A CO shift catalyst according to the present invention reforms carbon monoxide (CO) in gas. The CO shift catalyst has one of molybdenum (Mo) or iron (Fe) as a main component and has an active ingredient having one of nickel (Ni) or ruthenium (Ru) as an accessory component and one or two or more kinds of oxides from among titanium (Ti), zirconium (Zr), and cerium (Ce) for supporting the active ingredient as a support. The temperature at the time of manufacturing and firing the catalyst is equal to or higher than 550° C.

A temperature measurement system for a gasifier may employ a first stage gasifier with a refractory wall that defines a first stage gasifier volume. A protruding refractory brick may protrude from the first stage refractory wall and into a gaseous flow path of the first stage gasifier volume. The temperature sensor may reside completely through the refractory wall, which may be a plurality of brick layers, except for a tip end of a temperature sensor that may reside in a blind or non-through hole within the protruding refractory brick. The protruding refractory brick protrudes beyond a normal wall surface of the plurality of brick layers that defines the first stage gasifier volume. The protruding refractory brick may have a face that forms an angle that is not 90 degrees, such as 45 degrees, relative to the gaseous flow path of the fluid stream through the first stage gasifier volume.

The present disclosure relates to a power production system that is adapted to achieve high efficiency power production with carbon capture when using a solid or liquid hydrocarbon or carbonaceous fuel. More particularly, the solid or liquid fuel first is partially oxidized in a partial oxidation reactor that is configured to provide an output stream that is enriched in methane content. The resulting partially oxidized stream can be cooled, filtered, additionally cooled, and then directed to a combustor of a power production system as the combustion fuel. The partially oxidized stream is combined with a compressed recycle CO.sub.2 stream and oxygen. The combustion stream is expanded across a turbine to produce power and passed through a recuperator heat exchanger. The recycle CO.sub.2 stream is compressed and passed through the recuperator heat exchanger and optionally the POX heat exchanger in a manner useful to provide increased efficiency to the combined systems.

A cooling wall includes: a wall surface defined by arrangement of central axes of a plurality of cooling tubes; and an opening formed in a part of the wall surface in which a burner is installable, each of the plurality of cooling tubes forming the opening has a straight portion and a curved portion, the plurality of cooling tubes include a first cooling tube whose first virtual axis extending in an axial direction of the straight portion overlaps the opening, and a second cooling tube whose second virtual axis extending in an axial direction of the straight portion is located outside an outer circumference of the opening in a radial direction, the curved portion of the first cooling tube is arranged so as to form a curve along the outer circumference surface of the opening and on a surface along the wall surface.

A carbonaceous fuel gasification system for a supercritical CO.sub.2 power cycle system includes a micronized char preparation system comprising a devolatilizer that receives solid carbonaceous fuel, hydrogen, oxygen, and fluidizing steam and produces micronized char, steam, hydrogen, and volatiles. An indirect gasifier includes a vessel comprising a gasification chamber that receives the micronized char, a conveying gas, and steam where the gasification chamber provides syngas, ash, and steam. A combustion chamber receives syngas and an oxidant and burns the mixture of syngas with the oxidant to provide heat for gasification and for heating incoming flows, thereby generating steam and CO.sub.2. The heat for gasification is transferred from the combustion chamber to the gasification chamber by circulating refractory sand. A syngas cooler cools the syngas and generates steam and provides to a supercritical CO.sub.2 power cycle system that performs a supercritical CO.sub.2 power cycle for generating power.

A system for producing high purity carbon monoxide and hydrogen as well as activated carbon includes a pyrolysis reactor, a gasifier, a combustion turbine, a boiler, a steam turbine, a combined cycle unit and an electrolysis unit. Liquid fuel from the pyrolysis reactor is provided to the combustion turbine. Liquid and gaseous fuels are provided to the boiler. Compressed oxygen from the electrolysis unit is provided to the combustion turbine. Electric power from the combustion turbine and steam turbine are provided to the electrolysis unit. The gasifier includes a preheat region, a gasification region, and a cooling region. CO.sub.2 and O.sub.2 are injected into the gasifier at multiple injection levels to create an isothermal gasification region to produce CO. The CO.sub.2 and O.sub.2 are preheated in a heat exchanger using the CO exiting from the gasifier prior to injection.

A cooling wall includes: a wall surface defined by arrangement of central axes of a plurality of cooling tubes; and an opening formed in a part of the wall surface in which a burner is installable, each of the plurality of cooling tubes forming the opening has a straight portion and a curved portion, the plurality of cooling tubes include a first cooling tube whose first virtual axis extending in an axial direction of the straight portion overlaps the opening, and a second cooling tube whose second virtual axis extending in an axial direction of the straight portion is located outside an outer circumference of the opening in a radial direction, the curved portion of the first cooling tube is arranged so as to form a curve along the outer circumference surface of the opening and on a surface along the wall surface.

The invention relates to a process and system for converting carbon material into power. Carbon material 12 is gasified into synthesis gas 18 in a gasifier 16, and steam 14 is supplied to the gasifier 16. The synthesis gas 18 is supplied to a gas turbine 30, 36, 38 to produce power. Air 24 is added to the synthesis gas 18 prior to the gas turbine 30, 36, 38. Exhaust gas 40 from the gas turbine 30, 36, 38 is cooled in a first cooling device 42 with water 46 to produce steam 52. The steam is used in at least one steam turbine to produce power 56 and the steam 58 from at least one steam turbine 56 is recycled to the gasifier 16.

Provided are a slag crusher, a gasifier, an integrated gasification combined cycle, and an assembly method of a slag crusher that can ensure the strength of a guide rod. The slag crusher includes: a porous member screen; a spreader that is reciprocated in a predetermined direction along a top surface of the screen and crushes the slag accumulated on the screen; and a guide rod having an axis line along the predetermined direction, is connected to the spreader, and restricts a moving direction of the spreader, the guide rod has a spreader-side member connected to the spreader and a shaft member connected to the spreader-side member, the spreader-side member and the shaft member are connected by butt welding in the axis line direction, and the spreader-side member and the shaft member have the same shape of cross sections orthogonal to the axis line direction at a butt welding position.

A chemical looping combustion (CLC) based power generation, particularly using liquid fuel, ensures substantially complete fuel combustion and provides electrical efficiency without exposing metal oxide based oxygen carrier to high temperature redox process. An integrated fuel gasification (reforming)-CLC-followed by power generation model is provided involving (i) a gasification island, (ii) CLC island, (iii) heat recovery unit, and (iv) power generation system. To improve electrical efficiency, a fraction of the gasified fuel may be directly fed, or bypass the CLC, to a combustor upstream of one or more gas turbines. This splitting approach ensures higher temperature (efficiency) in the gas turbine inlet. The inert mass ratio, air flow rate to the oxidation reactor, and pressure of the system may be tailored to affect the performance of the integrated CLC system and process.