A method for producing granular metallic iron of the present invention includes: an agglomeration step of obtaining agglomerates through agglomeration of a mixture that contains an iron oxide-containing material and a carbonaceous reducing agent; and a granulation step of obtaining granular metallic iron by heating the agglomerates, reducing iron oxides in the agglomerates, aggregating generated metallic iron to be granular while separating the metallic iron from slag generated as a by-product, and thereafter cooling and solidifying the metallic iron, wherein agglomerates satisfying all the conditions given by formulas (1) to (3) below are used as the agglomerates: (1) [(total CaO amount+total SiO.sub.2 amount+total Al.sub.2O.sub.3 amount)/total Fe amount]≧0.250; (2) (total CaO amount/total SiO.sub.2 amount)≧0.9; (3) [total Al.sub.2O.sub.3 amount/(total CaO amount+total SiO.sub.2 amount+total Al.sub.2O.sub.3 amount)]×100≧9.7. In the formulas, the total CaO amount, the total SiO.sub.2 amount, the total Al.sub.2O.sub.3 amount and the total Fe amount respectively represent the mass percentage of CaO, the mass percentage of SiO.sub.2, the mass percentage of Al.sub.2O.sub.3 and the mass percentage of Fe contained in the agglomerates.

A method of forming a metal alloy. The method comprises forming a metal oxide precursor and conducting cathodic polarization of the metal oxide precursor in a molten salt electrolyte to form a metal alloy. In an additional method, a metal oxide precursor is formed. The metal oxide precursor is reduced to a metal in an electrochemical cell that comprises a working electrode, a counter electrode, and an electrolyte. The metal is reacted with a metal of the working electrode to form a metal alloy. In another method, a metal oxide precursor is formed on a base material. The base material is introduced into a molten salt electrolyte of an electrochemical cell and the metal oxide precursor is reduced to a metal in the electrochemical cell. The metal is reacted with the base material to form a metal alloy on the base material.

A process for the incineration of precious metal catalyst briquettes, wherein the precious metal catalyst briquettes comprise precious metal catalyst, optionally water, and, also optionally, binder.

A process for upgrading waste powders of the mining industry containing iron oxides is described, which includes preparing a mixture containing powder based on iron oxides, an aqueous dispersion of a thermosetting resin and optionally carbon powder, and a catalyst of acidic nature; kneading the mixture at a temperature between 5 and 100° C. to form a homogeneous paste, and granulating such homogeneous paste at a temperature between 100 and 300° C., thus obtaining granules of powder based on iron oxides and optionally carbon powder bound by the resin that has been polymerized.

A process for upgrading waste powders of the mining industry containing iron oxides is described, which includes preparing a mixture containing powder based on iron oxides, an aqueous dispersion of a thermosetting resin and optionally carbon powder, and a catalyst of acidic nature; kneading the mixture at a temperature between 5 and 100° C. to form a homogeneous paste, and granulating such homogeneous paste at a temperature between 100 and 300° C., thus obtaining granules of powder based on iron oxides and optionally carbon powder bound by the resin that has been polymerized.

The invention also provides a briquette comprising: (i) a particulate material; and (ii) a binder, the binder comprising (a) at least partially saponified polyvinyl alcohol and (b) an alkali metal alkyl siliconate or polyalkylsilicic acid; wherein the particulate material is selected from a carbonaceous material, metal, metal ore, mineral waste or a mixture thereof.

The present invention relates to metallurgical processes, and more particularly to a process for producing titaniferous feedstock and fines, a process for agglomerating titaniferous fines, and a process for producing titaniferous metals and titaniferous alloys. Recovery of rare-earth, vanadium and scandium from titanium iron bearing resources is also disclosed. Selective leaching for Scandium recovery from all magnetite type resources such as ilmenite, ferro titanic resources, nickel laterites, magnetite iron resources etc.

A method and an apparatus method for producing direct reduced iron (DRI) from iron ore using biomass as a source of reductant and as a heating source of the iron ore and electromagnetic energy as a further heating source in a furnace having multiple zones. The zones include a preheat zone and a reduction zone between an inlet for briquettes of iron ore and biomass and an outlet for direct reduced iron. The method includes counter-current movement of (a) briquettes of iron ore and biomass in a direction from the inlet to the outlet and (b) combustible gases in an opposite direction in the furnace.

In some variations, the disclosure provides a renewable biocarbon composition comprising from 50 wt% to 99 wt% total carbon, wherein the biocarbon composition is characterized by a base-acid ratio selected from 0.1 to 10, an iron-calcium ratio selected from 0.05 to 5, iron-plus-calcium parameter selected from 5 to 50 wt%, a slagging factor selected from 0.001 to 1, and/or a fouling factor or modified fouling factor selected from 0.1 to 10. Some variations provide a process comprising: providing a biomass feedstock; pyrolyzing the biomass feedstock to generate an intermediate biocarbon stream; washing or treating the intermediate biocarbon stream with an acid, a base, a salt, a metal, H.sub.2, H.sub.2O, CO, CO.sub.2, or a combination thereof, and/or introducing an additive in the process, to adjust a base-acid ratio or other compositional parameter; and recovering a biocarbon composition comprising from 50 wt% to 99 wt% total carbon and optimized for a compositional parameter.

In some variations, the disclosure provides a renewable biocarbon composition comprising from 50 wt% to 99 wt% total carbon, wherein the biocarbon composition is characterized by a base-acid ratio selected from 0.1 to 10, an iron-calcium ratio selected from 0.05 to 5, iron-plus-calcium parameter selected from 5 to 50 wt%, a slagging factor selected from 0.001 to 1, and/or a fouling factor or modified fouling factor selected from 0.1 to 10. Some variations provide a process comprising: providing a biomass feedstock; pyrolyzing the biomass feedstock to generate an intermediate biocarbon stream; washing or treating the intermediate biocarbon stream with an acid, a base, a salt, a metal, H.sub.2, H.sub.2O, CO, CO.sub.2, or a combination thereof, and/or introducing an additive in the process, to adjust a base-acid ratio or other compositional parameter; and recovering a biocarbon composition comprising from 50 wt% to 99 wt% total carbon and optimized for a compositional parameter.