Systems and methods are provided for co-processing of used lubricant oils with a coker feedstock in a fluidized coking process to form lubricant base stocks. The fluidized coking process can remove contaminants and/or additives from used lubricant oils with modest conversion of the lubricant boiling range portion.

A catalyst structure includes a porous support structure, where the support structure includes an aluminosilicate material. Any two or more metals are loaded in the porous support structure, the two or more metals selected from the group consisting of Ga, Ag, Mo, Zn, Co and Ce, where each metal loaded in the porous support structure is present in an amount from about 0.1 wt % to about 20 wt %. In example embodiments, the catalyst structure includes three or more of the metals loaded in the porous support structure. The catalyst structure is used in a hydrocarbon upgrading process that is conducted in the presence of methane, nitrogen or hydrogen.

Methods for conserving the use of fresh wash water in crude oil desalting are described. A crude oil stream including salt mixes with a wash water stream to form an emulsion. The emulsion flows to a desalter, and the wash water coalesces to reform the wash water stream and to transfer at least a portion of the salt from the crude oil stream to the wash water stream. The crude oil stream with reduced salt content separates from the wash water stream. The effluent, which includes the wash water stream, flows from the desalter to a processing unit. The effluent is processed to reduce a concentration of salt in the effluent to be substantially equal to or less than a concentration of salt in the wash water stream. At least a portion of the processed effluent mixes with the crude oil stream before the emulsion flows to the desalter.

The present invention relates to crude oil processing, particularly related to conversion of crude oil containing high amount of naphthenic acid compounds to lighter hydrocarbon materials with minimum capital expenditure. The invented process utilizes a novel scheme for high TAN crude oils by employing thermal cracking process to maximize the residue conversion to valuable products, which require minimum modifications in unit metallurgies and corrosion inhibitor injection schemes in refineries.

A method and apparatus for continuously treating acid gases including recovering absorbent chemicals by introducing streams leaving a regenerator and/or leaving an absorber into a static mixing zone wherein supplemental washing water is added to recover absorbent chemicals. Improvements to the prior art methods are provided where one or more absorbent chemical recovery units are included to increase the amount of recovered absorbent chemicals exiting the regenerator and/or exiting the absorber are increased and/or maximized. Absorbent chemical recovery units can include mixing units where liquid is added to the stream of sour gas and absorbent chemical to mix with and absorb the absorbent chemical from the stream.

The systems and methods reduce the total acid number (TAN) in crude oil. The crude oil, that includes naphthenic acid, is mixed with at least a caustic solution (e.g., sodium hydroxide) to produce a mixture. After mixing, the mixture is pumped to an atomizing tank. The mixture is spray-atomized in the mixing tank to produce a condensed liquid state of the crude oil that settles at the bottom of the atomizer tank and to produce minute droplets (e.g. mist, fog or the like) of the caustic. The minute droplets interact with and neutralize the naphthenic acid in the condensed liquid state of the crude oil for a predefined period of time. As a result, the resulting crude oil in the bottom of the atomizer tank has a reduced TAN and includes salt water. Additionally, the resulting crude oil has a water concentration that does not exceed 0.5%.

A process for producing naphthenic base oils from low quality naphthenic crude feedstocks. The naphthenic base oils produced by the process have improved low temperature properties at high yields based on feedstock.

Processes for quantitating the corrosivity of naphthenic acids in a sample comprising crude oil or a liquid fraction thereof by reacting the sample with a metal comprising iron to produce iron naphthenates that are then stabilized by a ligand. The stabilized iron naphthenates are then analyzed by mass spectrometry to accurately quantitate the percentage of total naphthenic acids in the sample that are iron-reactive naphthenic acids associated with metal corrosion.

Methods and systems are provided herein utilizing a membrane cascade to separate a hydrocarbon feed into boiling point fractions. Also provided herein are methods for selecting membranes for said cascades to achieve the desired boiling point fraction separation.

A process for extracting fuel products from waste rubber, comprising the steps of subjecting the waste rubber to pyrolysis to produce a pyrolysis vapour, subjecting the pyrolysis vapour to a condensation step to produce a pyrolytic oil having a boiling point range of 45-400? C. and a flash point below 25? C., and then subjecting the pyrolytic oil to a vacuum steam stripping step so as to recover a fraction having a first composition having a flash point above 55? C., a boiling point range starting at 140? C. or higher, a density at 15? C. of less than 990 kg/m.sup.3, a total acid number TAN of up to 12, a styrene content of less than 3000 ppm, and an organic halogen (as Cl) content of less than 50 ppm, and a second composition having an initial boiling point not exceeding 75? C. under atmospheric pressure, a density at 15? C. of greater than 790 kg/m.sup.3, a benzene content of at least 1.25 vol %, an existent gum (washed) content greater than 10 mg/100 ml, an organic halogen (as Cl) content of less than 50 mg/kg, and a colour of less than 5.0.