A carbonaceous fuel gasification system for all-steam gasification with carbon capture includes a micronized char preparation system comprising a devolatilizer that receives solid carbonaceous fuel, hydrogen, oxygen, and fluidizing steam and produces micronized char, steam, volatiles, hydrogen, and volatiles at outlets. An indirect gasifier includes a vessel comprising a gasification chamber that receives the micronized char, a conveying fluid, and steam. The gasification chamber produces syngas, ash, and steam at one or more outlets. A combustion chamber receives a mixture of hydrogen and oxidant and burns the mixture of hydrogen and oxidant to provide heat for gasification and for heating incoming flows, thereby generating steam and nitrogen. The heat for gasification is transferred from the combustion chamber to the gasification chamber by circulating refractory sand. The system of the present teaching produces nitrogen free high hydrogen syngas for applications such as IGCC with CCS, CTL, and Polygeneration plants.

The description describes the integration of a gas fermentation process with a gasification process whereby effluent from the gas fermentation process is recycled to the gasification process. The one or more effluents which can be recycled include a stream comprising microbial biomass, a product stream comprising at least a portion of the at least one fermentation product, a by-product stream comprising fusel oil, and a waste water stream comprising microbial biomass. The stream comprising biomass can be dried before it is passed to the gasification zone. At least a portion of the waste water stream can be passed to the gasification process where one use is to replace at least a portion of the process water. The waste water stream can be further processed to produce a clarified water stream and a biogas stream comprising methane either or both of which can be passed to the gasification process.

The present disclosure provides a novel and practical alcohol and derivatives thereof which have more industrial value than existing petrochemical raw materials. The present disclosure further provides ethanol, characterized in that a peak in gas chromatography measured by gas chromatograph mass spectrometry (GC/MS) has at least one peak with a retention time selected from (A) a peak of 5 minutes 25 seconds to 5 minutes 35 seconds and two peaks of 2 minutes 55 seconds to 3 minutes 5 seconds; (B) a peak of 12 minutes 30 seconds to 12 minutes 40 seconds; (C) a peak of 6 minutes 36 seconds to 6 minutes 45 seconds; and (D) a peak of 15 minutes 00 seconds to 15 minutes 15 seconds.

It is provided a method of converting a carbonaceous material into syngas at a carbon conversion rate of at least 78% comprising gasifying the carbonaceous material in a fluidized bed reactor producing a crude syngas, classifying the crude syngas by particle size and density into a cut sizing device, introducing the classified particle crude syngas into a thermal reformer and reforming the classified crude syngas at a temperature above mineral melting point, producing the syngas.

A process for preparing methanol by a methanol synthesis reaction of carbon dioxide with hydrogen may involve a distillation step and a condensation step following the synthesis of a crude methanol. A volatile component and water may be separated off from a methanol-containing product stream, and a gas stream containing a volatile component that has been separated off may be discharged at least partially as offgas. At least part of the gas stream that has been separated off may be recirculated into the methanol synthesis reaction. A plant for preparing methanol can store or utilize electric power generated from renewable energy sources and provide facilities for discharging the offgas stream, which can be purified by catalytic after-combustion. Alternatively, the plant can be configured without discharge of an offgas substream, or the offgas streams are so small that they can be released without treatment into the environment at a suitable position.

Densified textile aggregates are co-fed with a fuel into a partial oxidation gasifier. High solids concentrations in the feedstock composition can be obtained without significant impact on the feedstock composition stability and pumpability. A consistent quality of syngas can be continuously produced, including generation of carbon dioxide and a carbon monoxide/hydrogen ratio while stably operating the gasifier and avoiding the high tar generation of fluidized bed or fixed bed waste gasifiers and without impacting the operations of the gasifier. The syngas quality, composition, and throughput are suitable for produce a wide range of chemicals.

High concentrations of recycle polymer are gasified in a partial oxidation gasifier to make a syngas useful to make a variety of chemicals and polymers, such as cellulose ester. Polymers such as cellulose esters can be made that are obtained from sustainable sources, recycle sources, and are biodegradable. Circularity in the manufacture of textiles and/or plastics made from the fibers of such cellulose esters can now be achieved. The process of making such a syngas from high concentrations of recycle polymer (e.g. textiles and/or plastics) includes campaigning for the production of syngas.

Torrefied textiles can be gasified to produce a syngas suitable for making chemicals. Gasifying torrefied textile can generate a consistent quality of syngas and a hydrogen/carbon monoxide ratio closer to that of coal relative to gasifying textiles. A variety of chemical compounds, reactants, polymers, fibers, and textiles can now be made utilizing syngas made by gasifying torrefied textiles.

Densified textile aggregates are co-fed with a fuel into a partial oxidation gasifier. High solids concentrations in the feedstock composition can be obtained without significant impact on the feedstock composition stability and pumpability. A consistent quality of syngas can be continuously produced, including generation of carbon dioxide and a carbon monoxide/hydrogen ratio while stably operating the gasifier and avoiding the high tar generation of fluidized bed or fixed bed waste gasifiers and without impacting the operations of the gasifier. The syngas quality, composition, and throughput are suitable for produce a wide range of chemicals.

An organic material gasification system is configured such that a carbonization furnace provided with a first air supply mechanism that radiates high-temperature combustion air and high-temperature steam to an organic material combustion region and with a second air supply mechanism that supplies combustion air to an exhaust gas combustion region, to discharge high-temperature exhaust gas is connected to a gasification furnace including a heating unit penetrating through a reactor. A carbide from the carbonization furnace is supplied to the reactor, and the high-temperature exhaust gas from the carbonization furnace is supplied to the heating unit, so that the carbonization efficiency and the carbonization quality are improved and the gasification efficiency is improved.