED ACCUMULATION OF HEAVY POLYNUCLEAR AROMATICS
Provided is a hydrocracking process with a recycle loop for converting a petroleum feed to lower boiling products, which process comprises reacting a stream over a non-zeolite noble metal catalyst at a temperature of about 650 F. (343 C.) or less in a reactor positioned in the recycle loop of the hydrocracking reactor.