A fuel for an internal combustion engine includes a C.sub.5 to C.sub.30 dialkoxyalkanoate corresponding to formula (I):

##STR00001##

wherein the R.sub.1 group is —H or a —CH.sub.3 group, the R.sub.2 and R.sub.2′ groups are alkyl groups independently selected to have 1 to 9 carbon atoms; and the R.sub.3 group is selected to have 1 to 9 carbon atoms. The compounds described herein may be used as neat fuels or mixed fuels (with diesel, biodiesel, jet fuel, marine fuel or other fuel compounds) in autoignition or spark ignition engines, such as diesel engines, gasoline (spark ignition) engines, MCCI, Homogeneous Charge Compression Ignition (HCCI) engines, or more generally in Low-Temperature Gasoline Combustion (LTGC) engines (using gasoline-like fuels), that have the high-efficiency advantages of HCCI but can operate with some level of charge inhomogeneities. Methods of making these compounds are environmentally friendly and can be done in a continuous manner.

A method for conversion of food waste to biofuel can include a first fermentation in which food waste is converted C.sub.2-C.sub.4 short-chain carboxylic acids, and a second fermentation in which the C.sub.2-C.sub.4 short-chain carboxylic acid are elongated into C.sub.5-C.sub.8 medium-chain carboxylic acids. Medium-chain carboxylic acids can undergo hydrogenation-dehydration of the medium-chain carboxylic acids into C.sub.5-C.sub.8 linear olefins. The C.sub.5-C.sub.8 linear olefins are then oligomerized to a C.sub.10-C.sub.25 mixture comprising olefins, paraffin, cycloparaffins, and aromatics through dimerization; and saturated to C.sub.10-C.sub.25 mixture by hydrogenation to produce the biofuel.

A fuel for an internal combustion engine includes a C.sub.5 to C.sub.30 dialkoxyalkanoate corresponding to formula (I): ##STR00001## wherein the R.sub.1 group is —H or a —CH.sub.3 group, the R.sub.2 and R.sub.2′ groups are alkyl groups independently selected to have 1 to 9 carbon atoms; and the R.sub.3 group is selected to have 1 to 9 carbon atoms. The compounds described herein may be used as neat fuels or mixed fuels (with diesel, biodiesel, jet fuel, marine fuel or other fuel compounds) in autoignition or spark ignition engines, such as diesel engines, gasoline (spark ignition) engines, MCCI, Homogeneous Charge Compression Ignition (HCCI) engines, or more generally in Low-Temperature Gasoline Combustion (LTGC) engines (using gasoline-like fuels), that have the high-efficiency advantages of HCCI but can operate with some level of charge inhomogeneities. Methods of making these compounds are environmentally friendly and can be done in a continuous manner.

Hydroprocessed residual fuel and/or fuel blending components are provided that have a sulfur and nitrogen level comparable to liquefied natural gas (LNG). Because of the low starting level of sulfur and/or nitrogen, the severity of the hydroprocessing that is needed for the crude oil or bottoms fraction in order to remove sulfur to a level that is comparable to LNG is reduced or minimized. This can allow the resulting marine residual fuels to have low carbon intensity, low SOx and NOx emission and high energy density. Since the hydroprocessed fractions correspond to a fuel oil product, the resulting marine fuel can be used in existing fleets, and can be distributed in existing bunkering systems.

Systems and methods to provide low carbon intensity (CI) transportation fuels through one or more targeted reductions of carbon emissions based upon an analysis of carbon emissions associated with a combination of various options for feedstock procurement, feedstock refining, processing, or transformation, and fuel product distribution pathways to end users. Such options are selected to maintain the total CI (carbon emissions per unit energy) of the transportation fuel below a pre-selected threshold that defines an upper limit of CI for the transportation fuel.

A method comprising a series of selective extraction techniques for the parallel production of biodiesel and isolation of several valuable co-products including an alkenone hydrocarbon mixture of the kerosene/jet fuel range (primarily C10-, C12-, and C17-hydrocarbons) and fucoxanthin, a high-valued carotenoid, from the marine alkenone-producing microalgae Isochrysis.

Systems and methods to provide low carbon intensity (CI) transportation fuels through one or more targeted reductions of carbon emissions based upon an analysis of carbon emissions associated with a combination of various options for feedstock procurement, feedstock refining, processing, or transformation, and fuel product distribution pathways to end users. Such options are selected to maintain the total CI (carbon emissions per unit energy) of the transportation fuel below a pre-selected threshold that defines an upper limit of CI for the transportation fuel.

The present invention concerns a process for producing biodiesel with bifunctional heterogeneous acidic catalysts from acidic raw materials, such as fatty acids and mixtures of fatty acids with triglycerides.

Disclosed are multifunctional compounds represented by structural formula (I):

##STR00001##

methods of producing compounds represented by structural formula (I) and their use in inhibiting corrosion in corrodible material.

Provided are marine fuels or fuel blending compositions, methods of making such fuels or compositions and methods of potentially reducing the life cycle carbon intensity of marine fuels or a fuel blending compositions. The marine fuel or fuel blending composition disclosed herein includes at least 20 vol % of a resid-containing fraction, and from 5 vol % to 80 vol % of one or more renewable fuel blending components. The one or more renewable fuel blending components includes one or more fatty acid alkyl esters. Optionally the one or more renewable fuel blending components may include gas-to-liquid hydrocarbons from renewable synthesis gas, hydrotreated natural fat or oil, hydrotreated waste cooking oil, hydrotreated tall oil, pyrolysis gas oil, or combinations thereof. Optionally, the resulting marine fuel or fuel blending composition can have a BMCI−TE difference value of 15 or less.