Patent classifications
C10G2300/1055
Process for producing light olefins and aromatics
A process for producing light olefins and aromatics, which comprises reacting a feedstock by contacting with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone among the reaction zones downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone, separating the spent catalyst from the reaction product vapor, regenerating the separated spent catalyst and returning the regenerated catalyst to the reactor, and separating the reaction product vapor to obtain the desired products, light olefins and aromatics. This process produces maximum light olefins such as propylene, ethylene, etc from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc at the same time.
Catalyst for producing monocyclic aromatic hydrocarbons, and method for producing monocyclic aromatic hydrocarbons
A catalyst for producing monocyclic aromatic hydrocarbons, used for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number from a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., wherein the catalyst contains a crystalline aluminosilicate, gallium and/or zinc, and phosphorus, the molar ratio between silicon and aluminum (Si/Al ratio) in the crystalline aluminosilicate is not more than 100, the molar ratio between the phosphorus supported on the crystalline aluminosilicate and the aluminum of the crystalline aluminosilicate (P/Al ratio) is not less than 0.01 and not more than 1.0, and the amount of gallium and/or zinc is not more than 1.2% by mass based on the mass of the crystalline aluminosilicate.
Catalyst for producing monocyclic aromatic hydrocarbon and production method of monocyclic aromatic hydrocarbon
The catalyst for producing aromatic hydrocarbon is for producing monocyclic aromatic hydrocarbon having 6 to 8 carbon number from oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower and contains crystalline aluminosilicate and phosphorus. A molar ratio (P/Al ratio) between phosphorus contained in the crystalline aluminosilicate and aluminum of the crystalline aluminosilicate is from 0.1 to 1.0. The production method of monocyclic aromatic hydrocarbon is a method of bringing oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower into contact with the catalyst for producing monocyclic aromatic hydrocarbon.
PROCESS FOR CONVERSION OF A HYDROCARBON STREAM
In a broad aspect the present disclosure relates to a process plant and a process for upgrading a hydrocarbon mixture, withdrawn as a direct stream from a crude distillation unit and an initial boiling point below 200° C., and a fraction of at least 5% boiling above 500° C., 550° C. or 650° C. comprising the steps of a. directing said hydrocarbon mixture to a vacuum flasher unit, b. withdrawing a heavy hydrocarbon fraction from said vacuum flasher unit, c. withdrawing a light hydrocarbon mixture for hydrocracking from said vacuum flasher unit, d. directing said light hydrocarbon mixture for hydrocracking and a stream rich in hydrogen to con-tact a material catalytically active in hydrocracking, e. withdrawing a hydrocracked stream of hydrocarbon from said hydrocracker. with the associated benefit of limiting the amount of asphaltenes, metals and other heavy components contacting said material catalytically active in hydrocracking.
Catalyst for producing monocyclic aromatic hydrocarbons, and method for producing monocyclic aromatic hydrocarbons
A catalyst for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number from a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., or a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and a 90 volume % distillation temperature of not more than 360° C., wherein the catalyst contains a crystalline aluminosilicate, gallium and/or zinc, and phosphorus, and the amount of phosphorus supported on the crystalline aluminosilicate is within a range from 0.1 to 1.9% by mass based on the mass of the crystalline aluminosilicate; and a method for producing monocyclic aromatic hydrocarbons, the method involving bringing a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., or a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and a 90 volume % distillation temperature of not more than 360° C., into contact with the above-mentioned catalyst for producing monocyclic aromatic hydrocarbons.
AN IMPROVED PROCESS TO PRODUCE AROMATICS RICH AVIATION FUEL ALONG WITH OTHER C1-C24 HYDROCARBONS
A single step catalytic process for the preparation of aromatic rich aviation fuel from renewable resource in the presence of a hydrogen stream, and one or more hydroprocessing catalysts, under operating conditions for hydroconversion reactions, as defined herein, with mixed hot and cold streams of the renewable feed and getting desired product after separation of water, lighter hydrocarbon gases and carbon oxides, the said product comprising of hydrocarbons C6-C24, rich in aromatic content in the aviation fuel range, including kerosene range.
STEAM CRACKING PROCESS INTEGRATING OXIDIZED DISULFIDE OIL ADDITIVE
Oxidized disulfide oil (ODSO) compounds or ODSO compounds and disulfide oil (DSO) compounds are added to a steam cracker feed. During the thermal cracking, the ODSO or ODSO and DSO components in the steam cracker mixture minimize coke formation on the steam cracker coils.
Naphtha catalytic cracking for light olefins production over cyclic regenerative process with dry gas diluent
A method of producing olefins by catalytic cracking of hydrocarbons is disclosed. The method may include catalytic cracking hydrocarbons in a feed stream that includes the hydrocarbons and the dry gas diluent. The catalytic cracking may be carried out in a process using a train of fixed bed reactors while one or more other trains of fixed bed reactors are being regenerated or are on standby after being regenerated. When the train of fixed bed reactors being used needs regenerating, it is taken out of service and the one or more other trains of fixed bed reactors put in service to carry out the catalytic cracking process. Dry gas instead of steam may be used to reduce the partial pressure of hydrocarbons.
APPARATUS AND PROCESS FOR THE ENHANCED PRODUCTION OF AROMATIC COMPOUNDS
Embodiments of the present disclosure are directed to a process for the upgrading of petroleum products comprising subjecting a diesel feed to a hydrocracking process, thereby producing a hydrocrackate fraction; subjecting the hydrocrackate fraction to a catalytic reforming process, thereby producing a reformate; and recovering aromatics from the reformate. In accordance with another embodiment of the present disclosure, a method of producing aromatics may comprise introducing a diesel feed to a hydrocracking unit to produce a hydrocrackate fraction, passing the hydrocrackate fraction to a catalytic reforming unit to produce a reformate, and passing the reformate to an aromatic recovery complex to produce an aromatic fraction. In accordance with yet another embodiment of the present disclosure, an apparatus for the upgrading of petroleum products may comprise a hydrocracker, a catalytic reformer, and an aromatic recovery complex. The hydrocracker may be in fluid communication with the catalytic reformer, the catalytic reformer may be in fluid communication with an aromatic recovery complex, and the hydrocracker may be structurally configured to receive a diesel feed.
Process for catalytic cracking of naphtha using radial flow moving bed reactor system
A method of catalytically cracking liquid hydrocarbons is disclosed. The method includes the use of one or more radial flow moving bed reactors. The method may include mixing a liquid hydrocarbon stream comprising primarily C5 and C6 hydrocarbons with water or a dry gas to form a feed mixture and flowing the feed mixture into the one or more radial flow moving bed reactors in a manner so that the feed mixture flows radially inward or radially outward through the moving catalyst bed and thereby contacts the catalyst particles under reaction conditions to produce a hydrocarbon stream comprising light olefins (C2 to C4 olefins).