The present disclosure provides an ionic liquid produced from a renewable source and with excellent lubricating properties, and methods of making the same. The ionic liquid includes an anion salt of at least one of a fatty acid, a rosin acid, or derivative thereof. The method for making the ionic liquid or lubricant composition of the present disclosure includes admixing a cation and an anion in a ratio of about a 1.5:1 to about 1:1.5 at room temperature to form a reaction mixture, wherein the anion comprises at least one of a fatty acid, a rosin acid, derivative thereof, or a combination thereof, and the cation comprises at least one of choline, imidazolium, pyridium, pyrrolidinium, ammonium, phosphonium, sulfonium, derivatives thereof, or combinations thereof; maintaining the reaction mixture at a pH of about 6 to about 9; and drying under reduced pressure to yield a lubricant including an ionic liquid.

The present disclosure provides an ionic liquid produced from a renewable source and with excellent lubricating properties, and methods of making the same. The ionic liquid includes an anion salt of at least one of a fatty acid, a rosin acid, or derivative thereof. The method for making the ionic liquid or lubricant composition of the present disclosure includes admixing a cation and an anion in a ratio of about a 1.5:1 to about 1:1.5 at room temperature to form a reaction mixture, wherein the anion comprises at least one of a fatty acid, a rosin acid, derivative thereof, or a combination thereof, and the cation comprises at least one of choline, imidazolium, pyridium, pyrrolidinium, ammonium, phosphonium, sulfonium, derivatives thereof, or combinations thereof; maintaining the reaction mixture at a pH of about 6 to about 9; and drying under reduced pressure to yield a lubricant including an ionic liquid.

Embodiments are directed to a lubricant package for water based drilling fluids. The lubricant package includes water, a polyethylene glycol, and a lubricating agent. The lubricating agent includes triethanolamine, or a C.sub.12-C.sub.14 alcohol ethoxylate, or a combination of triethanolamine and C.sub.12-C.sub.14 alcohol ethoxylate. The weight ratio of the polyethylene glycol to the lubricating agent in the lubricant package is from 1:2 to 2:1. Embodiments are also directed to a water-based drilling fluid composition including an aqueous base fluid, one or more additives, and the lubricant package for water based drilling fluids.

Embodiments are directed to a lubricant package for water based drilling fluids. The lubricant package includes water, a polyethylene glycol, and a lubricating agent. The lubricating agent includes triethanolamine, or a C.sub.12-C.sub.14 alcohol ethoxylate, or a combination of triethanolamine and C.sub.12-C.sub.14 alcohol ethoxylate. The weight ratio of the polyethylene glycol to the lubricating agent in the lubricant package is from 1:2 to 2:1. Embodiments are also directed to a water-based drilling fluid composition including an aqueous base fluid, one or more additives, and the lubricant package for water based drilling fluids.

In one embodiment, a retarded acid system comprises an aqueous acid and a retarding surfactant. The aqueous acid may comprise from 5 wt. % to 25 wt. % of a strong acid, that is, an acid having a K.sub.a greater than or equal to 0.01. The aqueous acid may further comprise from 75 wt. % to 95 wt. % water. The retarding surfactant may have the general chemical formula R(OC.sub.2H.sub.4).sub.XOH where R is a hydrocarbon having from 11 to 15 carbon atoms and x is an integer from 6 to 10. The retarding surfactant may have a hydrophilic-lipophilic balance from 8 to 16.

In one embodiment, a retarded acid system comprises an aqueous acid and a retarding surfactant. The aqueous acid may comprise from 5 wt. % to 25 wt. % of a strong acid, that is, an acid having a K.sub.a greater than or equal to 0.01. The aqueous acid may further comprise from 75 wt. % to 95 wt. % water. The retarding surfactant may have the general chemical formula R(OC.sub.2H.sub.4).sub.XOH where R is a hydrocarbon having from 11 to 15 carbon atoms and x is an integer from 6 to 10. The retarding surfactant may have a hydrophilic-lipophilic balance from 8 to 16.

A drilling fluid composition which includes a base fluid, one or more additives, and a viscosifier package. The base fluid is an invert emulsion comprising oil and water. Further, the one or more additives is chosen from an emulsifier, a weighting material, a fluid-loss control additive, or an alkaline compound. The viscosifier package includes a fatty acid having 6 or more carbon atoms and an aliphatic polyester. The drilling fluid composition has a yield point of from 30 lb.sub.f/100 ft.sup.2 to 100 lb.sub.f/100 ft.sup.2 and a low shear yield point of from 10 lb.sub.f/100 ft.sup.2 to 40 lb.sub.f/100 ft.sup.2. The associated method of drilling a subterranean well including operating a drill in a wellbore in the presence of the drilling fluid composition is also provided.

A drilling fluid composition which includes a base fluid, one or more additives, and a viscosifier package. The base fluid is an invert emulsion comprising oil and water. Further, the one or more additives is chosen from an emulsifier, a weighting material, a fluid-loss control additive, or an alkaline compound. The viscosifier package includes a fatty acid having 6 or more carbon atoms and an aliphatic polyester. The drilling fluid composition has a yield point of from 30 lb.sub.f/100 ft.sup.2 to 100 lb.sub.f/100 ft.sup.2 and a low shear yield point of from 10 lb.sub.f/100 ft.sup.2 to 40 lb.sub.f/100 ft.sup.2. The associated method of drilling a subterranean well including operating a drill in a wellbore in the presence of the drilling fluid composition is also provided.

In one embodiment, a spacer fluid may comprise a base fluid and a surfactant package. The surfactant package may comprise one or more surfactants, where the surfactant package comprises a first surfactant having the chemical structure R(OC.sub.2H.sub.4).sub.xOH. R may be a hydrocarbyl group having from 9 to 20 carbon atom, and x may be an integer from 5 and 15. The first surfactant may have a hydrophilic-lipophilic balance (HLB) of from 12 to 13.5.

In one embodiment, a spacer fluid may comprise a base fluid and a surfactant package. The surfactant package may comprise one or more surfactants, where the surfactant package comprises a first surfactant having the chemical structure R(OC.sub.2H.sub.4).sub.xOH. R may be a hydrocarbyl group having from 9 to 20 carbon atom, and x may be an integer from 5 and 15. The first surfactant may have a hydrophilic-lipophilic balance (HLB) of from 12 to 13.5.