Patent classifications
C10M145/34
Polyalkylene glycol lubricant compositions
The present disclosure provides A lubricant composition comprises an antioxidant; and an esterified polyalkylene glycol: R.sup.1[O(R.sup.2O).sub.n(R.sup.3O).sub.m(C═O)R.sup.4].sub.p, wherein R.sup.1 is a linear alkyl having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R.sup.2O is an oxypropylene moiety derived from 1,2-propylene oxide; R.sup.3O is an oxybutylene moiety derived from butylene oxide, wherein R.sup.2O and R.sup.3O are in a block or a random distribution; R.sup.4 is a linear alkyl with 1 to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4, wherein the antioxidant is present in an amount by weight of at least 0.5% to 20% based upon the weight of the antioxidant and the esterified polyalkylene glycol and the antioxidant is soluble in the esterified polyalkylene glycol in an amount of at least 0.5% by weight. The lubricant composition may be used as an additive to form a hydrocarbon lubricant composition.
Polyalkylene glycol lubricant compositions
The present disclosure provides A lubricant composition comprises an antioxidant; and an esterified polyalkylene glycol: R.sup.1[O(R.sup.2O).sub.n(R.sup.3O).sub.m(C═O)R.sup.4].sub.p, wherein R.sup.1 is a linear alkyl having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R.sup.2O is an oxypropylene moiety derived from 1,2-propylene oxide; R.sup.3O is an oxybutylene moiety derived from butylene oxide, wherein R.sup.2O and R.sup.3O are in a block or a random distribution; R.sup.4 is a linear alkyl with 1 to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4, wherein the antioxidant is present in an amount by weight of at least 0.5% to 20% based upon the weight of the antioxidant and the esterified polyalkylene glycol and the antioxidant is soluble in the esterified polyalkylene glycol in an amount of at least 0.5% by weight. The lubricant composition may be used as an additive to form a hydrocarbon lubricant composition.
Alkyl capped oil soluble polymer viscosity index improving additives for base oils in automotive applications
An automotive lubricant base oil formulation contains a base oil, preferably a hydrocarbon base oil, having a kinematic viscosity of 100 centiStokes or less at 40 degrees Celsius and an ailcyl capped oil soluble polymer where the alkyl capped oil soluble polymer has the structure of Formula 0): where R.sup.1 is an alkyl having from one to thirty carbons, R.sup.2 and R.sup.3 are independently selected from alkyl groups having three or four carbons and can be in block form or randomly combined, R.sup.4 is an alkyl having from one to 18 carbon atoms, n and m are independently numbers ranging from zero to 20 provided that n+m is greater than zero and p is a number within a range of one to three and a kinematic viscosity of 100 centiStokes or less at 40 degrees Celsius is useful in a lubricant for mechanical devices.
R.sup.1[O(R.sup.2O).sub.n(R.sup.3O).sub.mR.sup.4].sub.p (I)
Alkyl capped oil soluble polymer viscosity index improving additives for base oils in automotive applications
An automotive lubricant base oil formulation contains a base oil, preferably a hydrocarbon base oil, having a kinematic viscosity of 100 centiStokes or less at 40 degrees Celsius and an ailcyl capped oil soluble polymer where the alkyl capped oil soluble polymer has the structure of Formula 0): where R.sup.1 is an alkyl having from one to thirty carbons, R.sup.2 and R.sup.3 are independently selected from alkyl groups having three or four carbons and can be in block form or randomly combined, R.sup.4 is an alkyl having from one to 18 carbon atoms, n and m are independently numbers ranging from zero to 20 provided that n+m is greater than zero and p is a number within a range of one to three and a kinematic viscosity of 100 centiStokes or less at 40 degrees Celsius is useful in a lubricant for mechanical devices.
R.sup.1[O(R.sup.2O).sub.n(R.sup.3O).sub.mR.sup.4].sub.p (I)
LUBRICATING OIL COMPOSITIONS AND METHODS OF USE
This disclosure relates to a method for improving air release in a lubricating oil. The method involves formulating a composition having at least one lubricating oil base stock as a major component, and one or more lubricating oil additives, as a minor component. The one or more lubricating oil additives include at least one polyalkylene glycol. The at least one polyalkylene glycol is soluble in the at least one lubricating oil base stock. The weight ratio of the at least one polyalkylene glycol to the at least one lubricating oil base stock is from about 1:99 to about 7:93. During operation of a lubricating system containing the lubricating oil, release of entrained air in the lubricating oil is improved, as determined by ASTM D-3427-15, as compared to release of entrained air achieved using a lubricating oil containing other than the at least one polyalkylene glycol. This disclosure also relates to lubricating oils having at least one oil soluble polyalkylene glycol (OSP).
LUBRICATING OIL COMPOSITIONS AND METHODS OF USE
This disclosure relates to a method for improving air release in a lubricating oil. The method involves formulating a composition having at least one lubricating oil base stock as a major component, and one or more lubricating oil additives, as a minor component. The one or more lubricating oil additives include at least one polyalkylene glycol. The at least one polyalkylene glycol is soluble in the at least one lubricating oil base stock. The weight ratio of the at least one polyalkylene glycol to the at least one lubricating oil base stock is from about 1:99 to about 7:93. During operation of a lubricating system containing the lubricating oil, release of entrained air in the lubricating oil is improved, as determined by ASTM D-3427-15, as compared to release of entrained air achieved using a lubricating oil containing other than the at least one polyalkylene glycol. This disclosure also relates to lubricating oils having at least one oil soluble polyalkylene glycol (OSP).
METHOD FOR CONTROLLING LUBRICATION OF A ROTARY SHAFT SEAL
This disclosure relates to a method for controlling lubrication of a rotary shaft seal. The method involves providing an apparatus having a bulk lubricating oil reservoir, a rotary shaft that passes through the bulk lubricating oil reservoir, and a rotary shaft seal. The rotary shaft seal has a sealing edge in proximity with the rotary shaft creating a contact zone. The contact zone has a film of lubricating oil. The method also involves increasing the rate of heat flow along the rotary shaft to reduce temperature of the film of lubricating oil in the contact zone. Increasing the rate of heat flow along the rotary shaft is accomplished by using rotary shaft materials of construction having sufficient high thermal conductivity, rotary shaft coatings having sufficient high thermal conductivities, or increasing the surface area of the rotary shaft. This disclosure also relates to a method for controlling heat transfer in a contact zone, and a method for improving performance of an apparatus.
MULTIFUNCTIONAL LUBRICANT ADDITIVE AND SELECTION METHOD
A blend for lubricating a surface includes a lubricant and a polyepoxide co(ter)polymer additive mixed with the lubricant. The polyepoxide co(ter)polymer additive includes a first block having monomer M.sub.1 and a second block having monomer M.sub.2. The first monomer M.sub.1 includes hexene oxide, HO, or octene oxide, OO, and the second monomer M.sub.2 includes propylene oxide, PO.
MULTIFUNCTIONAL LUBRICANT ADDITIVE AND SELECTION METHOD
A blend for lubricating a surface includes a lubricant and a polyepoxide co(ter)polymer additive mixed with the lubricant. The polyepoxide co(ter)polymer additive includes a first block having monomer M.sub.1 and a second block having monomer M.sub.2. The first monomer M.sub.1 includes hexene oxide, HO, or octene oxide, OO, and the second monomer M.sub.2 includes propylene oxide, PO.
Use of Lubricants on the Basis of Water-Soluble, High Viscosity Polyglycols
The present invention relates to the use of lubricants on the basis of water-soluble, high-viscosity polyethylene glycols for lubricating open gearing, which is for example used in rotary kilns and mills.