Patent classifications
C10J2300/0976
INTEGRATED PYROLYSIS AND GASIFICATION OF BIOMASS
Systems and methods are provided for integrated pyrolysis and gasification of a biomass feed, either as a separate feed or under co-processing conditions. The integrated pyrolysis and gasification can be performed using any convenient reactor configuration, such as fluidized coking reactor configuration or a fluid catalytic cracking reactor configuration. The biomass feed can initially by pyrolyzed to form liquid products, gas phase products, and char. The char can then be used as the input feed to gasification. In aspects where the biomass feed is co-processed, the biomass can be co-processed with a co-feed that is suitable for processing under fluidized coking conditions or other pyrolysis conditions, such as a conventional fluidized coking feedstock.
Manufacture of a synthetic fuel
The present invention provides a process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.
Char Preparation System and Gasifier for All-Steam Gasification with Carbon Capture
An ASG system for polygeneration with CC includes a devolatilizer that pyrolyzes solid fuel to produce char and gases. A burner adds exothermic heat by high-pressure sub-stoichiometric combustion, a mixing pot causes turbulent flow of the gases to heat received solid fuel, and a riser micronizes resulting friable char. A devolatilizer cyclone separates the micronized char by weight providing micronized char, steam and gases to a gasifier feed and oversized char to the mixing pot. An indirect fluid bed gasifier combustion loop includes a gasifier coupled to the gasifier feed, a steam input to provide oxygen for gasification and to facilitate sand-char separation, and an output for providing syngas. A burner provides POC to a mixing pot which provides hot sand with POC to a POC cyclone via a riser, where the POC cyclone separates sand and POC by weight and provides POC and sand for steam-carbon reaction.
PLASMA PROCESS TO CONVERT SPENT POT LINING (SPL) TO INERT SLAG, ALUMINUM FLUORIDE AND ENERGY
Apparatus for converting Spent Pot Lining (SPL) into inert slag, aluminum fluoride and energy includes a plasma arc furnace such that the destruction of SPL occurs therein. The furnace generates an electric arc within the waste, which arc travels from an anode to a cathode and destroys the waste due to the arc's extreme temperature, thereby converting a mineral fraction of SPL into vitrified inert slag lying within a crucible of the furnace. The furnace gasifies the carbon content of the SPL and produces a well-balanced syngas. The gasification takes place due to the controlled intake of air and steam into the furnace. The gasification reaction liberates significant amount of energy. Steam captures this excess energy, to provide part of the oxygen requirement for gasification and to contribute to raise the syngas H2 content. Steam also contributes to converting some SPL fluorides (NaF and Al2F3) into hydrogen fluoride. The plasma SPL processing system is compact (occupying less area than some competitive methods of SPL treatment), can be installed in close proximity to the aluminium plant (minimizing transportation of SPL and AlF3), and requires only electricity as its energy source and thus no fossil fuels.
PYROLYSIS OF WASTE PLASTICS IN A FILM REACTOR
A process and system for liquefying and plasticizing a waste plastic in a pyrolysis film reactor are provided. More particularly, a liquefied waste plastic, which may include halogen-depleted molten waste plastics, may be pyrolyzed in a pyrolysis film reactor to form a pyrolysis oil and a pyrolysis gas. The pyrolysis film reactors may include a falling film reactor and/or an upflow film reactor.
METHOD FOR GASIFICATION OF CARBONACEOUS FEEDSTOCK AND DEVICE FOR IMPLEMENTING SAME
The invention relates to the field of gasification of a carbonaceous feedstock and can be used in the chemical, petrochemical, coke-gas and energy industries. A method for gasification of a carbonaceous feedstock comprises partial oxidation of the carbonaceous feedstock in an oxidation chamber in a mixture of oxygen-containing gas and water vapour in a partial oxidation channel, which is mounted coaxially in the vertical oxidation chamber. The water vapour for the partial oxidation of the carbonaceous feedstock is supplied at the input and output of the vertical oxidation chamber of a combustion chamber. A gas producer comprises a housing, a burner device, a vertical oxidation chamber, manifolds for supplying carbonaceous feedstock, water vapour and oxygen-containing gas, a pipe for discharging gasification products, a slag removal chamber, and also a partial oxidation channel, which is arranged coaxially in the vertical oxidation chamber and is attached to an upper internal part of the housing, in which the burner device is installed. What is achieved is the production of producer gas with an elevated concentration of hydrogen.
Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from municipal solid wastes (MSW) feedstocks
Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.
PROCESS FOR PRODUCING A SYNTHESIS GAS
Process for manufacturing a hydrogen-containing synthesis gas from a natural gas feedstock, comprising the conversion of said natural gas into a raw product gas and purification of said product gas, the process having a heat input provided by combustion of a fuel; said process comprises a step of conversion of a carbonaceous feedstock, and at least a portion of said fuel is a gaseous fuel obtained by said step of conversion of said carbonaceous feedstock.
CARBONIZING FURNACE, PYROLYTIC FURNACE, WATER GAS GENERATION SYSTEM, HYDROGEN GAS GENERATION SYSTEM, AND POWER GENERATION SYSTEM
Provided is a carbonizing furnace capable of improving combustion efficiency of combustible gas generated by combustion of organic waste and of improving carbonization efficiency of organic waste by appropriately controlling the temperature of carbide. Provided is a pyrolytic furnace in which heating gas can be suppressed from outflowing to the outside from a gap between the upper surface of the body part of the pyrolytic furnace and the outer circumferential surface of a reaction tube where a pyrolysis reaction between carbide and a gasification agent is caused, and in which the temperature of a region where the pyrolysis reaction is caused can be suppressed from being reduced. Provided is a water gas generation system which improves thermal efficiency without using a dedicated heat source for generating water steam to be used as a gasification agent for carbide, promotes a pyrolysis reaction, and thereby, achieves the excellent heat efficiency. Provided are a hydrogen gas generation system and a power generation system which use water gas generated by a water gas generation system including a carbonizing furnace and a pyrolytic furnace and which have excellent productivity. Provided is a carbonizing furnace which improves combustion efficiency by controlling the supply amount of air being supplied to the carbonizing furnace according to the temperature of combustion gas in the carbonizing furnace, and which improves carbonization efficiency by controlling the discharge amount of carbide to be discharged to the outside according to the temperature of carbide or the deposit amount of organic waste in the carbonizing furnace, to make the temperature of carbide appropriate, and by controlling the temperature of air being supplied to the carbonizing furnace. In addition, provided is a pyrolytic furnace which blocks outflow of heating gas or water gas by providing seal portions at the attachment positions of a body part, a reaction tube, and a water gas outlet part, etc. of the pyrolytic furnace, and which maintains a pyrolysis reaction temperature by providing a pyrolysis promoting mechanism to the reaction tube. Provided is a water gas generation system which has excellent thermal efficiency and in which a combustion gas flow path is formed so as to allow combustion gas generated by a carbonizing furnace to flow through a carbonizing furnace, a pyrolytic furnace, a steam superheater, a steam generator, a dryer, and the like. Provided is a hydrogen gas generation system or a power generation system formed by combining the water gas generation system with a hydrogen purifying apparatus or a power generation equipment.
Method and device for preparing active particle-containing steam
A method for preparing high-temperature, active particle-containing steam. The method includes: 1) preparing steam; selecting one or several non-oxidizing gases as a working gas; ionizing the working gas into a plasma working medium by using a plasma generator; and 2) injecting the plasma working medium into a high-temperature steam generator to form high-temperature ionized environment while introducing the steam into the high-temperature steam generator for allowing the steam to contact with the plasma working medium so that the steam is heated and activated to form active particle-containing steam. A device for preparing the high-temperature, active particle-containing steam is also provided.