A sulfonatocalixarene tanning agent for leather tanning and a preparation method comprises: using resorcinol and aldehyde monomers as raw materials for the tanning agent; adding an ethanol solution into the resorcinol, dropwise adding an inorganic strong acid catalyst and aldehyde derivatives, heating to react, cooling, carrying out suction filtration, repeatedly washing with ethanol and distilled water, and drying to obtain resorcinol calixarene; and weighing the resorcinol calixarene, and adding a sulfonating agent to react, thereby obtaining a sulfonatocalixarene tanning agent aqueous solution.

A sulfonatocalixarene tanning agent for leather tanning and a preparation method comprises: using resorcinol and aldehyde monomers as raw materials for the tanning agent; adding an ethanol solution into the resorcinol, dropwise adding an inorganic strong acid catalyst and aldehyde derivatives, heating to react, cooling, carrying out suction filtration, repeatedly washing with ethanol and distilled water, and drying to obtain resorcinol calixarene; and weighing the resorcinol calixarene, and adding a sulfonating agent to react, thereby obtaining a sulfonatocalixarene tanning agent aqueous solution.

The present invention relates to the tanning industry and in particular to the use of an epoxidized vegetable oil as a tanning agent in at least one step of the leather processing process of the tanning industry.

The present invention relates to the tanning industry and in particular to the use of an epoxidized vegetable oil as a tanning agent in at least one step of the leather processing process of the tanning industry.

The present invention provides a method of manufacturing leather, which not only significantly suppresses the occurrence of adhesive wrinkling and boarding/alighting wrinkling when used for an automobile seat, for example, but also exhibits appropriate flexibility. The present invention is a method of manufacturing leather including a pretreatment step, a tanning step, a retanning step, and a drying and finishing step in this order, the retanning process including, in the following order, subjecting a shaving leather obtained from the tanning process to a stage of performing treatment using a predetermined retanning agent and a predetermined resin, a stage of performing treatment using a predetermined retanning agent, a predetermined resin, and a predetermined fatliquoring agent, and a stage of performing treatment using a predetermined resin and a predetermined fatliquoring agent, and the drying in the drying and finishing process including, in the following order, subjecting a leather obtained from the retanning process to a stage of drying under reduced pressure under predetermined conditions and a step of drying at atmospheric pressure under predetermined conditions.

The present invention provides a method of manufacturing leather, which not only significantly suppresses the occurrence of adhesive wrinkling and boarding/alighting wrinkling when used for an automobile seat, for example, but also exhibits appropriate flexibility. The present invention is a method of manufacturing leather including a pretreatment step, a tanning step, a retanning step, and a drying and finishing step in this order, the retanning process including, in the following order, subjecting a shaving leather obtained from the tanning process to a stage of performing treatment using a predetermined retanning agent and a predetermined resin, a stage of performing treatment using a predetermined retanning agent, a predetermined resin, and a predetermined fatliquoring agent, and a stage of performing treatment using a predetermined resin and a predetermined fatliquoring agent, and the drying in the drying and finishing process including, in the following order, subjecting a leather obtained from the retanning process to a stage of drying under reduced pressure under predetermined conditions and a step of drying at atmospheric pressure under predetermined conditions.

A sulfonatocalixarene tanning agent for leather tanning and a preparation method comprises: using resorcinol and aldehyde monomers as raw materials for the tanning agent; adding an ethanol solution into the resorcinol, dropwise adding an inorganic strong acid catalyst and aldehyde derivatives, heating to react, cooling, carrying out suction filtration, repeatedly washing with ethanol and distilled water, and drying to obtain resorcinol calixarene; and weighing the resorcinol calixarene, and adding a sulfonating agent to react, thereby obtaining a sulfonatocalixarene tanning agent aqueous solution.

A sulfonatocalixarene tanning agent for leather tanning and a preparation method comprises: using resorcinol and aldehyde monomers as raw materials for the tanning agent; adding an ethanol solution into the resorcinol, dropwise adding an inorganic strong acid catalyst and aldehyde derivatives, heating to react, cooling, carrying out suction filtration, repeatedly washing with ethanol and distilled water, and drying to obtain resorcinol calixarene; and weighing the resorcinol calixarene, and adding a sulfonating agent to react, thereby obtaining a sulfonatocalixarene tanning agent aqueous solution.

A method of synthesizing a resin including mixing a first solution including a melamine compound with a second solution including glutaraldehyde to form a third solution, heating the third solution to 35 C. to 90 C. in at a pH above 7 for 5 to 70 minutes, and cooling the third solution to room temperature.

A process for tanning leathers including a pre-tanning step and a tanning step is provided. In the pre-tanning step leathers are treated with a cationic active agent including a quaternized ester of a fatty acid and triethanolamine, or mixtures thereof and, subsequently, with an anionic active agent including tannins vegetable extracts and a natural or synthetic dispersant selected from the group consisting of lignosulfonates, distillation stillages, sulfonated disulfonic polymers, sulfonated naphthalene polymers or mixtures thereof, to obtain leathers with a shrinkage temperature of at least 65 C. The pre-tanning and tanning steps do not include treatment with aldehydes or aldehyde donor compounds and/or with metal salts.