This disclosure relates to compositions and methods of making an additized fuel composition comprising a base fuel composition and a randomly branched nitrate composition. The randomly branched nitrate composition includes a plurality of primary nitrate molecules, each molecule therein having an empirical chemical formula of C.sub.nNO.sub.3, wherein C.sub.n is a branched aliphatic moiety which may be the same or different for each molecule, n is an integer selected from the group consisting of 8, 9, 10, 11 and 12, at least one carbon atom in the branched aliphatic moiety being bound to three or more carbon atoms, a branching index ranging from 1.8 to 2.2, and greater than 80% of the branches in the aliphatic moiety being in other than the alpha position. The additized fuel composition may be diesel fuel composition or a gasoline fuel composition.

Improved fuel compositions and fuel additive packages which serve to prolong stability at various ambient conditions and to increase fuel efficiency and fuel economy while also significantly reducing the level of multiple emissions constituents generated upon combustion of the fuels including CO.sub.2, NO.sub.X, SO.sub.X, Particulate Matter PM2.5, PM10 and Black Carbon. The fuels may include the hydrocarbon fuels gasolines, diesel fuels, biodiesel fuels, biomass diesel fuels, renewable fuels, synthetic fuels, algae-based fuels, kerosene fuel or heavy fuel oils, or may alternatively be hydrosols, and include an additive package having a sorbitan oleate, a polyoxyethylene alcohol, an alkylene glycol, and an amine. The fuels are mixed with an additive and are emulsified with clean, soft water having a water quality of 1 micron or less.

The invention relates to quaternary ammonium amide and/or ester salts and their use as additives, including their use in fuels, such as diesel fuel. The invention particularly relates to the use of quaternary ammonium amide and/or ester salts as detergents in diesel fuels.

A fuel composition for a spark-ignition internal combustion engine comprises a non-metallic octane-boosting additive. The non-metallic octane-boosting additive is an additive which, when used at a treat rate of 0.67 % by weight, increases the research octane number of a fuel by at least 1.8 whilst maintaining the T.sub.90 and/or the vapour pressure.

An additive composition for use in a fuel for a spark-ignition internal combustion engine comprises an octane-boosting additive and one or more further fuel additives. The octane-boosting additive has a chemical structure comprising a 6-membered aromatic ring sharing two adjacent aromatic carbon atoms with a 6- or 7-membered saturated heterocyclic ring, the 6- or 7-membered saturated heterocyclic ring comprising a nitrogen atom directly bonded to one of the shared carbon atoms to form a secondary amine and an atom selected from oxygen or nitrogen directly bonded to the other shared carbon atom, the remaining atoms in the 6- or 7-membered heterocyclic ring being carbon. The additive composition increases the octane number of the fuel, thereby proving the auto-ignition characteristics of a fuel.

A fuel composition for a spark-ignition internal combustion engine comprises an additive having a chemical structure comprising a 6-membered aromatic ring sharing two adjacent aromatic carbon atoms with a 6- or 7-membered saturated heterocyclic ring, the 6- or 7-membered saturated heterocyclic ring comprising a nitrogen atom directly bonded to one of the shared carbon atoms to form a secondary amine and an atom selected from oxygen or nitrogen directly bonded to the other shared carbon atom, the remaining atoms in the 6- or 7-membered heterocyclic ring being carbon. The additive increases the octane number of the fuel, thereby improving the auto-ignition characteristics of the fuel.

This disclosure relates to compositions and methods of making an additized fuel composition comprising a base fuel composition and a randomly branched nitrate composition. The randomly branched nitrate composition includes a plurality of primary nitrate molecules, each molecule therein having an empirical chemical formula of CnNO3, wherein Cn is a branched aliphatic moiety which may be the same or different for each molecule, n is an integer selected from the group consisting of 8, 9, 10, 11 and 12, at least one carbon atom in the branched aliphatic moiety being bound to three or more carbon atoms, a branching index ranging from 1.8 to 2.2, and greater than 80% of the branches in the aliphatic moiety being in other than the alpha position. The additized fuel composition may be diesel fuel composition or a gasoline fuel composition. Such randomly branched nitrate composition may be more stable, and thus safer to handle than 2-ethylhexylnitrate and may have a lower overall nitrogen content, leading to lower NOx emissions upon combustion in diesel and gasoline fuel compositions.

A compression ignition engine fuel has 95.0% to 99.9% by weight ammonia and 0.01% to 5.0% by weight of an alkyl nitrate or mixture of alkyl nitrates.

A compression ignition engine fuel includes 98.0% to 99.9% by weight of methanol and 0.01% to 2.0% by weight of an alkyl nitrate or mixture of alkyl nitrates.

The invention relates to a compression ignition engine fuel comprising 95.0% to 99.9% by weight ammonia and 0.01% to 5.0% by weight of an alkyl nitrate or mixture of alkyl nitrates.